Skip to main content
SpringerLink
Log in

Polymerization of 1,3-Conjugated Dienes with Rare-Earth Metal Precursors

  • Chapter
  • First Online:
Molecular Catalysis of Rare-Earth Elements

Part of the book series: Structure and Bonding ((STRUCTURE,volume 137))

Abstract

This chapter surveys the publications except patents related to cis-1,4-, trans-1,4-, 3,4-regio-, and stereoselective polymerizations of 1,3-conjugated dienes with rare-earth metal-based catalytic systems during the past decade from 1999 to 2009. The concerned catalyst systems are classified into the conventional Ziegler–Natta catalysts, the modified Ziegler–Natta catalysts, and the single-site cationic systems composed of lanthanocene and noncyclopentadienyl precursors, respectively. For the conventional Ziegler–Natta catalysts of the most promising industry applicable recipe, the multicomponents based on lanthanide carboxylate or phosphate or alkoxide precursors, research works concern mainly about optimizing the catalyst preparation and polymerization techniques. Special emphases are put on the factors that influence the catalyst homogeneority, catalytic activity and efficiency, as well as cis-1,4-selectivity. Meanwhile, tailor-made lanthanide aryloxide and amide complexes are designed and fully characterized to mimic the conventional Ziegler–Natta catalysts, anticipated to elucidate the key processes, alkylation and cationization, for generating the active species. Regarding to the single-site catalytic systems generally comprising well-defined complexes containing lanthanide–carbon bonds, investigations cover their versatile catalytic activity and efficiency, and the distinguished regio- and stereoselectivity for both polymerization of dienes and copolymerization of dienes with alkenes. The correlation between the sterics and electronics of ligands and the molecular structures of the complexes and their catalytic performances are highlighted. The isolation of the probable active species in these polymerization processes from the stoichiometric reactions of the precursors with activators will be presented.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Abbreviations

Ar:

Aryl

BD:

Butadiene

BR:

Polybutadiene rubber

Bu:

Butyl

CN:

Coordination number

cot:

Cyclooctatetraene

Cp:

Cyclopentadienyl

d:

Day(s)

DIBAC:

Diisobutylaluminum chloride

DIBAH:

Diisobutylaluminum hydride

DMAC:

Dimethylaluminum chloride

DME:

Dimethoxyethane

DMPE:

1,2-Bis(dimethylphosphino)ethane

DMSO:

Dimethyl sulfoxide

EASC:

Ethylaluminum sesquichloride

equiv:

Equivalent(s)

Et:

Ethyl

Flu:

Fluorenyl

FTIR:

Fourier transform infrared spectroscopy

h:

Hour(s)

Hex:

Hexyl

HIBAO:

Hexaisobutylaluminoxane

iBu:

Isobutyl

Ind:

Indenyl

IP:

Isoprene

iPr:

Isopropyl

IR:

Polyisoprene rubber

L:

Liter(s)

Ln:

Rare-earth metal (i.e., Sc, Y, La–Lu)

MAO:

Methylaluminoxane

Me:

Methyl

Mes:

Mesityl

min:

Minute(s)

MMA:

Methyl methacrylate

MMAO:

Modified methylaluminoxane

ND:

Neodecanoate

NDH:

Neodecanoic acid

NdP:

Neodymium bis(2-ethylhexyl)phosphate

NdV:

Neodymium versatate

NHC:

N-heterocyclic carbene

NMR:

Nuclear magnetic resonance

NR:

Natural rubber

Oct:

Octyl

Ph:

Phenyl

Phen:

1,10-Phenanthroline

Pr:

Propyl

Py:

Pyridine

RT:

Room temperature

SBR:

Styrene–butadiene rubbers

SEC:

Size exclusion chromatography

TBP:

Tributylphosphate

tBu:

Tertbutyl

TEA:

Triethylaluminum

THF:

Tetrahydrofuran

TIBA:

Triisobutylaluminum

TMA:

Trimethylaluminum

TNHA:

Tri(n-hexyl)aluminum

TNOA:

Tri(n-octyl)aluminum

TON:

Turnover number

VT:

Variable temperature

References

  1. Shen Z, Gong ZY, Zhong ZQ, Ouyang J (1964) Sci Sin (Engl Transl) 13:1339

    Google Scholar 

  2. Von Dohlen WC, Wilson TP, Caflisch EG (1964) Belg Patent 644291

    Google Scholar 

  3. Von Dohlen WC, Wilson TP, Caflisch EG (1965) Chem Abstr 63:32659

    Google Scholar 

  4. Throckmorton MC (1969) Kautsch Gummi Kunstst 22:293

    CAS  Google Scholar 

  5. Yang JH, Tsutsui M, Chen Z, Bergbreiter DE (1982) Macromolecules 15:230

    Article  CAS  Google Scholar 

  6. Shen Z (1987) Inorg Chim Acta 140:7

    Article  CAS  Google Scholar 

  7. Kuran W (2001) Principle of coordination polymerisation. Wiley, West Sussex

    Book  Google Scholar 

  8. Shen Z, Ouyang J (1987) Handbook on the physics and chemistry of rare earth. Elsevier, Dordrecht

    Google Scholar 

  9. Friebe L, Nuyken O, Obsrecht W (2006) Adv Polym Sci 204:1 and references therein

    Article  CAS  Google Scholar 

  10. Fischbach A, Anwander R (2006) Adv Polym Sci 204:155 and references therein

    Article  CAS  Google Scholar 

  11. The synthesis and catalysis of cationic rare-earth metal complexes, see review: Hou Z, Wakatsuki Y (2002) Coord Chem Rev 231:1

    Google Scholar 

  12. Arndt S, Okuda J (2001) Chem Rev 102:1953

    Article  CAS  Google Scholar 

  13. Zeimentz PM, Arndt S, Elvidge BR, Okuda J (2006) Chem Rev 106:2404

    Article  CAS  Google Scholar 

  14. Natta G, Porri L, Carbonaro A (1964) Makromol Chem 77:126

    Article  CAS  Google Scholar 

  15. Milione S, Cuomo C, Capacchione C, Zannoni C, Grassi A, Proto A (2007) Macromolecules 40:5638

    Article  CAS  Google Scholar 

  16. Natta G, Porri L, Corradini P, Morero D (1958) Chim Ind 40:263

    Google Scholar 

  17. Natta G, Porri L, Mazzei A (1959) Chim Ind 41:116

    CAS  Google Scholar 

  18. Colamarco E, Milione S, Cuomo C, Grassi A (2004) Macromol Rapid Commun 25:450

    Article  CAS  Google Scholar 

  19. Nakayama Y, Baba Y, Yasuda H, Kawakita K, Ueyama N (2003) Macromolecules 36:7953

    Article  CAS  Google Scholar 

  20. Jenkins DK (1985) Polymer 26:147

    Article  CAS  Google Scholar 

  21. Baudry-Barbier D, Andre N, Dormond A, Pardes C, Richard P, Visseaux M, Zhu CJ (1998) Eur J Inorg Chem, p 1721

    Google Scholar 

  22. Gronski W, Murayama N, Cantow HJ, Miyamoto T (1976) Polymer 17:358

    Article  CAS  Google Scholar 

  23. Ricci G, Battistella M, Porri L (2001) Macromolecules 34:5766

    Article  CAS  Google Scholar 

  24. Sun Q, Wang F (1988) Acta Polym Sin 2:145

    Google Scholar 

  25. Bazzini C, Giarrusso A, Porri L (2002) Macromol Rapid Commun 23:922

    Article  CAS  Google Scholar 

  26. Nakayama Y, Baba Y, Yasuda H, Kawakita K, Ueyama N (2003) Macromolecules 36:7953

    Article  CAS  Google Scholar 

  27. Bazzini C, Giarrusso A, Porri L, Pirozzi B, Napolitano R (2004) Polymer 45:2871

    Article  CAS  Google Scholar 

  28. Marina NG, Monakov YB, Sabirov ZM, Tolstikov GA, (1991) Polym Sci USSR (Engl. Trans.) 33:387

    Article  Google Scholar 

  29. Monakov YB, Marina NG, Sabirov ZM (1994) Polym Sci USSR (Engl. Trans.) 36:1404

    Google Scholar 

  30. Taube R, Sylvester G, (1996) Stereospecific polymerization of butadiene or isoprene. In: Cornils B, Herrmann WA (eds) Applied homogeneous catalysis with organometallic compounds, vol. 1 VCH, Weinheim, p 280

    Google Scholar 

  31. Iovu H, Hubea G, Racoti D, Hurst JS (1999) Eur Polym J 35:335

    Article  CAS  Google Scholar 

  32. Porri L, Ricci G, Shubin N (1988) Macromol Symp 128:53

    Article  Google Scholar 

  33. Kobayashi E, Hayashi N, Aoshima S, Furukawa J (1998) J Polym Sci Part A Polym Chem 36:241

    Article  CAS  Google Scholar 

  34. Mello IL, Coutinho FMB. (2008) Eur Polym J 44:2893

    Article  CAS  Google Scholar 

  35. Mello IL, Coutinho FMB, Nunes DSS, Soares BG, Costa MAS, Maria LCS (2004) Quim Nova 27:277

    Article  CAS  Google Scholar 

  36. Yang J, Hu J, Fang S, Pan E, Xie D, Zhong CG, Ouyang J (1980) Sci Sin 23:734

    CAS  Google Scholar 

  37. Srinivasa Rao GS, Upadhyay VK, Jain RC (1997) Angew Makromol Chem 251:193

    Article  Google Scholar 

  38. Gallazzi MC, Bianchi F, Depero L, Zocchi M (1988) Polymer 29:1516

    Article  CAS  Google Scholar 

  39. Rafikov SR, Monakov YB, Marina NG, Duvakina NV, Tolstikov GA, Krivonogov VP, Nurmukhametov FN, Kovalev NF, Tikhomirova GA (1980) USSR Pat. 730,710. Chem Abstr 1980, 93:96152V

    Google Scholar 

  40. Monakov YB, Rafikov SR, Bezgina AS, Tolstikov GA, Duvakina NV, Marina NG, Murinov YI, Nikitin YE, Berg AA (1980) USSR Pat. 726, 110. Chem Abstr 1980, 93:72926Z

    Google Scholar 

  41. Ren C, Li G, Dong W, Jiang L, Zhang X, Wang F (2007) Polymer 48:2470

    Article  CAS  Google Scholar 

  42. Srinivasa Rao GS, Upadhyay VK, Jain RC (1999) J Appl Polym Sci 71:595

    Article  Google Scholar 

  43. Barbotin F, Spitz R, Boisson C (2001) Macromol Rapid Commun 22:1411

    Article  CAS  Google Scholar 

  44. Dong W, Masuda T (2002) J Polym Sci Part A Polym Chem 40:1838

    Article  CAS  Google Scholar 

  45. Ricci G, Italia S, Comitani C, Porri L (1991) Polym Commun 32:514

    CAS  Google Scholar 

  46. Endo K, Masaki K, Uchida Y (1997) Polym J 29:583

    Article  CAS  Google Scholar 

  47. Wilson DJ (1996) Polym Int 39:235

    Article  CAS  Google Scholar 

  48. Cui L, Ba X, Teng H, Ying L, Li K, Jin Y (1998) Polym Bull 40:729

    Article  CAS  Google Scholar 

  49. Dong W, Masuda T (2003) Polymer 44:1561

    Article  CAS  Google Scholar 

  50. Taniguchi Y, Dong W, Katsumata T, Shiotsuki M, Masuda T (2005) Polym Bull 54:173

    Article  CAS  Google Scholar 

  51. Boisson C, Barbotin F, Boisson RS (1999) Macromol Chem Phys 200:1163

    Article  CAS  Google Scholar 

  52. Oehme A, Gebauer U, Gehrke K (1993) J Mol Catal 82:83

    Article  CAS  Google Scholar 

  53. Kaita S, Kobayashi E, Sakakibara S, Aoshima S, Furukawa J (1996) J Polym Sci A Polym Chem 34:3431

    Article  Google Scholar 

  54. Hsieh HL, Yeh HC (1985) Rubber Chem Technol 58:117

    Article  CAS  Google Scholar 

  55. Pires NMT, Coutinho FMB, Costa MAS (2004) Eur Polym J 40:2599

    Article  CAS  Google Scholar 

  56. Friebe L, Müller JM, Nuyken O, Obsrecht W (2006) J Macromol Sci A Pure Appl Chem 43:841

    Article  CAS  Google Scholar 

  57. Porri L, Giannini U, Pino P (1987) Encyclopedia of polymer science and engineering, vol 8. Identification to lignin, 2nd edn. Wiley, New York

    Google Scholar 

  58. Mello IL, Coutinho FMB, Nunes DSS, Soares BG, Costa MAS, Luiz Claudio de Santa Maria (2004) Eur Polym J 40:635

    Article  CAS  Google Scholar 

  59. Coutinho FMB, Rocha TCJ, Mello IL, Nunes, DSS, Soares BG, Costa MAS (2005) J Appl Polym Sci 98:2539

    Article  CAS  Google Scholar 

  60. Gallazzi MC, Giarrusso A, Porri L (1981) Makromol Chem Rapid Commun 2:59

    Article  CAS  Google Scholar 

  61. Porri L, Gallazzi MC (1983) Makromol Chem Rapid Commun 4:485

    Article  CAS  Google Scholar 

  62. Mello IL, Coutinho FMB (2009) J Appl Polym Sci 112:1496

    Article  CAS  Google Scholar 

  63. Rocha TCJ, Coutinho FMB, Soares BG (2009) Polym Bull 62:1

    Article  CAS  Google Scholar 

  64. Sigaeva NN, Usmanov TS, Zaikov GE, Monakov YB (2003) J Appl Polym Sci 89:674

    Article  CAS  Google Scholar 

  65. Friebe L, Nuyken O, Windisch H, Obsrecht W (2002) Macromol Chem Phys 203:1055

    Article  CAS  Google Scholar 

  66. Friebe L, Windisch H, Nuyken O, Obsrecht W (2004) J Macromol Sci A Pure Appl Chem 41:245

    Article  CAS  Google Scholar 

  67. Friebe L, Müller JM, Nuyken O, Obsrecht W (2006) J Macromol Sci A Pure Appl Chem 43:11

    Article  CAS  Google Scholar 

  68. Friebe L, Nuyken O, Obsrecht W (2005) J Macromol Sci A Pure Appl Chem 42:839

    Article  CAS  Google Scholar 

  69. Quirk RP, Kells AM (2000) Polym Int 49:751

    Article  CAS  Google Scholar 

  70. Quirk RP, Kells AM, Yunlub K, Cuif J-P (2000) Polymer 41:5903

    Article  CAS  Google Scholar 

  71. Kwag G (2002) Macromolecules 35:4875

    Article  CAS  Google Scholar 

  72. Kwag G, Kim P, Han S, Choi H (2005) Polymer 46:3782

    Article  CAS  Google Scholar 

  73. James DI (1967) Abrasion of rubber. Maclarren, London

    Google Scholar 

  74. Erma B, Mark JE (1998) Macromolecules 31:3099

    Article  Google Scholar 

  75. Su T-K, Mark JE (1993) Macromolecules 26:7161

    Article  Google Scholar 

  76. Mark JE (2003) Macromol Symp 201:77

    Article  CAS  Google Scholar 

  77. Merwe MJ, Gradwell MHS, McGill WJ (2001) J Appl Polym Sci 81:2587

    Article  Google Scholar 

  78. Maiwald S, Sommer C, Müller G, Taube R (2001) Macromol Chem Phys 202:1446

    Article  CAS  Google Scholar 

  79. Maiwald S, Sommer C, Müller G, Taube R (2002) Macromol Chem Phys 203:1029

    Article  CAS  Google Scholar 

  80. Evans WJ, Giarikos DG, Allen NT (2003) Macromolecules 36:4256

    Article  CAS  Google Scholar 

  81. Evans WJ, Giarikos DG, Ziller JW (2001) Organometallics 20:5751

    Article  CAS  Google Scholar 

  82. Quirk R, Kells A, Yunlu KM, Cuif J-P (2000) Polymer 41:5903

    Article  CAS  Google Scholar 

  83. Oehme A, Gebauer U, Gehrke K, Lechner MD (1996) Angew Makromol Chem 235:121

    Article  CAS  Google Scholar 

  84. Kwag G, Lee H, Kim S (2001) Macromolecules 34:5367

    Article  CAS  Google Scholar 

  85. Koboyashi E, Hayashi N, Aoshima S, Furukaya J (1998) J Polym Sci Polym Chem 36:1707

    Article  Google Scholar 

  86. Pross A, Marquardt P, Reichert K-H, Nentwig W, Knauf T (1993) Angew Makromol Chem 211:89

    Article  CAS  Google Scholar 

  87. Ricci G, Italia S, Cabassi F, Porri L (1987) Polym Commun 28:223

    CAS  Google Scholar 

  88. Iovu H, Hubca G, Racoti D, Hurst JS (1999) Eur Polym J 35:335

    Article  CAS  Google Scholar 

  89. Dimonie M, Hubca G, Badea E, Simionescu E, Iovu H, Vasile I, Stan S (1991) Rev Roum Chim 40:83 and references therein

    Google Scholar 

  90. Boisson C, Barbotin F, Spitz R (1999) Macromol Chem Phys 200:1163

    Article  CAS  Google Scholar 

  91. Evans WJ, Giarikos DG (2004) Macromolecules 37:5130

    Article  CAS  Google Scholar 

  92. Fischbach A, Perdih F, Sirsch P, Scherer W, Anwander R (2002) Organometallics 21:4569

    Article  CAS  Google Scholar 

  93. Fink G, Mühlhaupt R, Brintzinger H-H (eds) (1995) Ziegler catalysts. Springer, Berlin

    Google Scholar 

  94. Mühlhaupt R (2003) Macromol Chem Phys 204:289

    Article  Google Scholar 

  95. Böhm LL (2003) Angew Chem Int Ed 42:5010

    Article  CAS  Google Scholar 

  96. Evans WJ, Champagne TM, Giarikos DG, Ziller JW (2005) Organometallics 24:570

    Article  CAS  Google Scholar 

  97. Evans WJ, Champagne TM, Ziller JW (2005) Organometallics 24:4882

    Article  CAS  Google Scholar 

  98. Evans WJ, Champagne, TM, Ziller JW (2005) Chem Commun, p 5925

    Google Scholar 

  99. Fischbach A, Perdih F, Herdtweck E, Anwander R (2006) Organometallics 25:1626

    Article  CAS  Google Scholar 

  100. Fischbach A, Klimpel MG, Widenmeyer M, Herdtweck E, Scherer W, Anwander R (2004) Angew Chem Int Ed 43:2234

    Article  CAS  Google Scholar 

  101. Zimmermann M, Froystein NA, Fischbach A, Sirsch P, Martin Dietrich H, Tönroos KW, Herdtweck E, Anwander R (2007) Chem Eur J 13:8784

    Article  CAS  Google Scholar 

  102. Fischbach A, Meermann C, Eickerling G, Scherer W, Anwander R (2006) Macromolecules 39:6811

    Article  CAS  Google Scholar 

  103. Meermann C, Törnroos KW, Nerdal W, Anwander R (2007) Angew Chem Int Ed 46:6508

    Article  CAS  Google Scholar 

  104. Kaita S, Hou Z, Wakatsuki Y (1999) Macromolecules 32:9078

    Article  CAS  Google Scholar 

  105. Schumann H, Marks TJ (1985) J Am Chem Soc 107:8091

    Article  Google Scholar 

  106. Jeske G, Schock LE, Swepston PN, Schumann H, Marks TJ (1985) J Am Chem Soc 107:8103

    Article  CAS  Google Scholar 

  107. Yasuda H, Yamamoto H, Yokota K, Miyake S, Nakamura A (1992) J Am Chem Soc 114:4908

    Article  CAS  Google Scholar 

  108. Yasuda H, Furo M, Yamamoto H, Miyake S, Kibino N (1992) Macromolecules 25:5115

    Article  CAS  Google Scholar 

  109. Yamashita M, Ihara E, Yasuda H (1995) Macromolecules 29:1798

    Article  Google Scholar 

  110. Kaita S, Takeguchi Y, Hou Z, Nishiura M, Doi Y, Wakatsuki Y (2003) Macromolecules 36:7923

    Article  CAS  Google Scholar 

  111. Kaita S, Hou Z, Nishiura M, Doi Y, Kurazumi J, Akira C, Horiuchi AC, Wakatsuki Y (2003) Macromol Rapid Commun 24:179

    Article  CAS  Google Scholar 

  112. Kaita S, Yamanaka M, Horiuchi AC, Wakatsuki Y (2006) Macromolecules 39:1359

    Article  CAS  Google Scholar 

  113. Yang Y, Liu B, Lv K, Gao W, Cui D, Chen X, Jing X (2007) Organometallics 26:4575

    Article  CAS  Google Scholar 

  114. Kaita S, Doi Y, Kaneko K, Horiuchi AC, Wakatsuki Y (2004) Macromolecules 37:5860

    Article  CAS  Google Scholar 

  115. Tardif O, Kaita S (2008) Dalton Trans, p 2531

    Google Scholar 

  116. Bonnet F, Violante CDC, Roussel P, Mortreux A, Visseaux M (2009) Chem Commun, p 3380

    Google Scholar 

  117. Aubrecht KB, Chang K, Hillmyer MA, Tolman WB (2001) J Polym Sci A Polym Chem 39:284

    Google Scholar 

  118. Zinck P, Barbier-Baudry D, Loupy A (2005) Macromol Rapid Commun 26:46

    Article  CAS  Google Scholar 

  119. Bijpost EA, Duchateau R, Teuben JH (1995) J Mol Catal A Chem 95:121

    Article  CAS  Google Scholar 

  120. Duchateau R, van Wee CT, J. H. Teuben, (1996) Organometallics 15:2291

    Article  CAS  Google Scholar 

  121. Aubrecht KB, Chang K, Hillmyer MA, Tolman WB (2001) J Polym Sci A Polym Chem 39:284

    Article  CAS  Google Scholar 

  122. Duchateau R, van Wee CT, Meetsma A, Teuben JH (1993) J Am Chem Soc 115:4931

    Article  CAS  Google Scholar 

  123. Bailey PJ, Pace S (2001) Coord Chem Rev 214:91

    Article  CAS  Google Scholar 

  124. Giesbrecht GR, Whitener GD, Arnold J (2001) J Chem Soc Dalton Trans, p 923

    Google Scholar 

  125. Lu Z, Yap GPA, Richeson DS (2001) Organometallics 20:706

    Article  CAS  Google Scholar 

  126. Hayes PG, Piers WE, Lee LWM, Knight LK, Parvez M, Elsegood MRJ, Clegg W (2001) Organometallics 20:2533

    Article  CAS  Google Scholar 

  127. Emslie DJH, Piers WE, McDonald R (2002) J Chem Soc Dalton Trans, p 293

    Google Scholar 

  128. Arndt S, Beckerle K, Zeimentz PM, Spaniol TP, Okuda J (2005) Angew Chem Int Ed 44:7473

    Article  CAS  Google Scholar 

  129. Robert D, Abinet E, Spaniol TP, Okuda J (2009) Chem Eur J 15:11937

    Article  CAS  Google Scholar 

  130. Yang Y, Liu B, Lv K, Gao W, Cui D, Chen X, Jing X (2007) Organometallics 26:4575

    Article  CAS  Google Scholar 

  131. Yang Y, Wang Q, Cui D (2008) J Polym Sci A Polymer Chem 46:5251

    Article  CAS  Google Scholar 

  132. Zhang L, Suzuki T, Luo Y, Nishiura M, Hou Z (2007) Angew Chem Int Ed 46:1909

    Article  CAS  Google Scholar 

  133. Zhang L, Nishiura M, Yuki M, Luo Y, Hou Z (2008) Angew Chem Int Ed 47:2642

    Article  CAS  Google Scholar 

  134. Allen G (1989) Comprehensive polymer science, vol 4. Pergamon, Oxford, pp 53–108

    Google Scholar 

  135. Longiave C, Castelli R (1963) J Polym Sci C Polym Symp 4:387

    Article  Google Scholar 

  136. Thuilliez J, Monteil V, Spitz R, Boisson C (2005) Angew Chem Int Ed 44:2593

    Article  CAS  Google Scholar 

  137. Gao W, Cui D (2008) J Am Chem Soc 130:4984

    Article  CAS  Google Scholar 

  138. Sugiyama H, Gambarotta S, Yap GPA, Wilson DR, Thiele SKH (2004) Organometallics 23:5054

    Article  CAS  Google Scholar 

  139. Gehrke K, Harwart M (1993) Plast Kautsch 40:356

    CAS  Google Scholar 

  140. Anzai S, Irako K, Onishi A, Furukawa J (1969) Kogyo Kagaku Zasshi 72:2081

    Article  CAS  Google Scholar 

  141. Oehme A, Gebauer U, Gehrke K (1995) Macromol Rapid Commun 16:563

    Article  CAS  Google Scholar 

  142. Zambelli A, Proto A, Longo P, Oliva P (1994) Macromol Chem Phys 195:2623

    Article  CAS  Google Scholar 

  143. Rastätter M, Muterle RB, Roesky PW, Thiele SKH (2009) Chem Eur J 15:474

    Article  CAS  Google Scholar 

  144. Halasa AF, Hsu WL, Austin LE, Jasiunas CA (2002) U.S. Patent 183469

    Google Scholar 

  145. Halasa AF, Hsu WL, Austin LE, Jasiunas CA, Goodyear (2002) Chem Abstr 138:14610

    Google Scholar 

  146. Song JS, Huang BC, Yu DS (2001) J Appl Polym Sci 82:81

    Article  CAS  Google Scholar 

  147. Visseaux M, Barbier-Baudry D, Bonnet F, Dormond A (2001) Macromol Chem Phys 202:2485

    Article  CAS  Google Scholar 

  148. Bonnet F, Visseaux M, Barbier-Baudry D, Dormond A (2002) Macromolecules 35:1143

    Article  CAS  Google Scholar 

  149. Boisson C, Monteil V, Ribour D, Spitz R, Barbotin F (2003) Macromol Chem Phys 204:1747

    Article  CAS  Google Scholar 

  150. Urazbaev VN, Efimov VP, Sabirov ZM, Monakov YB (2003) J Appl Polym Sci 89:601

    Article  CAS  Google Scholar 

  151. Bonnet F, Visseaux M, Pereira A, Bouyer F, Barbier-Baudry D (2004) Macromol Rapid Commun 25:873

    Article  CAS  Google Scholar 

  152. Bonnet F, Visseaux M, Barbier-Baudry D, Vigier E, Marek M, Kubicki MK (2004) Chem Eur J 10:2428

    Article  CAS  Google Scholar 

  153. Bonnet F, Visseaux M, Pereira A, Barbier-Baudry D (2005) Macromolecules 38:3162

    Article  CAS  Google Scholar 

  154. Terrier M, Visseaux M, Chenal T, Mortreux A (2007) J Polym Sci A Polym Chem 45:2400

    Article  CAS  Google Scholar 

  155. Visseaux M, Terrier M, Mortreux A, Roussel P (2007) C R Chimie 10:1195

    Article  CAS  Google Scholar 

  156. Visseaux M, Zinck P, Terrier M, Mortreux A, Roussel P (2008) J Alloys Compd 451:352

    Article  CAS  Google Scholar 

  157. Valente A, Zinck P, Mortreux A, Visseaux M (2009) Macromol Rapid Commun 30:528

    Article  CAS  Google Scholar 

  158. Barbier-Baudry D, Blacque O, Hafid A, Nyassi A, Sitzmann H, Visseaux M (2000) Eur J Inorg Chem, p 2333

    Google Scholar 

  159. Zimmermann M, Törnroos KW, Anwander R (2008) Angew Chem Int Ed 47:775

    Article  CAS  Google Scholar 

  160. Zimmermann M, Törnroos KW, Sitzmann H, Anwander R (2008) Chem Eur J 14:7266

    Article  CAS  Google Scholar 

  161. Robert D, Spaniol TP, Okuda J (2008) Eur J Inorg Chem, p 2801

    Google Scholar 

  162. Taube R, Maiwald S, Sieler J (2001) J Organomet Chem 621:327

    Article  CAS  Google Scholar 

  163. Maiwald S, Weißenborn H, Sommer C, Müller G, Taube R (2001) J Organomet Chem 640:1

    Article  CAS  Google Scholar 

  164. Ajellal N, Furlan L, Thomas CM, Casagrande OL, Jr Carpentier J-F (2006) Macromol Rapid Commun 27:338

    Article  CAS  Google Scholar 

  165. Paolucci G, Zanella A, Bortoluzzi M, Sostero S, Longoc P, Napoli M (2007) J Mol Catal A Chem 272:258

    Article  CAS  Google Scholar 

  166. Wang D, Li S, Liu X, Gao W, Cui D (2008) Organometallics 27:6531

    Article  CAS  Google Scholar 

  167. Monakov Y B, Duvakina NV, Ionova IA (2008) Polym Sci Ser B 50:134

    Article  Google Scholar 

  168. Wolpers J (1992) US Patent 5,104,941

    Google Scholar 

  169. Jonny DM (1994) US Patent 5,356,997

    Google Scholar 

  170. Duddey J (2002) US Patent 6,390,163

    Google Scholar 

  171. Yamasita K, Murachi M, Sugiyama M (1999) US Patent 5,906,959

    Google Scholar 

  172. Hsu W, Halasa A (1993) US Patent 5,239,023

    Google Scholar 

  173. Zhang L, Luo Y, Hou Z (2005) J Am Chem Soc 127:14562

    Article  CAS  Google Scholar 

  174. Wang B, Cui D, Lv K (2008) Macromolecules 41:1983

    Article  CAS  Google Scholar 

  175. Wang B, Wang D, Cui D, Gao W, Tang T, Chen X, Jing X (2007) Organometallics 26:3167

    Article  CAS  Google Scholar 

  176. Li S, Miao W, Tang T, Dong W, Zhang X, Cui D (2008) Organometallics 27:718

    Article  CAS  Google Scholar 

  177. Li S, Cui D, Li D, Hou Z (2009) Organometallics 28:4814

    Article  CAS  Google Scholar 

  178. Barbotin F, Monteil V, Llauro M, Boisson C, Spitz R. (2000) Macromolecules 33:8521

    Article  CAS  Google Scholar 

  179. Döring C, Kretschmer WP, Bauer T, Kempe R (2009) Eur J Inorg Chem, p 4255

    Google Scholar 

  180. Monteil V, Spitz R, Barbotin F, Boisson C (2004) Macromol Chem Phys 205:737

    Article  CAS  Google Scholar 

  181. Thuilliez J, Ricard L, Nief F, Boisson F, Boisson C (2009) Macromolecules 42:3774

    Article  CAS  Google Scholar 

  182. Thuilliez J, Spitz R, Boisson C (2006) Macromol Chem Phys 207:1727

    Article  CAS  Google Scholar 

  183. Boisson C, Monteil V, Thuilliez J, Spitz R, Monnet C, Llauro MF, Barbotin F, Robert P (2005) Macromol Symp 226:17

    Article  CAS  Google Scholar 

  184. Woodman TJ, Sarazin Y, Fink G, Hauschild K, Manfred Bochmann M (2005) Macromolecules 38:3060

    Article  CAS  Google Scholar 

  185. Barbier-Baudry D, Bonnet F, Dormond A, Hafid A, Nyassi A, Visseaux M (2001) J Alloys Compd 323–324:592

    Article  Google Scholar 

  186. Barbier-Baudry D, Bonnet F, Domenichini B, Dormond A, Visseaux M. (2002) J Organomet Chem 647:167

    Article  CAS  Google Scholar 

  187. Bonnet F, Barbier-Baudry D, Dormond A, Visseaux M (2002) Polym Int 51:986

    Article  CAS  Google Scholar 

  188. Barbier-Baudry D, Bonnet F, Dormond A, Finot E, Visseaux M (2002) Macromol Chem Phys 203:1194

    Article  CAS  Google Scholar 

  189. Monteil V, Spitz R, Boisson C (2004) Polym Int 53:576

    Article  CAS  Google Scholar 

  190. Zhang Q, Li W, Shen Z (2002) Eur Polym J 38:869

    Article  CAS  Google Scholar 

  191. Zhang Q, Ni X, Shen Z (2002) Polym Int 51:208

    Article  CAS  Google Scholar 

  192. Zhang Q, Ni X, Shen Z (2004) J Macromol Sci A Pure Appl Chem 41:39

    Article  CAS  Google Scholar 

  193. Zhu H, Wu Y-X, Zhao J-W, Guo Q-L, Huang Q-G, Wu G-Y (2007) J Appl Polym Sci 106:103

    Article  CAS  Google Scholar 

  194. Gromada J, Pichon LL, Mortreux A, Leising F, Carpentier J-F (2003) J Organomet Chem 683:44

    Article  CAS  Google Scholar 

  195. Zinck P, Terrier M, Mortreux A, Valente A, Visseaux M (2007) Macromol Chem Phys 208:973

    Article  CAS  Google Scholar 

  196. Rodrigues A-S, Kirillov E, Vuillemin B, Razavi A, Carpentier J-F (2008) Polymer 49:2039

    Article  CAS  Google Scholar 

  197. Kaita S, Hou Z, Wakatsuki Y (2001) Macromolecules 34:1539

    Article  CAS  Google Scholar 

  198. Zhang H, Luo Y, Hou Z (2008) Macromolecules 41:1064

    Article  CAS  Google Scholar 

  199. Li X, Nishiura M, Hu L, Mori K, Hou Z (2009) J Am Chem Soc 131:13870

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

    Zhichao Zhang, Dongmei Cui, Baoli Wang, Bo Liu & Yi Yang

Authors
  1. Zhichao Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dongmei Cui
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Baoli Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Bo Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yi Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dongmei Cui .

Editor information

Editors and Affiliations

  1. Inst. Anorganische Chemie, Univ. Karlsruhe, Engesserstr. 30-45, Karlsruhe, 76137, Germany

    Peter W. Roesky

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Zhang, Z., Cui, D., Wang, B., Liu, B., Yang, Y. (2010). Polymerization of 1,3-Conjugated Dienes with Rare-Earth Metal Precursors. In: Roesky, P. (eds) Molecular Catalysis of Rare-Earth Elements. Structure and Bonding, vol 137. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2010_16

Download citation

Publish with us

Policies and ethics

Search

Navigation