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Contemporary Metal Boron Chemistry I pp 29–122Cite as

Transition Metal Boryl Complexes

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 130))

Abstract

The article represents a review of the chemistry of transition metal complexes containing the boryl (–BX2) ligand based on the chemical literature published up to and including the calendar year 2006. A brief compendium of papers published in the year 2007 is also included. Notwithstanding the ever-growing volume of literature detailing useful organic transformations in which these complexes have been implicated (e.g. C–H activation, hydroboration, diboration), the primary focus of this article is a review of issues of structure and bonding in boryl systems. Thus, the evidence for boryl ligands acting – to a greater or lesser extent – as sigma donors and/or pi acceptors is examined at length, as are issues relating to secondary interactions (e.g with hydride co-ligands) within the metal coordination sphere, and the consequent relationship to borane sigma complexes.

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Authors and Affiliations

  1. School of Chemistry, University of Nottingham, University Park, NG7 2RD, Nottingham, UK

    Deborah L. Kays

  2. Inorganic Chemistry, South Parks Road, OX1 3QR, Oxford, UK

    Simon Aldridge

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  1. Deborah L. Kays
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Todd B. Marder Zhenyang Lin

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Kays, D.L., Aldridge, S. (2008). Transition Metal Boryl Complexes. In: Marder, T.B., Lin, Z. (eds) Contemporary Metal Boron Chemistry I. Structure and Bonding, vol 130. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2007_079

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