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Molecular Catalysis of Rare-Earth Elements pp 165–228Cite as

Rare-Earth Metal Postmetallocene Catalysts with Chelating Amido Ligands

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 137))

Abstract

This review deals with the synthesis and the catalytic application of noncyclopentadienyl complexes of the rare-earth elements. The main topics of the review are amido metal complexes with chelating bidentate ligands, which show the most similarities to cyclopentadienyl ligands. Benzamidinates and guanidinates will be reviewed in a separate contribution within this book. Beside the synthesis of the complexes, the broad potential of these compounds in homogeneous catalysis is demonstrated. Most of the reviewed catalytic transformations are either C–C multiple bond transformation such as the hydroamination and hydrosilylation or polymerization reaction of polar and nonpolar monomers. In this area, butadiene and isoprene, ethylene, as well as lactides and lactones were mostly used as monomers.

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Abbreviations

Ar:

Aryl

ATI:

Aminotroponiminate

Bu:

Butyl

CHO:

Cyclohexene oxide

cod:

Cyclooctadiene

cot:

Cyclooctatetraene

Cp:

Cyclopentadienyl, η5-C5H5

Cp∗ :

η5-C5Me5

dep:

Deprotonated

DME:

Dimethoxyethane

equiv:

Equivalent(s)

Et:

Ethyl

h:

Hour(s)

iBu:

iso-Butyl

iPr:

iso-Propyl

Ln:

Rare-earth metal

Me:

Methyl

min:

Minute(s)

MMA:

Methyl methacrylate

MMAO:

Modified methylalumoxane

NMR:

Nuclear magnetic resonance

nPr:

n-Propyl

Ph:

Phenyl

PMMA:

Poly(methyl methacrylate)

Py:

Pyridine

ROP:

Ring-opening polymerization

solv:

Solvent

SSIP:

Solvent-separated ion pair

tBu:

tert-butyl

THF:

Tetrahydrofuran

TMEDA:

Tetramethylethylenediamine

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Acknowledgment

We thank the DFG (SPP 1166 “Lanthanide specific functionalities in molecules and materials”) for financial support of our work related to the topic of this contribution.

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  1. Institut für Anorganische Chemie, Karlsruhe Institute of Technology (KIT), Geb. 30.45, Engesserstr. 15, 76131, Karlsruhe, Germany

    Tianshu Li, Jelena Jenter & Peter W. Roesky

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  1. Tianshu Li
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Correspondence to Peter W. Roesky .

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  1. Inst. Anorganische Chemie, Univ. Karlsruhe, Engesserstr. 30-45, Karlsruhe, 76137, Germany

    Peter W. Roesky

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Dedicated to the memory of Professor Herbert Schumann († 2010), a pioneer of organolanthanide chemistry

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© 2010 Springer-Verlag Berlin Heidelberg

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Li, T., Jenter, J., Roesky, P.W. (2010). Rare-Earth Metal Postmetallocene Catalysts with Chelating Amido Ligands. In: Roesky, P. (eds) Molecular Catalysis of Rare-Earth Elements. Structure and Bonding, vol 137. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2010_18

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