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Controllable Assembly, Structures, and Properties of Lanthanide–Transition Metal–Amino Acid Clusters

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Controlled Assembly and Modification of Inorganic Systems

Part of the book series: Structure and Bonding ((STRUCTURE,volume 133))

Abstract

Amino acids are the basic building blocks in the chemistry of life. This chapter describes the controllable assembly, structures and properties of lathanide(III)–transition metal–amino acid clusters developed recently by our group. The effects on the assembly of several factors of influence, such as presence of a secondary ligand, lanthanides, crystallization conditions, the ratio of metal ions to amino acids, and transition metal ions have been expounded. The dynamic balance of metalloligands and the substitution of weak coordination bonds account for the occurrence of diverse structures in this series of compounds.

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Acknowledgement

This work was supported by the grants from NNSF of China (20673118 and 20733003), NSF of Fujian Province (2005HZ01-1 and 2006J0014), 973 program (2007CB815301 and 2006CB932900) and the Chinese Academy of Sciences (KJCX2-YW-M05).

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  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China

    Sheng-Chang Xiang, Sheng-Min Hu, Tian-Lu Sheng, Ling Chen & Xin-Tao Wu

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  1. Sheng-Chang Xiang
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Correspondence to Sheng-Chang Xiang .

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  1. Fujian Institute of Research on the, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China, People's Republic

    Xin-Tao Wu

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Xiang, SC., Hu, SM., Sheng, TL., Chen, L., Wu, XT. (2009). Controllable Assembly, Structures, and Properties of Lanthanide–Transition Metal–Amino Acid Clusters. In: Wu, XT. (eds) Controlled Assembly and Modification of Inorganic Systems. Structure and Bonding, vol 133. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2008_15

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