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New Progress in Monomeric Phthalocyanine Chemistry: Synthesis, Crystal Structures and Properties

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Controlled Assembly and Modification of Inorganic Systems

Part of the book series: Structure and Bonding ((STRUCTURE,volume 133))

Abstract

In this chapter, recent progress in the synthesis, crystal structures and physical properties of monomeric phthalocyanines (Pcs) is summarized and analysed. The strategies for synthesis and modification of Pcs include axial coordination of central metal ions, peripheral substitution of Pc rings and the ionization of Pcs. The crystal structures of various typical Pcs, especially the effects of different synthetic and modification strategies on the supramolecular assemblies of Pcs via π–π interactions between Pc rings, are discussed in detail. Finally, the UV–vis spectroscopic, conducting, magnetic and catalytic properties of some Pcs with crystal structures are presented briefly, and the correlations between various properties and the molecular structure discussed.

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Abbreviations

ac:

Acetone

AO:

Amyloxy

BA:

Benzylamine

BzT:

Benzylthio

4-tBuB:

4-(Tertiary-butyl)benzoate

BuO:

Butyloxy

15-C-5:

15-Crown-5

ClNP:

Chloronaphthalene

4-CP:

4-Cyanopyridine

DHCP:

1,1-Dihexylcyclopentane

DMF:

N,N-Dimethylformamide

DMPO:

2,4-Dimethyl-3-pentyloxy

DMPP:

3-(3,4-Dimethoxyphenyl)propanoate

DPP:

2,3-Di(2-pyridyl)pyrazino

DiPPO:

2,6-Diisopropylphenoxy

DTB:

3,5-Di-[1,4,7,10-tetraoxaundecyl]benzyloxy

EE:

Ethoxyethanol

EO:

Ethyloxy

4-FP:

4-Fluorophenyl

HT:

Hexylthio

MEA:

2-Methoxyethylamine

4-MP:

4-Methylpyridine

MPc:

Metal phthalocyanine

PFiP:

Perfluoroisopropyl

Pc:

Phthalocyanine, phthalocyaninato

PO:

3-Pentyloxy

Py:

Pyridine

PXX:

Peri-xanthenoxanthene

3-TA:

3-Thienylacetate

TMPO:

2,2,4-Trimethyl-3-pentyloxy

TPIP:

1-Triphenylphosphoranylidene-2-propanone

TPP:

Tetraphenylphosphonium, tetraphenylporphyrin

TDOFe:

Tridioximates macrobicyclic ironII complex

TED:

Triethylenediamine

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Acknowledgement

The authors thank the National Natural Science Foundation of China, the Education Ministry of China, and Shandong University for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Shandong University, Jinan, 250100, China

    Zhonghai Ni, Renjie Li & Jianzhuang Jiang

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  1. Zhonghai Ni
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  2. Renjie Li
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  3. Jianzhuang Jiang
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Correspondence to Zhonghai Ni .

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Editors and Affiliations

  1. Fujian Institute of Research on the, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China, People's Republic

    Xin-Tao Wu

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Ni, Z., Li, R., Jiang, J. (2009). New Progress in Monomeric Phthalocyanine Chemistry: Synthesis, Crystal Structures and Properties. In: Wu, XT. (eds) Controlled Assembly and Modification of Inorganic Systems. Structure and Bonding, vol 133. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2008_13

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