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NMR Spectroscopic Techniques for Determining Acidity and Basicity

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Acidity and Basicity

Part of the book series: Molecular Sieves ((SIEVES,volume 6))

Abstract

Solid acids and bases have found numerous applications in heterogeneous catalysis. However, the characterization of the acidic and basic properties of solids is relatively complicated compared to that of liquids. This contribution summarizes the state of the art in the spectroscopic determination of acidity and basicity by NMR methods, especially with respect to zeolites. Zeolites are porous inorganic crystals built from TO4 tetrahedra. In original zeolites, T represents Si or Al. The latter atoms may be replaced to some extent by other elements like B, Ga, Be, Ti etc. Other classes of microporous materials are based, e.g. on AlPO4 compounds. The ability of zeolites to act as acid catalysts had already been described in the early 1960s and has remained an interesting subject of research. In recent years, zeolites have also found increasing interest as basic catalysts. The presence of both acidic and basic sites is responsible for the broad applicability of zeolites as catalysts.

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References

  1. Weitkamp J (1991) Stud Surf Sci Catal 65:21

    CAS  Google Scholar 

  2. Haag WO (1994) Stud Surf Sci Catal 84:1375

    CAS  Google Scholar 

  3. Naber JE, de Jong KP, Stork WHJ, Kuipers HPCE, Post MFM (1994) Stud Surf Sci Catal 84:2197

    CAS  Google Scholar 

  4. Barthomeuf D (1994) In: Fraissard J, Petrakis L (eds) Acidity and basicity of solids, NATO ASI Series C, vol 444. Kluwer Academic, Dordrecht, p 181

    Google Scholar 

  5. Kouwenhoven HW, Gunnewegh EA, van Bekkum H (1996) In: Weitkamp J, Lücke B (eds) Proceedings 9601 of the DGMK-conference: catalysis on solid acids and bases, Berlin, 14–15 March 1996. DGMK, Hambuerg, p 9

    Google Scholar 

  6. Hölderich W, Gallei E (1985) Ger Chem Eng 8:337

    Google Scholar 

  7. Tißler A, Müller U, Unger K (1988) Nachr Chem Tech Lab 36:624

    Google Scholar 

  8. Breck DW (1974) Zeolite molecular sieves: structure, chemistry and use. Wiley, London

    Google Scholar 

  9. Barrer RM (1978) Zeolite and clay minerals as sorbents and molecular sieves. Academic, London

    Google Scholar 

  10. Meier WM, Olson DH (1992) Atlas of zeolite structure types, 3rd edn. Butterworth, London

    Google Scholar 

  11. Barrer RM (1982) Hydrothermal chemistry of zeolites. Academic, London

    Google Scholar 

  12. Bellussi G, Rigutto MS (1994) Stud Surf Sci Catal 85:177

    CAS  Google Scholar 

  13. Wilson ST, Lok BM, Messina CA, Cannan TR, Flanigen EM (1982) J Am Chem Soc 104:1146

    CAS  Google Scholar 

  14. Lok BM, Messina CA, Patton RL, Gajek RT, Cannan TR, Flanigen EM (1984) J Am Chem Soc 106:6092

    CAS  Google Scholar 

  15. Martens JA, Jacobs PA (1994) Stud Surf Sci Catal 85:653

    CAS  Google Scholar 

  16. Rabo JA, Pickert PE, Stamires DN, Boyle JE (1960) Actes Du Deuxieme Congres International De Catalyse. Paris, p 2055

    Google Scholar 

  17. Weisz PB, Frilette VJ (1960) J Phys Chem 64:342

    Google Scholar 

  18. Curtiss LA, Brand H, Nicholas JB, Iton LE (1991) Chem Phys Lett 184:215

    CAS  Google Scholar 

  19. Brunner E (1995) J Mol Struct 355:61

    CAS  Google Scholar 

  20. Haag WO, Lago RM, Weisz PB (1984) Nature 309:589

    CAS  Google Scholar 

  21. Ward JW (1970) J Catal 17:355

    CAS  Google Scholar 

  22. Tsutsumi K, Takahashi H (1972) J Catal 24:1

    CAS  Google Scholar 

  23. Beaumont R, Barthomeuf D (1972) J Catal 26:218

    CAS  Google Scholar 

  24. Sanderson RT (1976) Chemical bonds and bond energy. Academic, New York

    Google Scholar 

  25. Jacobs PA (1982) Catal Rev-Sci Eng 24:415

    CAS  Google Scholar 

  26. Jacobs PA, Mortier WJ (1982) Zeolites 2:226

    CAS  Google Scholar 

  27. Pelmenschikov AG, Paukshtis EA, Stepanov VG, Pavlov VI, Yurchenko EN, Ione KG, Zhidomirov GM (1989) J Phys Chem 93:6725

    Google Scholar 

  28. Kramer GJ, van Santen RA (1993) J Am Chem Soc 115:2887

    CAS  Google Scholar 

  29. Schröder K-P, Sauer J, Leslie M, Catlow CRA, Thomas JM (1992) Chem Phys Lett 188:320

    Google Scholar 

  30. Eichler U, Brändle M, Sauer J (1997) J Phys Chem B 101:10035

    CAS  Google Scholar 

  31. Hopkins PD (1968) J Catal 12:325

    CAS  Google Scholar 

  32. Lunsford JH (1968) J Phys Chem 72:4163

    CAS  Google Scholar 

  33. Mirodatos C, Barthomeuf D (1981) J Chem Soc Chem Commun, p 39

    Google Scholar 

  34. Lago RM, Haag WO, Mikovsky RJ, Olson DH, Hellring SD, Schmitt KD, Kerr GT (1986) Stud Surf Sci Catal 28:677

    CAS  Google Scholar 

  35. Brunner E, Ernst H, Freude D, Hunger M, Krause CB, Prager D, Reschetilowski W, Schwieger W, Bergk K-H (1989) Zeolites 9:282

    CAS  Google Scholar 

  36. Brunner E, Beck K, Koch M, Pfeifer H, Staudte B, Zscherpel D (1994) Stud Surf Sci Catal 84:357

    CAS  Google Scholar 

  37. Zholobenko VL, Kustov LM, Kazansky VB, Loeffler E, Lohse U, Peuker C, Oehlmann G (1990) Zeolites 10:304

    CAS  Google Scholar 

  38. Fritz PO, Lunsford JH (1989) J Catal 118:85

    CAS  Google Scholar 

  39. Freude D, Hunger M, Pfeifer H (1982) Chem Phys Lett 91:307

    CAS  Google Scholar 

  40. Freude D, Hunger M, Pfeifer H, Scheler G, Hoffmann J, Schmitz W (1984) Chem Phys Lett 105:427

    CAS  Google Scholar 

  41. Pfeifer H, Freude D, Hunger M (1985) Zeolites 5:274

    CAS  Google Scholar 

  42. Freude D, Hunger M, Pfeifer H (1987) Z Phys Chemie NF 152:171

    CAS  Google Scholar 

  43. Engelhardt G, Jerschkewitz H-G, Lohse U, Sarv P, Samoson A, Lippmaa E (1987) Zeolites 7:289

    CAS  Google Scholar 

  44. Brunner E, Ernst H, Freude D, Hunger M, Pfeifer H (1988) Stud Surf Sci Catal 37:155

    CAS  Google Scholar 

  45. Pfeifer H, Ernst H (1994) Ann Rep NMR Spectrosc 28:91

    CAS  Google Scholar 

  46. Pfeifer H (1994) NMR of solid surfaces. In: Diehl P, Fluck E, Günther H, Kosfeld R, Seelig J (eds) NMR basic principles and progress, vol 31. Springer, Berlin, p 31

    Google Scholar 

  47. Hunger M (1996) Solid State Nucl Magn Reson 6:1

    CAS  Google Scholar 

  48. Vega AJ, Luz Z (1987) J Phys Chem 91:365

    CAS  Google Scholar 

  49. Gluszak TJ, Chen DT, Sharma SB, Dumesic JA, Root TW (1992) Chem Phys Lett 190:36

    CAS  Google Scholar 

  50. Ernst H, Freude D, Wolf I (1993) Chem Phys Lett 212:588

    CAS  Google Scholar 

  51. Freude D, Ernst H, Wolf I (1994) Solid State Nucl Magn Reson 3:271

    CAS  Google Scholar 

  52. Andrew ER, Bradbury A, Eades RG (1958) Nature (London) 182:1659

    CAS  Google Scholar 

  53. Haeberlen U, Waugh JS (1968) Phys Rev 175:453

    CAS  Google Scholar 

  54. Schnabel B, Haubenreisser U, Scheler G, Müller R (1976) In: Brunner H, Hausser KH, Schweitzer D (eds) Proceedings 19th Congress Ampere. Heidelberg, 27 Sept–1 Oct 1976. Groupement Ampere, Geneva, p 441

    Google Scholar 

  55. Pembleton RG, Ryan LM, Gerstein BC (1977) Rev Sci Instrum 48:1286

    CAS  Google Scholar 

  56. Ryan LM, Taylor RE, Paff AJ, Gerstein BC (1980) J Chem Phys 72:508

    CAS  Google Scholar 

  57. Scheler G, Haubenreisser U, Rosenberger H (1981) J Magn Reson 44:134

    CAS  Google Scholar 

  58. Maricq MM, Waugh JS (1979) J Chem Phys 70:3300

    CAS  Google Scholar 

  59. Brunner E, Freude D, Gerstein BC, Pfeifer H (1990) J Magn Reson 90:90

    CAS  Google Scholar 

  60. Brunner E, Fenzke D, Freude D, Pfeifer H (1990) Chem Phys Lett 169:591

    CAS  Google Scholar 

  61. Brunner E (1990) J Chem Soc Faraday Trans 86:3957

    CAS  Google Scholar 

  62. Brunner E (1993) J Chem Soc Faraday Trans 89:165

    CAS  Google Scholar 

  63. Wind R (1991) In: Popov AF, Hallenga K (eds) Modern NMR techniques and their application in chemistry. Dekker, New York, p 125

    Google Scholar 

  64. Stevenson RL (1971) J Catal 21:113

    CAS  Google Scholar 

  65. Freude D, Klinowski J, Hamdan H (1988) Chem Phys Lett 149:355

    CAS  Google Scholar 

  66. Kaplan DE, Hahn EL (1958) Le Journal de Physique et le Radium 19:821

    Google Scholar 

  67. Slichter CP (1978) Principles of magnetic resonance, 2nd edn. Springer, Berlin

    Google Scholar 

  68. Wang P-K, Slichter CP, Sinfelt JH (1984) Phys Rev Lett 53:82

    CAS  Google Scholar 

  69. Kenaston NP, Bell AT, Reimer JA (1994) J Phys Chem 98:894

    CAS  Google Scholar 

  70. Fenzke D, Hunger M, Pfeifer H (1991) J Magn Reson 95:477

    CAS  Google Scholar 

  71. Zscherpel D, Brunner E, Koch M (1995) Z Phys Chem 190:123

    CAS  Google Scholar 

  72. Liu H, Kao H-M, Grey C (1999) J Phys Chem B 103:4786

    CAS  Google Scholar 

  73. Freude D, Pfeifer H (1980) In: Rees LVC (ed) Proceedings 5th international zeolite conference. Heyden, London, p 732

    Google Scholar 

  74. Andrew ER, Jasinski A (1971) J Phys C: Solid State Phys 4:391

    CAS  Google Scholar 

  75. Fenzke D, Gerstein BC, Pfeifer H (1992) J Magn Reson 98:469

    CAS  Google Scholar 

  76. Sarv P, Tuherm T, Lippmaa E, Keskinen K, Root A (1995) J Phys Chem 99:13763

    CAS  Google Scholar 

  77. Baba T, Inoue Y, Shoji H, Uematsu T, Ono Y (1995) Microporous Mater 3:647

    CAS  Google Scholar 

  78. Baba T, Komatsu N, Ono Y, Sugisawa H, Takahashi T (1998) Microporous Mesoporous Mater 22:203

    CAS  Google Scholar 

  79. Baba T, Ono Y (1999) Appl Catal A: General 181:227

    CAS  Google Scholar 

  80. Sauer J (1987) Mol Catal 54:312

    Google Scholar 

  81. Fleischer U, Kutzelnigg W, Bleiber A, Sauer J (1993) J Am Chem Soc 115:7833

    CAS  Google Scholar 

  82. Brunner E, Pfeifer H (1995) Z Phys Chemie 192:77

    CAS  Google Scholar 

  83. Sauer J (1994) Stud Surf Sci Catal 84:2039

    CAS  Google Scholar 

  84. Sauer J, Hill J-R (1994) Chem Phys Lett 218:333

    CAS  Google Scholar 

  85. Paukshtis EA, Yurchenko EN (1983) Usp Khim 52:426

    Google Scholar 

  86. Paukshtis EA, Yurchenko EN (1981) React Kinet Catal Lett 16:131

    Google Scholar 

  87. Hunger M, Ernst S, Steuernagel S, Weitkamp J (1996) Microporous Mater 6:349

    CAS  Google Scholar 

  88. Hunger B, von Szombathely M (1995) Z Phys Chemie 190:19

    CAS  Google Scholar 

  89. Brunner E, Karge HG, Pfeifer H (1992) Z Phys Chemie 176:173

    CAS  Google Scholar 

  90. Beck LW, White JL, Haw JF (1994) J Am Chem Soc 116:9657

    CAS  Google Scholar 

  91. Brunner E, Beck K, Koch M, Heeribout L, Karge HG (1995) Microporous Mater 3:395

    CAS  Google Scholar 

  92. Zholobenko VL, Kustov LM, Borovkov VY, Kazansky VB (1988) Zeolites 8:175

    CAS  Google Scholar 

  93. Berglund B, Vaughan RW (1980) J Chem Phys 73:2037

    CAS  Google Scholar 

  94. Sternberg U, Brunner E (1994) J Magn Reson A 108:142

    CAS  Google Scholar 

  95. Koch M, Brunner E, Fenzke D, Pfeifer H, Staudte B (1994) Stud Surf Sci Catal 84:709

    CAS  Google Scholar 

  96. White JL, Beck LW, Haw JF (1992) J Am Chem Soc 114:6182

    CAS  Google Scholar 

  97. Kubelková L, Beran S, Lercher JA (1989) Zeolites 9:539

    Google Scholar 

  98. Kustov LM, Kazansky VB, Beran S, Kubelková L, Jirù P (1987) J Phys Chem 91:5247

    CAS  Google Scholar 

  99. Mirsojew I, Ernst S, Weitkamp J, Knözinger H (1994) Catal Lett 24:235

    CAS  Google Scholar 

  100. Brunner E (1995) Stud Surf Sci Catal 97:11

    CAS  Google Scholar 

  101. Sachsenröder H, Brunner E, Koch M, Pfeifer H, Staudte B (1996) Microporous Mater 6:341

    Google Scholar 

  102. Jänchen J, van Wolput JHMC, van de Ven LJM, de Haan JW, van Santen RA (1996) Catal Lett 39:147

    Google Scholar 

  103. Maciel GE, Haw JF, Chuang I-S, Hawkins BL, Early TA, McKay DR, Petrakis L (1983) J Am Chem Soc 105:5529

    CAS  Google Scholar 

  104. Ripmeester JA (1983) J Am Chem Soc 105:2925

    CAS  Google Scholar 

  105. Pines A, Gibby MG, Waugh JS (1973) J Chem Phys 59:569

    CAS  Google Scholar 

  106. Mehring M (1983) High resolution NMR in solids, 2nd edn. Springer, Berlin

    Google Scholar 

  107. Schulze D, Ernst H, Fenzke D, Meiler W, Pfeifer H (1990) J Phys Chem 94:3499

    CAS  Google Scholar 

  108. Lunsford JH, Rothwell WP, Shen W (1985) J Am Chem Soc 107:1540

    CAS  Google Scholar 

  109. Lunsford JH, Tutunjian PN, Chu P-J, Yeh EB, Zalewski DJ (1989) J Phys Chem 93:2590

    CAS  Google Scholar 

  110. Baltusis L, Frye JS, Maciel GE (1987) J Am Chem Soc 109:40

    CAS  Google Scholar 

  111. Peng L, Chupas PJ, Grey CP (2004) J Am Chem Soc 126:12254

    CAS  Google Scholar 

  112. Haase F, Sauer J (1994) J Phys Chem 98:3083

    CAS  Google Scholar 

  113. Krossner M, Sauer J (1996) J Phys Chem 100:6199

    CAS  Google Scholar 

  114. Batamack P, Dorémieux-Morin C, Vincent R, Fraissard J (1991) Chem Phys Lett 180:545

    CAS  Google Scholar 

  115. Batamack P, Dorémieux-Morin C, Fraissard J, Freude D (1991) J Phys Chem 95:3790

    CAS  Google Scholar 

  116. Batamack P, Dorémieux-Morin C, Vincent R, Fraissard J (1993) J Phys Chem 97:9779

    CAS  Google Scholar 

  117. Hirschler AE (1963) J Catal 2:428

    CAS  Google Scholar 

  118. Plank CJ (1964) In: Sachtler WMH, Schuit GCA, Zwietering P (eds) Proceedings 3rd international congress on catalysis, Amsterdam, 1964. North-Holland, Amsterdam

    Google Scholar 

  119. Hunger M, Freude D, Pfeifer H (1991) J Chem Soc Faraday Trans 87:657

    CAS  Google Scholar 

  120. Heeribout L, Dorémieux-Morin C, Nogier J-P, Vincent R, Fraissard J (1998) Microporous Mesoporous Mater 24:101

    CAS  Google Scholar 

  121. Gale JD, Catlow CRA, Carruthers JR (1993) Chem Phys Lett 216:155

    CAS  Google Scholar 

  122. Bates S, Dwyer J (1994) J Mol Struct (Theochem) 306:57

    Google Scholar 

  123. Haase F, Sauer J (1995) J Am Chem Soc 117:3780

    CAS  Google Scholar 

  124. Luz Z, Vega AJ (1987) J Phys Chem 91:374

    CAS  Google Scholar 

  125. Hunger M, Horvath T (1995) Ber Bunsenges Phys Chem 99:1316

    CAS  Google Scholar 

  126. Thursfield A, Anderson MW (1996) J Phys Chem 100:6698

    CAS  Google Scholar 

  127. Biaglow AI, Gorte RJ, Kokotailo GT, White D (1994) J Catal 148:779

    CAS  Google Scholar 

  128. Haw JF, Hall MB, Alvarado-Swaisgood AE, Munson EJ, Lin Z, Beck LW, Howard T (1994) J Am Chem Soc 116:7308

    CAS  Google Scholar 

  129. Nicholas JB, Haw JF, Beck LW, Krawietz TR, Ferguson DB (1995) J Am Chem Soc 117:12350

    CAS  Google Scholar 

  130. Mildner T, Freude D (1998) J Catal 178:309

    CAS  Google Scholar 

  131. Beeler AJ, Orendt AM, Grant DM, Cutts PW, Michl J, Zilm KW, Downing JW, Facelli JC, Schindler MS, Kutzelnigg W (1984) J Am Chem Soc 106:7672

    CAS  Google Scholar 

  132. Koch M, Brunner E, Pfeifer H, Zscherpel D (1994) Chem Phys Lett 228:501

    CAS  Google Scholar 

  133. Geerlings P, Tariel N, Botrel A, Lissillour R, Mortier WJ (1984) J Phys Chem 88:5752

    CAS  Google Scholar 

  134. Bates S, Dwyer J (1993) J Phys Chem 97:5897

    CAS  Google Scholar 

  135. Neyman KM, Strodel P, Ruzankin SP, Schlensog N, Knözinger H, Rösch N (1995) Catal Lett 31:273

    CAS  Google Scholar 

  136. Farnworth KJ, O'Malley PJ (1996) J Phys Chem 100:1814

    CAS  Google Scholar 

  137. Gullion T, Schaefer J (1989) J Magn Reson 81:196

    CAS  Google Scholar 

  138. Koch M (1996) Thesis, University of Leipzig

    Google Scholar 

  139. Kao H-M, Grey CP (1996) J Phys Chem 100:5105

    CAS  Google Scholar 

  140. Dwyer J (1987) Stud Surf Sci Catal 37:333

    Google Scholar 

  141. Karge HG (1991) Stud Surf Sci Catal 65:133

    CAS  Google Scholar 

  142. Engelhardt G, Michel D (1987) High-resolution solid-state NMR of silicates and zeolites. Wiley, Chichester

    Google Scholar 

  143. Lippmaa E, Samoson A, Mägi M (1986) J Am Chem Soc 108:1730

    CAS  Google Scholar 

  144. Kerr GT (1969) J Catal 15:200

    CAS  Google Scholar 

  145. Samoson A, Lippmaa E, Engelhardt G, Lohse U, Jerschkewitz H-G (1987) Chem Phys Lett 134:589

    CAS  Google Scholar 

  146. Grobet PJ, Geerts H, Tielen M, Martens JA, Jacobs PA (1989) Stud Surf Sci Catal 46:721

    Google Scholar 

  147. Kellberg L, Linsten M, Jacobsen HJ (1991) Chem Phys Lett 182:120

    CAS  Google Scholar 

  148. Gilson JP, Edwards GC, Peters AW, Rajagopalan K, Wormsbecher RF, Roberie TG, Shatlock MP (1987) J Chem Soc Chem Commun, p 91

    Google Scholar 

  149. Ray GJ, Samoson A (1993) Zeolites 13:410

    CAS  Google Scholar 

  150. Frydman L, Harwood JS (1995) J Am Chem Soc 117:5367

    CAS  Google Scholar 

  151. Menezes SMC, Camorim VL, Lam YL, San Gil RAS, Bailly A, Amoureux JP (2001) Appl Catal A: General 207:367

    CAS  Google Scholar 

  152. Müller D, Gessner W, Behrens H-J, Scheler G (1981) Chem Phys Lett 79:59

    Google Scholar 

  153. Freude D, Haase J (1993) Quadrupole effects in solid-state nuclear magnetic resonance. In: Diehl P, Fluck E, Günther H, Kosfeld R, Seelig J (eds) NMR basic principles and progress, vol 29. Springer, Berlin, p 1

    Google Scholar 

  154. Samoson A, Lippmaa E, Pines A (1988) Mol Phys 65:1013

    CAS  Google Scholar 

  155. Samoson A, Lippmaa E (1989) J Magn Reson 84:410

    CAS  Google Scholar 

  156. Samoson A, Pines A (1989) Rev Sci Instrum 60:3239

    CAS  Google Scholar 

  157. Woessner DE, Timken HKC (1990) J Magn Reson 90:411

    CAS  Google Scholar 

  158. Ehresmann JO, Wang W, Herreros B, Luigi D-P, Venkatraman TN, Song W, Nicholas JB, Haw JF (2002) J Am Chem Soc 124:10868

    CAS  Google Scholar 

  159. Majors PD, Ellis PD (1987) J Am Chem Soc 109:1648

    CAS  Google Scholar 

  160. Kao H-M, Grey CP (1996) Chem Phys Lett 259:459

    CAS  Google Scholar 

  161. Michael A, Meiler W, Michel D, Pfeifer H (1981) Chem Phys Lett 84:30

    CAS  Google Scholar 

  162. Michael A, Meiler W, Michel D, Pfeifer H, Hoppach D, Delmau J (1986) J Chem Soc Faraday Trans I 82:3053

    CAS  Google Scholar 

  163. Wutscherk T (1990) Thesis, University of Leipzig

    Google Scholar 

  164. Brunner E, Pfeifer H, Wutscherk T, Zscherpel D (1992) Z Phys Chemie 178:173

    CAS  Google Scholar 

  165. Zscherpel D, Brunner E, Koch M, Pfeifer H (1995) Microporous Mater 4:141

    Google Scholar 

  166. Mastikhin VM, Mudrakovsky IL, Filimonova SV (1988) Chem Phys Lett 149:175

    CAS  Google Scholar 

  167. Borovkov VJ, Zhidomirov GM, Kazansky VB (1975) Zhurn Strukt Chim 16:308

    CAS  Google Scholar 

  168. Swift TJ, Connick RE (1962) J Chem Phys 37:307

    CAS  Google Scholar 

  169. Ettinger R, Blume P, Patterson A Jr, Lauterbur PC (1960) J Chem Phys 33:1597

    CAS  Google Scholar 

  170. Forsén S, Hoffman R (1963) J Chem Phys 39:2892

    Google Scholar 

  171. Hattori H (1995) Chem Rev 95:537

    CAS  Google Scholar 

  172. Barthomeuf D (1996) In: Weitkamp J, Lücke B (eds) Proceedings of the DGMK-conference: catalysis on solid acids and bases. Berlin, 14–15 March 1996. DGMK Hamburg, p 65

    Google Scholar 

  173. Huang M, Adnot A, Kaliaguine S (1992) J Am Chem Soc 114:10005

    CAS  Google Scholar 

  174. Uytterhoeven L, Dompas D, Mortier W (1992) J Chem Soc Faraday Trans 88:2753

    CAS  Google Scholar 

  175. Huang M, Kaliaguine S (1992) J Chem Soc Faraday Trans 88:751

    CAS  Google Scholar 

  176. Mueller KT, Baltisberger JH, Wooten EW, Pines A (1992) J Phys Chem 96:7001

    CAS  Google Scholar 

  177. Grandinetti PJ, Baltisberger JH, Farnan I, Stebbins JF, Werner U, Pines A (1995) J Phys Chem 99:12341

    CAS  Google Scholar 

  178. Bull LM, Cheetham AK, Anupold T, Reinhold A, Samoson A, Sauer J, Bussemer B, Lee Y, Gann S, Shore J, Pines A, Dupree R (1998) J Am Chem Soc 120:3510

    CAS  Google Scholar 

  179. Amoureux J-P, Bauer F, Ernst H, Fernandez C, Freude D, Michel D, Pingel U-T (1998) Chem Phys Lett 285:10

    CAS  Google Scholar 

  180. Bull LM, Bussemer B, Anupold T, Reinhold A, Samoson A, Sauer J, Cheetham AK, Dupree R (2000) J Am Chem Soc 122:4948

    CAS  Google Scholar 

  181. Freude D, Loeser T, Michel D, Pingel U, Prochnow D (2001) Sol State Nucl Magn Reson 20:46

    CAS  Google Scholar 

  182. Readman JE, Kim N, Ziliox M, Grey CP (2002) Chem Commun, p 2808

    Google Scholar 

  183. Bosácek V (1993) J Phys Chem 97:10732

    Google Scholar 

  184. Kheir AA, Haw JF (1994) J Am Chem Soc 116:817

    CAS  Google Scholar 

  185. Lima E, Lasperas M, de Menorval L-C, Tichit D, Fajula F (2004) J Catal 223:28

    CAS  Google Scholar 

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  1. Fachrichtung Chemie und Lebensmittelchemie, Bioanalytische Chemie, Technische Universität Dresden, 01062, Dresden, Germany

    Eike Brunner

  2. Universität Leipzig, Fakultät für Physik und Geowissenschaften, Linnéstraße 5, 04103, Leipzig, Germany

    Harry Pfeifer

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Brunner, E., Pfeifer, H. (2007). NMR Spectroscopic Techniques for Determining Acidity and Basicity. In: Acidity and Basicity. Molecular Sieves, vol 6. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3829_2007_016

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