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Chiral Lewis Acid Rare-Earth Metal Complexes in Enantioselective Catalysis

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Chiral Lewis Acids

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 62))

Abstract

The progress made over the past two decades in asymmetric catalysis, focusing on chiral Lewis acid complexes of rare-earth metal, is reviewed. The applications of several different catalytic systems of chiral Lewis acid complexes in various asymmetric reactions have been discussed: (1) asymmetric aldol reaction, (2) asymmetric Mannich reaction, (3) asymmetric Michael reaction, (4) asymmetric Friedel-Crafts reaction, (5) asymmetric homologation of carbonyl compounds with α-diazoesters, (6) asymmetric ene-type reaction, (7) asymmetric cycloaddition reaction, (8) asymmetric ring-opening reaction, and (9) asymmetric miscellaneous reaction.

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Authors and Affiliations

  1. Sichuan University, Chengdu, P. R. China

    Xiaoming Feng & Xiaohua Liu

  2. Chongqing University, Chongqing, P. R. China

    Zhen Wang

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  1. Xiaoming Feng
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  2. Zhen Wang
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  3. Xiaohua Liu
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Correspondence to Xiaoming Feng .

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Editors and Affiliations

  1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, Tokyo, Japan

    Koichi Mikami

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Feng, X., Wang, Z., Liu, X. (2017). Chiral Lewis Acid Rare-Earth Metal Complexes in Enantioselective Catalysis. In: Mikami, K. (eds) Chiral Lewis Acids. Topics in Organometallic Chemistry, vol 62. Springer, Cham. https://doi.org/10.1007/3418_2017_1

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