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Crystal and magnetic structures of ternary metal hydrides: A comprehensive review

  • Klaus Yvon
  • Peter Fischer
Chapter
Part of the Topics in Applied Physics book series (TAP, volume 63)

Abstract

The crystal and magnetic structures of hydrides and deuterides of binary metal compounds as determined by neutron diffraction analysis are reviewed. Emphasis is placed on the distribution of hydrogen (deuterium) atoms in the metal atom host structure. At room temperature these distributions are characterized by thermal disorder and preferential occupation of large interstices which are surrounded by atoms belonging to hydride forming elements. The metal atom arrangements are usually similar to those of the binary metal compounds, except that their lattices are generally expanded and their symmetries reduced. At low temperatures the hydrogen (deuterium) atoms tend to order, thus inducing structural phase transitions and further symmetry lowering. Efforts to rationalize observed hydrogen (deuterium) site occupancies and maximum hydrogen (deuterium) contents in terms of empirical models are reviewed. The influence of hydrogenation (deuteration) on the magnetic structures is discussed.

Keywords

Metal Atom Neutron Diffraction Magnetic Structure Metal Hydride Neutron Diffraction Experiment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 4.1
    K. Yvon: J. Less-Common Met. 103, 53 (1984)Google Scholar
  2. 4.2
    Y. Noda, T. Kajitani, M. Hirabayashi, S. Sato: Acta Crystallogr. C 41, 1566 (1985)Google Scholar
  3. 4.3
    R.A. Alikhanov, V.I. Buzin, N.I. Kulikov, M.E. Kost, W. Sikora, L.S. Smirnov: J. LessCommon Met. 101, 291 (1984)Google Scholar
  4. 4.4
    R.R. Arons, J.W. Cable: Sol. State Commun. 55, 835 (1985)Google Scholar
  5. 4.5
    B. Lebech, N. Hessel-Andersen, S. Steenstrup, A. Schroeder Pedersen: Acta Cryst. C39, 1475 (1983Google Scholar
  6. 4.5a
    P. Fischer, J. Schefer, K. Tichy, R. Bischof, E. Kaldis: J. Less-Common Met. 94, 151 (1983)Google Scholar
  7. 4.6
    W. Bartscher, A. Boeuf, R. Caciuffo, J.M. Fournier, W.F. Kuhs, J. Rebizant, F. Rustichelli: Solid State Commun. 53, 423 (1985)Google Scholar
  8. 4.7
    W. Bartscher, A. Boeuf, R. Caciuffo, J.M. Fournier, J.M. Haschke, L. Manes, J. Rebizant, F. Rustichelli, J.W. Ward: Physica 130B, 530 (1985)Google Scholar
  9. 4.8
    H. Nagel, R.S. Perkins: Z. Metallkd. 66, 362 (1975)Google Scholar
  10. 4.9.
    H. Kaneko, T. Kajitani, M. Hirabayashi, M. Ueno, K. Suzuki: J. Less-Common Met. 89, 237 (1983)Google Scholar
  11. 4.10
    B. Rodmacq, Ph. Mangin, A. Chamberod: J. Phys. F: Met. Phys. 15, 2259 (1985)Google Scholar
  12. 4.11
    A.J. Maeland, A.F. Andresen: J. Chem. Phys. 48, 4660 (1968)Google Scholar
  13. 4.12
    S.C. Abrahams, A.P. Ginsberg, K. Knox: Inorg. Chem. 3, 558 (1964)Google Scholar
  14. 4.12a
    S.C. Abrahams, K. Knox: J. Phys. 25, 461 (1964)Google Scholar
  15. 4.13
    A.N. Fitch, S.A. Barrett, B.E.F. Fender, A. Simon: J. Chem. Soc. Dalton Trans. 4, 501 (1984)Google Scholar
  16. 4.14
    S.D. Wijeyesekera, J.D. Corbett: Solid State Commun. 54, 657 (1985)Google Scholar
  17. 4.15
    H.J. Mattausch, A. Simon, K. Ziebeck: J. Less-Common Met. 113, 149 (1985)Google Scholar
  18. 4.16
    G. Bandel, M. Müllner, M. Trömel: Z. Anorg. Allg. Chem. 453, 5 (1979)Google Scholar
  19. 4.17
    J.M. Newsam, A.K. Cheetham, B.C. Tofield: Solid State Chem. 60, 214 (1985)Google Scholar
  20. 4.18
    C. Greaves: J. Appl. Cryst. 18, 48 (1985)Google Scholar
  21. 4.18a
    C. Greaves, M.A. Thomas: Acta Cryst. B 42, 51 (1986)Google Scholar
  22. 4.19
    M.T. Weller, P.G. Dickens: J. Solid State Chem. 58, 164 (1985)Google Scholar
  23. 4.20
    I.S. Latergaus, V.T. Em, I. Karimov, D.Ya. Khvatinskaya, S.K. Dolukhanyan: Inorg. Mat. 20, 1420 (1984)Google Scholar
  24. 4.21
    S. Mukawa, T. Kajitani, M. Hirabayashi: J. Less-Common Met. 103, 19 (1984)Google Scholar
  25. 4.22
    R.O. Moyer, Jr., C. Stanitski, J. Tanaka, M.I. Kay, R. Kleinberg: J. Solid State Chem. 3, 541 (1971)Google Scholar
  26. 4.23
    W. Bronger, G. Auffermann, P. Müller: J. Less-Common Met. 116, 9 (1986)Google Scholar
  27. 4.24
    G.G. Libowitz: The Solid-State Chemistry of Binary Metal Hydrides (W.A. Benjamin, Inc., New York, Amsterdam 1965)Google Scholar
  28. 4.25
    W.M. Mueller, J.P. Blackledge, G.G. Libowitz: Metal Hydrides (Academic, NewYork, London 1968)Google Scholar
  29. 4.26
    P. Eckerlin, H. Kandler: in Landolt-Börnstein, Vol. 6 Structure Data of Elements and Intermetallic Phases, ed. by K.-H. Hellwege, A.M. Hellwege (Springer, Berlin, Heidelberg 1971) pp. 138–174Google Scholar
  30. 4.27
    R.R. Arons et al.: In Landolt-Börnstein III, Vol. 12c (Springer, Berlin, Heidelberg 1982) pp. 372–405Google Scholar
  31. 4.28
    H. Asano, M. Hirabayashi: Z. Phys. Chem. NF 114, 1 (1979)Google Scholar
  32. 4.28a
    H. Asano, M. Hirabayashi: In Metal Hydrides, ed. by G. Bambakidis (Plenum, New York 1981) pp. 81–103Google Scholar
  33. 4.28b
    M. Hirabayashi, H. Asano: ibid. pp. 53–80Google Scholar
  34. 4.29
    J.W. Ward: Physica 130B, 510 (1985)Google Scholar
  35. 4.30
    R.G. Teller, R. Bau: In Structure and Bonding, Vol. 44, pp. 1–82 (Springer, Berlin, Heidelberg, New York 1981); see alsoGoogle Scholar
  36. 4.30a
    R. Bau, M.Y. Chiang, D.M. Ho, S.G. Gibbins, T.J. Emge, T.F. Koetzle: Inorg. Chem. 23, 2823 (1984)Google Scholar
  37. 4.31
    S. Rundqvist, R. Tellgren, Y. Andersson: J. Less-Common Met. 101, 145 (1984)Google Scholar
  38. 4.32
    A.F. Andresen: In Hydrides for Energy Storage, ed. by A.F. Andresen, A.J. Maeland (Pergamon, Oxford 1978) pp. 61–72Google Scholar
  39. 4.33
    A.F. Andresen: J. Less-Common Met. 88, 1 (1982)Google Scholar
  40. 4.34
    K.N. Semenenko, V.V. Burnasheva: J. Less-Common Met. 105, 1 (1985)Google Scholar
  41. 4.35
    A. Percheron-Guégan, C. Lartigue, J.C. Achard: J. Less-Common Met. 109, 287 (1985)Google Scholar
  42. 4.36
    G.D. Sandrock: In Hydrides for Energy Storage, ed. by A.F. Andresen, A.J. Maeland (Pergamon, Oxford 1978) pp. 353–393Google Scholar
  43. 4.37
    H. Oesterreicher: Appl. Phys. 24, 169 (1981)Google Scholar
  44. 4.38
    G.K. Shenoy, B.D. Dunlap, P.J. Viccaro, D. Niarchos: Adv. Chem. Series No. 194, ed. by J.G. Stevens, G.K. Shenoy, Chap. 23, pp. 501–521 (1981)Google Scholar
  45. 4.39
    H. Buchner: Energiespeicherung in Metallhydriden (Springer, Wien, New York 1982)Google Scholar
  46. 4.40
    K.H.J. Buschow, P.C.P. Bouten, A.R. Miedema: Rep. Prog. Phys. 45, 937 (1982)Google Scholar
  47. 4.41
    D.G. Ivey, D.O. Northwood: J. Mater. Sci. 18, 321 (1983)Google Scholar
  48. 4.42
    K.H.J. Buschow: In Handbook on the Physics and Chemistry of Rare Earths, Vol. 6, Chap. 47, ed. by K.A. Gschneider, Jr., L. Eyring (Elsevier, Amsterdam 1984)Google Scholar
  49. 4.43
    Proceedings of the International Symposium on the Properties and Applications of Metal Hydrides: J. Less-Common Met. Vols. 73 and 74 (1980), 88 (1982); 89 (1983); 101, 103, and 104 (1984); 129, 130, and 131 (1987)1Google Scholar
  50. 4.44
    International Tables for Crystallography, Vol. A (D. Reidel, Dordrecht 1983)Google Scholar
  51. 4.45
    H. Buchner, M.A. Gutjahr, K.-D. Beccu, H. Sdufferer: Z. Metallkde. 63, 497 (1972)Google Scholar
  52. 4.46
    C. Stioui, D. Fruchart, A. Rouault, R. Fruchart, E. Roudaut, J. Rebihre: Mat. Res. Bull. 16, 869 (1981)Google Scholar
  53. 4.47
    F.J. Rotella, H.E. Flotow, D.M. Gruen, J.D. Jorgensen: J. Chem. Phys. 79, 4522 (1983)Google Scholar
  54. 4.48
    J.-J. Didisheim, K. Yvon, P. Fischer, D. Shaltiel: J. Less-Common Met. 73, 355 (1980)Google Scholar
  55. 4.49
    J.-J. Didisheim, K. Yvon, P. Fischer, P. Tissot: Solid State Commun. 38, 637 (1981)Google Scholar
  56. 4.50
    J.-J. Didisheim, K. Yvon, D. Shaltiel, P. Fischer, P. Bujard, E. Walker: Solid State Commun. 32, 1087 (1979)Google Scholar
  57. 4.51
    D. Fruchart, A. Rouault, C.B. Shoemaker, D.P. Shoemaker: J. Less-Common Met. 73, 363 (1980); Phys. Status Solidi a 57, K119 (1980)Google Scholar
  58. 4.52
    A.V. Irodova, V.P. Glazkov, V.A. Somenkov, S.Sh. Shilstein: J. Less-Common Met. 77, 89 (1981); Sov. Phys. Solid State 22, 45 (1980)Google Scholar
  59. 4.53
    V.A. Yartys', V.V. Burnasheva, K.N. Semenenko, N.V. Fadeeva, S.P. Solov'ev: Int. J. Hydrogen Energy 7, 957 (1982)Google Scholar
  60. 4.53a
    V.A. Yartys', V.V. Burnasheva, S.E. Tsirkunova, E.N. Kozlov, K.N. Semenenko: Sov. Phys. Crystallogr. 27, 148 (1982)Google Scholar
  61. 4.53b
    V.V. Burnasheva, N.V. Fadeeva, K.N. Semenenko, S.P. Solov'ev, V.A. Yartys': Acta Crystallogr. A 37, C–182 (1981)Google Scholar
  62. 4.54
    A.V. Irodova, O.A. Lavrova, G.V. Laskova, L.N. Padurets: Sov. Phys.-Sol. State 24, 22 (1982)Google Scholar
  63. 4.55
    N.F. Miron, V.I. Shcherbak, V.N. Bykov, V.A. Levdik: Sov. Phys.-Crystallogr. 16, 266 (1971)Google Scholar
  64. 4.56
    D. Fruchart, F. Vaillant, A. Rouault, A. Benoit, J. Flouquet: J. Less-Common Met. 101, 285 (1984)Google Scholar
  65. 4.56a
    D. Fruchart, F. Vaillant, E. Roudaut, A. Nemoz, X.G. Tessema: Phys. Status Solidi a 65, K19 (1981)Google Scholar
  66. 4.57
    J.J. Rhyne, S.G. Sankar, W.E. Wallace: In The Rare-Earths in Modern Science and Technology, Vol. 1, ed. by G.J. McCarthy, J.J. Rhyne (Plenum, New York 1978) pp. 63–68Google Scholar
  67. 4.57a
    J.J. Rhyne, G.E. Fish, S.G. Sankar, W.E. Wallace: J. de Phys. 40, C5–209 (1979)Google Scholar
  68. 4.57b
    G.E. Fish, J.J. Ryne, S.G. Sankar, W.E. Wallace: J. Appl. Phys. 50, 2003 (1979)Google Scholar
  69. 4.57c
    G.E. Fish, J.J. Rhyne, T. Brun, P.J. Viccaro, D. Niarchos, B.D. Dunlap, G.K. Shenoy, S.G. Sankar, W.E. Wallace: In The Rare-Earths in Modern Science and Technology, Vol. 2, ed. by G.J. McCarthy, J.J. Rhyne, H.B. Silber (Plenum, New York 1980) pp.569–570Google Scholar
  70. 4.58
    W. Bartscher, J. Rebizant, A. Boeuf, R. Caciuffo, F. Rustichelli, J.M. Fournier, W.F. Kuhs: Proc. Actinides 85, Aix-en-Provence, Sept. 1985. J. Less-Common Met. 121, 455 (1986)Google Scholar
  71. 4.59
    K. Yvon, J. Schefer, F. Stucki: Inorg. Chem. 20, 2776 (1981)Google Scholar
  72. 4.59a
    J. Schefer, P. Fischer, W. Hdlg, F. Stucki, L. Schlapbach, J.J. Dididsheim, K. Yvon, A.F. Andresen: J. Less-Common Met. 74, 65 (1980)Google Scholar
  73. 4.60
    D. Noréus, L.G. Olsson: J. Chem. Phys. 78, 2419 (1983)Google Scholar
  74. 4.61
    J.L. Soubeyroux, D. Fruchart, A. Mikou, M. Pezat, B. Darriet, P. Hagenmuller: Mat. Res. Bull. 19, 969 (1984)Google Scholar
  75. 4.61a
    B. Darriet, J.L. Soubeyroux, M. Pezat, D. Fruchart: J. Less-Common Met. 103, 153 (1984); see also [4.63,99]Google Scholar
  76. 4.62
    D. Noréus, P.-E. Werner: J. Less-Common Met. 97, 215 (1984)Google Scholar
  77. 4.63
    J.L. Soubeyroux, D. Fruchart, A. Mikou, M. Pezat, B. Darriet: Mat. Res. Bull. 19, 1119 (1984)Google Scholar
  78. 4.64
    P. Zolliker, K. Yvon, J.D. Jorgensen, F. Rotella: Inorg. Chem. 25, 3590 (1986)Google Scholar
  79. 4.65
    P. Zolliker, K. Yvon, P. Fischer, J. Schefer: Inorg. Chem. 24, 4177 (1985)Google Scholar
  80. 4.66
    J.-J. Didisheim, P. Zolliker, K. Yvon, P. Fischer, J. Schefer, M. Gubelmann, A.F. Williams: Inorg. Chem. 23, 1953 (1984)Google Scholar
  81. 4.66a
    J.-J. Didisheim, K. Yvon, P. Fischer, J. Schefer, M. Gubelmann, A.F. Williams: Z. Kristallogr. 162, 61 (1983)Google Scholar
  82. 4.67
    M. Commandre, D. Fruchart, A. Rouault, D. Sauvage, C.B. Shoemaker, D.P. Shoemaker: J. de Phys. 40, L639 (1979)Google Scholar
  83. 4.68
    C. Crowder, B. Kebe, W.J. James, W. Yelon: In The Rare-Earths in Modern Science and Technology, Vol. 3, ed. by G.J. McCarthy, H.B. Silber, J.J. Rhyne (Plenum, New York 1982) pp. 473–476; for work on Er6Mn23D23 see: Amer. Inst. Phys. Conf. Proc. 89, 318 (1982)Google Scholar
  84. 4.69
    K. Hardman-Rhyne, J.J. Rhyne, E. Prince, C. Crowder, W.J. James: Phys. Rev. B 29, 416 (1984)Google Scholar
  85. 4.70
    K. Hardman, J.J. Rhyne, E. Prince, H.K. Smith, S.K. Malik, W.E. Wallace: In The RareEarths in Modern Science and Technology, Vol. 3, ed. by G.J. McCarthy, H.B. Silber, J.J. Rhyne (Plenum, New York 1982) pp. 477–478Google Scholar
  86. 4.70a
    K. Hardman, J.J. Rhyne, H.K. Smith, W.E. Wallace, S.K. Malik: J. Appl. Phys. 52, 2070 (1981)Google Scholar
  87. 4.71
    K. Hardman-Rhyne, H.K. Smith, W.E. Wallace: J. Less-Common Met. 96, 201 (1984)Google Scholar
  88. 4.71a
    K. Hardman, J.J. Rhyne, K. Smith, W.E. Wallace: J. Less-Common Met. 74, 97 (1980)Google Scholar
  89. 4.72
    J.J. Rhyne, K. Hardman-Rhyne, H.K. Smith, W.E. Wallace: J. Less-Common Met. 94, 95 (1983)Google Scholar
  90. 4.73
    P. Thompson, F. Reidinger, J.J. Reilly, L.M. Corliss, J.M. Hastings: J. Phys. F: Met. Phys. 10, L57 (1980)Google Scholar
  91. 4.74
    P. Thompson, M.A. Pick, F. Reidinger, L.M. Corliss, J.M. Hastings, J.J. Reilly: J. Phys. F: Met. Phys. 8, L75 (1978)Google Scholar
  92. 4.75
    P. Fischer, W. Hälg, L. Schlapbach, F. Stucki, A.F. Andresen: Mat. Res. Bull. 13, 931 (1978)Google Scholar
  93. 4.75a
    G. Busch, L. Schlapbach, F. Stucki, P. Fischer, A.F. Andresen: In Hydrogen Energy System, ed. by T.N. Veziroglu, W. Seifritz (Pergamon, Oxford 1979), Vol. 5, pp. 2615–2636; Int. J. Hydrogen Energy 4, 29 (1979)Google Scholar
  94. 4.76
    J. Schefer, P. Fischer, W. Hdlg, F. Stucki, L. Schlapbach, A.F. Andresen: Mat. Res. Bull. 14, 1281 (1979)Google Scholar
  95. 4.76a
    L. Schlapbach, A. Seiler, F. Stucki, P. Zürcher, P. Fischer, J. Schefer: Z. Phys. Chem. NF 117, 205 (1979)Google Scholar
  96. 4.77
    P. Thompson, J.J. Reilly, F. Reidinger, J.M. Hastings, L.M. Corliss: J. Phys. F: Met. Phys. 9, L61 (1979)Google Scholar
  97. 4.78
    W. Schäfer, G. Will, T. Schober: Mat. Res. Bull. 15, 627 (1980)Google Scholar
  98. 4.78a
    W. Schäfer, E. Lebsanft, A. Bläsius: Z. Phys. Chem. NF 115, 201 (1979) see also [4.124]Google Scholar
  99. 4.79
    P. Fischer, J. Schefer, K. Yvon, L. Schlapbach, T. Riesterer: J. Less-Common Met 129, 39 (1986)Google Scholar
  100. 4.80
    D. Fruchart, M. Commandré, D. Sauvage, A. Rouault, R. Tellgren: J. Less-Common Met. 74, 55 (1980)Google Scholar
  101. 4.81
    L.J. Vieland, A.W. Wicklund, J.G. White: Phys. Rev. B 11, 3311 (1975)Google Scholar
  102. 4.82
    A. Furrer, P. Fischer, W. Hdlg, L. Schlapbach: In Hydrides for Energy Storage, ed. by A.F. Andresen, A.J. Maeland (Pergamon, Oxford 1978) pp. 73–82; see also [4.84]Google Scholar
  103. 4.83
    A.L. Bowman, J.L. Anderson, N.G. Nereson: Proceedings of the 10th Rare-Earth Research Conference, Carefree (1973) pp. 485–489Google Scholar
  104. 4.84
    P. Fischer, A. Furrer, G. Busch, L. Schlapbach: Helv. Phys. Acta 50, 421 (1977)Google Scholar
  105. 4.84a
    G. Busch, L. Schlapbach, W. Thoeni, Th. v. Waldkirch, P. Fischer, A. Furrer, W. Hdlg: Proc. 2nd Int. Congress on Hydrogen in Metals (Paris 1977) 1137, pp. 1–8Google Scholar
  106. 4.84b
    P. Fischer, W. Hälg, L. Schlapbach, Th. von Waldkirch: Helv. Phys. Acta 51, 4 (1978); see also [4.82]Google Scholar
  107. 4.85
    D. Noréus, L.G. Olsson, P.-E. Werner: J. Phys. F: Met. Phys. 13, 715 (1983)Google Scholar
  108. 4.86
    A. Percheron-Guégan, C. Lartigue, J.C. Achard, P. Germi, F. Tasset: J. Less-Common Met. 74, 1 (1980)Google Scholar
  109. 4.86a
    C. Lartigue, A. Percheron-Guégan, J.C. Achard, F. Tasset: In The Rare-Earths in Modern Science and Technology, Vol. 2, ed. by G.J. McCarthy, J.J. Rhyne, H.B. Silber (Plenum, New York 1980)Google Scholar
  110. 4.86b
    C. Lartigue, A. Percheron-Guégan, J.C. Achard, F. Tasset: J. Less-Common Met. 75, 23 (1980)Google Scholar
  111. 4.86c
    J.C. Achard, F. Givord, A. Percheron-Guégan, J.L. Soubeyroux, F. Tasset: J. de Phys. 40, C5–218 (1979)Google Scholar
  112. 4.87
    C. Lartigue, A. Percheron-Guégan, J.C. Achard, J.L. Soubeyroux: J. Less-Common Met. 113, 127 (1985)Google Scholar
  113. 4.88
    P. Thompson, J.J. Reilly, L.M. Corliss, J.M. Hastings, R. Hempelmann: J. Phys. F: Met Phys. 16, 679 (1986)Google Scholar
  114. 4.89
    V.V. Burnasheva, V.A. Yartys', N.V. Fadeeva, S.P. Solov'ev, K.N. Semenenko: Sov. Phys. Dokl. 23, 97 (1978)Google Scholar
  115. 4.90
    A.V. Irodova, M.E. Kost, L.N. Padurets, V.A. Somenkov, E.I. Sokolova, S.Sh. Shil'shtein: Russ. J. Inorg. Chem. 26, 166 (1981)Google Scholar
  116. 4.91
    L.D. Calvert, B.M. Powell, J.J. Murray, Y. le Page: J. Sol. State Chem. 60, 62 (1985)Google Scholar
  117. 4.92
    F.A. Kuijpers, B.O. Loopstra: J. Phys. Chem. Solids 35, 301 (1974); J. de Phys. 32, Cl 657 (1971)Google Scholar
  118. 4.92a
    F.A. Kuijpers: Philips Res. Repts. Suppl. No. 2 (1973)Google Scholar
  119. 4.93
    C. Crowder, W.J. James, W. Yelon: J. Appl. Phys. 53, 2637 (1982)Google Scholar
  120. 4.94
    J.C. Achard, A.J. Dianoux, C. Lartigue, A. Percheron-Guégan, F. Tasset: In The RareEarths in Modern Science and Technology, Vol. 3, ed. by G.J. McCarthy, H.B. Silber, J.J. Rhyne (Plenum, New York 1982) pp. 481–486Google Scholar
  121. 4.95
    E. Gurewitz, H. Pinto, M.P. Dariel, H. Shaked: J. Phys. F 13, 545 (1983)Google Scholar
  122. 4.96
    J.-J. Didisheim, K. Yvon, D. Shaltiel, P. Fischer: Solid State Commun. 31, 47 (1979)Google Scholar
  123. 4.97
    H.W. Mayer, K.M. Alasafi, O. Bernauer: J. Less-Common Met. 88, L7 (1982)Google Scholar
  124. 4.98
    D. Fruchart, J.L. Soubeyroux, R. Hempelmann: J. Less-Common Met. 99, 307 (1984)Google Scholar
  125. 4.99
    J.L. Soubeyroux, D. Fruchart, A. Mikou, M. Pezat, B. Darriet: Mat. Res. Bull. 19, 895 (1984); sec also [4.61]Google Scholar
  126. 4.100
    D. Noréus, P.-E. Werner: Acta Chem. Scand. A 36, 847 (1982)Google Scholar
  127. 4.101
    A.F. Andresen, K. Otnes, A.J. Maeland: J. Less-Common Met. 89, 201 (1983)Google Scholar
  128. 4.102
    A.F. Andresen, H. Fjellvåg, A.J. Maeland: J. Less-Common Met. 103, 27 (1984)Google Scholar
  129. 4.103
    Y. Andersson, S. Rundqvist, R. Tellgren, T.B. Flanagan: Z. Phys. Chem. NF 145, 43 (1985)Google Scholar
  130. 4.104
    A. Santoro, A. Maeland, J.J. Rush: Acta Cryst. B 34, 3059 (1978)Google Scholar
  131. 4.105
    J. Bergsma, J.A. Goedkoop, J.H.N. van Vucht: Acta Crystallogr. 14, 223 (1961)Google Scholar
  132. 4.105a
    J.H.N. van Vucht: Philips Res. Repts. 18, 35 (1963)Google Scholar
  133. 4.106
    A.J. Maeland, E. Lukacevic, J.J. Rush, A. Santoro: J. Less-Common Met. 129, 77 (1987)Google Scholar
  134. 4.107
    D. Fruchart, P. Wolfers, P. Vulliet, A. Yaouanc, R. Fruchart, P.L'Heritier: In Proc. of the E. C. Workshop Meeting on Nd-Fe Permanent Magnets, Oct. 1984, Brussels, ed. by I.V. Mitchell (1985)Google Scholar
  135. 4.108
    S.W. Peterson, V.N. Sadana, W.L. Korst: J. de Phys. 25, 451 (1964)Google Scholar
  136. 4.109
    D.G. Westlake, H. Shaked, P.R. Mason, B.R. McCart, M.H. Mueller, T. Matsumoto, M. Amano: J. Less-Common Met. 88, 17 (1982)Google Scholar
  137. 4.110
    A.V. Irodova, V.A. Somenkov, S.Sh. Shil'shtein, L.N. Padurets, A.A. Chertkov: Sov. Phys. Crystallogr. 23, 591 (1978)Google Scholar
  138. 4.111
    Y. Andersson, S. Rundqvist, R. Tellgren, J.O. Thomas, T.B. Flanagan: J. Sol. State Chem. 32, 321 (1980)Google Scholar
  139. 4.112
    Y. Andersson, S. Rundqvist, R. Tellgren: J. Sol. State Chem. 52, 327 (1984)Google Scholar
  140. 4.113
    Y. Andersson, S. Rundqvist, R. Tellgren, J.O. Thomas, T.B. Flanagan: Acta Crystallogr. B37, 1965 (1981)Google Scholar
  141. 4.114
    D.G. Westlake: J. Less-Common Met. 91, 1 (1983)Google Scholar
  142. 4.115
    I. Jacob, D. Shaltiel, D. Davidov, I. Miloslavski: Solid State Commun. 23, 669 (1977)Google Scholar
  143. 4.115a
    I. Jacob, D. Shaltiel: J. Less-Common Met. 65, 117 (1979)Google Scholar
  144. 4.116
    I. Jacob, J.M. Bloch, D. Shaltiel, D. Davidov: Solid State Commun. 35, 155 (1980)Google Scholar
  145. 4.117
    J.J. Reilly, R.H. Wiswall, Jr.: Inorg. Chem. 13, 218 (1974)Google Scholar
  146. 4.118
    J.J. Reilly, R.H. Wiswall, Jr.: Inorg. Chem. 7, 2254 (1968)Google Scholar
  147. 4.119
    M.L. Post, J.J. Murray, G.J. Despault, J.B. Taylor: Mat. Res. Bull. 20, 337 (1985)Google Scholar
  148. 4.120
    D. Noréus, P.-E. Werner: Mat. Res. Bull. 16, 199 (1981)Google Scholar
  149. 4.121
    S. Ono, H. Hayakawa, A. Suzuki, K. Nomura, N. Nishimiya, T. Tabata: J. LessCommon Met. 88, 63 (1982)Google Scholar
  150. 4.122
    H. Hayakawa, Y. Ishido, K. Nomura, H. Uruno, S. Ono: J. Less-Common Met. 103, 277 (1984)Google Scholar
  151. 4.123
    P. Zolliker, K. Yvon, C. Bärlocher: J. Less-Common Met. 115, 65 (1986)Google Scholar
  152. 4.124
    T. Schober, W. Schäfer: J. Less-Common Met. 74, 23 (1980), see also [4.78]Google Scholar
  153. 4.125
    A.W. Hewat, I. Bailey: Nucl. Instrum. Methods 137, 463 (1976)Google Scholar
  154. 4.126
    R. Allemand, J. Bourdel, E. Roudaut, P. Convert, K. Ibel, J. Jacobe, J.P. Cotton, B. Farnoux: Nucl. Instrum. Methods 126, 29 (1975)Google Scholar
  155. 4.126a
    W. Hälg, H. Heer, J. Schäfer, P. Fischer, B. Bron, A. Isacson, M. Koch: Helv. Phys. Acta 57, 741 (1984)Google Scholar
  156. 4.126b
    P. Fischer: Neutron Diffraction Newsletter, Int. Union of Cryst. (1985) p.15Google Scholar
  157. 4.127
    J.D. Jorgensen, F.J. Rotella: J. Appl. Cryst. 15, 27 (1982)Google Scholar
  158. 4.128
    H.M. Rietveld: J. Appl. Crystallogr. 2, 65 (1969)Google Scholar
  159. 4.129
    P.-E. Werner, S. Salomé, G. Malmros, J.O. Thomas: J. Appl. Crystallogr. 12, 107 (1979)Google Scholar
  160. 4.130
    T.G. Worlton, J.D. Jorgensen, R.A. Beyerlein, D.L. Decker: Nucl. Instrum. Methods 137, 331 (1976)Google Scholar
  161. 4.131
    A. Albinati, B.T.M. Willis: The Rietveld method, publication MPD-NBS-136, Materials Physics Division, AERE Harwell (1980); J. Appl. Crystallogr. 15, 361 (1982)Google Scholar
  162. 4.132
    A.W. Hewat: Proc. of Symposium on Accuracy in Powder Diffraction, Gaithersburg, MD (1979), National Bureau of Standards Special Publication 567, 111 (1980); see also: C.R.A. Carlow (ed.): High Resolution Powder Diffraction, Mat. Science Forum (Trans Tech. Publ., Switzerland) Vol. 9, pp. 69–80 (1986)Google Scholar
  163. 4.133
    R.B. Von Dreele, J.D. Jorgensen, C.G. Windsor: J. Appl. Crystallogr. 15, 581 (1982)Google Scholar
  164. 4.134
    R.A. Young, E. Prince, R.A. Sparks: J. Appl. Crystallogr. 15, 357 (1982)Google Scholar
  165. 4.135
    H.G. Scott: J. Appl. Crystallogr. 16, 159 (1983)Google Scholar
  166. 4.136
    H.H. van Mal, K.H.J. Buschow, A.R. Miedema: J. Less-Common Met. 35, 65 (1974)Google Scholar
  167. 4.136a
    A.R. Miedema, K.H.J. Buschow, H.H. van Mal: J. Less-Common Met. 49, 463 (1976)Google Scholar
  168. 4.137
    P.C.P. Bouten, A.R. Miedema: J. Less-Common Met. 71, 147 (1980)Google Scholar
  169. 4.138
    D.G. Westlake: J. Less-Common Met. 90, 251 (1983)Google Scholar
  170. 4.139
    J. Osterwalder, T. Riesterer, L. Schlapbach, F. Vaillant, D. Fruchart: Phys. Rev. B 31, 8311 (1985)Google Scholar
  171. 4.140
    Z. Gavra, M.H. Mintz, G. Kimmel, Z. Hadari: Inorg. Chem. 18, 3595 (1979)Google Scholar
  172. 4.141
    J.P. Darnaudery, M. Pezat, B. Darriet, P. Hagenmuller: Mat. Res. Bull. 16, 1237 (1981)Google Scholar
  173. 4.142
    J.R. Johnson, J.J. Reilly, F. Reidinger, L.M. Corliss, J.M. Hastings: J. Less-Common Met. 88, 107 (1982)Google Scholar
  174. 4.143
    J. Zhuang, J.M. Hastings, L.M. Corliss, R. Bau, Chiau-Yu Wei, R.O. Moyer, Jr.: J. Sol. State Chem. 40, 352 (1981)Google Scholar
  175. 4.144
    P. Zolliker, K. Yvon: Mat. Res. Bull. 21, 415 (1986)Google Scholar
  176. 4.145
    M. Gupta, E. Belin, L. Schlapbach: J. Less-Common Met. 103, 389 (1984)Google Scholar
  177. 4.146
    D.G. Westlake: J. Mater. Sci. 19, 316 (1984)Google Scholar
  178. 4.147
    H. Behr, H. Metzger, J. Peisl: J. Less-Common Met. 88, 159 (1982)Google Scholar
  179. 4.148
    E.T. Teatum, K.A. Gschneidner, J.T. Waber: Los Alamos Natl. Lab., Los Alamos, New Mexico, Rept. No. LA-4003 (1968); see also [Ref. 4.168, p. 151]Google Scholar
  180. 4.149
    R.D. Shannon: Acta Crystallogr. A 32, 751 (1976)Google Scholar
  181. 4.150
    J.D. Corbett, H.S. Marek: Inorg. Chem. 22, 3194 (1983)Google Scholar
  182. 4.151
    A.C. Switendick: Z. Phys. Chem. NF 117, 89 (1979)Google Scholar
  183. 4.151a
    B.K. Rao, P. Jena: Phys. Rev. B 31, 6726 (1985)Google Scholar
  184. 4.152
    M. Gupta: J. Less-Common Met. 88, 221 (1982)Google Scholar
  185. 4.153
    D.A. Papaconstantopoulos, A.C. Switendick: J. Less-Common Met. 88, 273 (1982)Google Scholar
  186. 4.154
    M. Gupta: J. Less-Common Met. 103, 325 (1984)Google Scholar
  187. 4.155
    B.M. Klein, W.E. Pickett: J. Less-Common Met. 88, 231 (1982)Google Scholar
  188. 4.156
    W.A. Oates, T.B. Flanagan: Mat. Res. Bull. 19, 1397 (1984)Google Scholar
  189. 4.157
    R. Griessen, A. Driessen, D.G. de Groot: J. Less-Common Met. 103, 235 (1984)Google Scholar
  190. 4.158
    J.C. Achard, C. Lartigue, A. Percheron-Guégan, J.C. Mathieu, A. Pasturel, F. Tasset: J. Less-Common Met. 79, 161 (1981)Google Scholar
  191. 4.159
    J. Shinar, D. Shaltiel, D. Davidov, A. Grayevsky: J. Less-Common Met. 60, 209 (1978)Google Scholar
  192. 4.160
    R. Burch, N.B. Mason: J. Less-Common Met. 63, 57 (1979)Google Scholar
  193. 4.161
    F.L. Carter: J. Less-Common Met. 74, 245 (1980)Google Scholar
  194. 4.162
    A. Yoshikawa, T. Matsumoto, K. Yagisawa: J. Less-Common Met. 88, 73 (1982)Google Scholar
  195. 4.163
    A.L. Shilov, M.E. Kost, N.T. Kuznetsov: J. Less-Common Met. 105, 221 (1985)Google Scholar
  196. 4.164
    B.D. Dunlap, P.J. Viccaro, G.K. Shenoy: J. Less-Common Met. 74, 75 (1980)Google Scholar
  197. 4.165
    H.A. Kierstead: J. Less-Common Met. 96, 141 (1984)Google Scholar
  198. 4.166
    A.R. Williams, J. Kilbler, C.D. Gelatt, Jr.: Phys. Rev. B 19, 6094 (1979)Google Scholar
  199. 4.167
    A. Miedema, P.F. de Châtel, F.R. DeBoer: Physica 100 B, 1 (1980)Google Scholar
  200. 4.168
    W.B. Pearson: The Crystal Chemistry and Physics of Metals and Alloys (Wiley, New York 1980)Google Scholar
  201. 4.169
    C.E. Lundin, F.E. Lynch, C.B. Magee: J. Less-Common Met. 56 19 (1977)Google Scholar
  202. 4.170
    M.H. Mendelsohn, D.M. Gruen, A.E. Dwight: J. Less-Common Met. 63, 193 (1979); Nature (London) 269, 45 (1977)Google Scholar
  203. 4.171
    C.B. Magee, J. Liu, C.E. Lundin: J. Less-Common Met. 78, 119 (1981)Google Scholar
  204. 4.172
    D.G. Westlake: J. Chem. Phys. 79, 4532 (1983)Google Scholar
  205. 4.173
    D.G. Westlake: Mat. Res. Bull. 18, 1409 (1983)Google Scholar
  206. 4.174
    D.G. Westlake: J. Mat. Science 18, 605 (1983); and Scripta Metall. 16, 1049 (1982)Google Scholar
  207. 4.175
    D.G. Westlake: Sol. State Chem. 53, 130 (1984)Google Scholar
  208. 4.176
    D.G. Westlake: J. Less-Common. Met. 91, 275 (1983)Google Scholar
  209. 4.177
    D.G. Westlake: J. Less-Common Met. 103, 203 (1984); J. Less-Common Met. 107,189 (1985)Google Scholar
  210. 4.178
    D.G. Westlake: J. Less-Common Met. 105, 69 (1985)Google Scholar
  211. 4.179
    G.A. Stewart, D.C. Creagh: J. Phys. F 15, 1639 (1985)Google Scholar
  212. 4.180
    Y. Chung, T. Takeshita, O.D. McMasters, K.A. Gschneidner, Jr.: J. Less-Common Met. 74, 217 (1980)Google Scholar
  213. 4.181
    D.P. Shoemaker, C.B. Shoemaker: J. Less-Common Met. 68, 43 (1979)Google Scholar
  214. 4.182
    W.A. Oates, J.A. Lambert, P.T. Gallagher: Trans. Met. Soc. AIME 245, 47 (1969)Google Scholar
  215. 4.183
    W.E. Wallace: J. Less-Common Met. 88, 141 (1982)Google Scholar
  216. 4.184
    J.F. Lakner, F.S. Uribe, S.A. Steward: J. Less-Common Met. 72, 87 (1980)Google Scholar
  217. 4.185
    W.E. Wallace, E.B. Boltich: J. Sol. State Chem. 33, 435 (1980)Google Scholar
  218. 4.186
    H. Goretzki: Naturwiss. 54, 163 (1967)Google Scholar
  219. 4.187
    K. Yvon, H. Nowotny, R. Kieffer: Monatsh. Chem. 98, 2164 (1967)Google Scholar
  220. 4.188
    D.M.P. Mingos, J.C. Hawes: In Structure and Bonding, Vol. 63 (Springer, Berlin, Heidelberg 1986) pp. 1–63Google Scholar
  221. 4.189
    K.A. Gschneidner, Jr., T. Takeshita, Y. Chung, O.D. McMasters: J. Phys. F. Met. Phys. 12, L1 (1982)Google Scholar
  222. 4.190
    M.H. Mendelsohn, D.M. Gruen: J. Less-Common Met. 78, 275 (1981)Google Scholar
  223. 4.191
    I. Jacob, A. Stern, A. Moran, D. Shaltiel, D. Davidov: J. Less-Common Met. 73, 369 (1980)Google Scholar
  224. 4.192
    I. Jacob: Sol. State Commun. 40, 1015 (1981)Google Scholar
  225. 4.192a
    I. Jacob, J.M. Bloch, E. Gurevich: J. Less-Common Met. 88, 25 (1982)Google Scholar
  226. 4.193
    D. Shaltiel: J. Less-Common Met. 73, 329 (1980)Google Scholar
  227. 4.194
    I. Jacob, J.M. Bloch: Sol. State Commun. 42, 541 (1982)Google Scholar
  228. 4.195
    T. Riesterer: J. Less-Common Met. 103, 219 (1984)Google Scholar
  229. 4.196
    D.M. Gruen, M. Mendelsohn: J. Less-Common Met. 55, 149 (1977)Google Scholar
  230. 4.197
    C.E. Crowder, W.J. James: J. Less-Common Met. 95, 1 (1983)Google Scholar
  231. 4.198
    C. Geibel, W. Goldacker, H. Keiber, V. Oestreich, H. Rietschel, H. Wühl: Phys. Rev. B 30, 6363 (1984)Google Scholar
  232. 4.199
    M.Yu. Belyaev, AN. Skripov, V.N. Kozhanov, A.B. Stepanov, E.V. Galoshina: Solid State Commun. 48, 1049 (1983)Google Scholar
  233. 4.200
    J.-J. Didisheim, P. Fischer: J. Less-Common Met. 103, 267 (1984)Google Scholar

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© Springer-Verlag 1988

Authors and Affiliations

  • Klaus Yvon
  • Peter Fischer

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