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Recent Advances on the Chemistry of POCOP–Nickel Pincer Compounds

  • Matthew Asay
  • David Morales-MoralesEmail author
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 54)

Abstract

A description of the vertiginous development of the chemistry of POCOP–Ni complexes and their applications is described. Recent advances include the discovery and initially challenging synthesis of these species to the high-yield green procedures recently developed. The various applications of these compounds, particularly in catalysis, are discussed in detail.

Keywords

Catalysis CO2 activation Cross-coupling reactions Fluorination Hydrogen production Nickel pincer compounds Organometallic nickel compounds POCOP compounds Suzuki–Miyaura Thioetherification 

Notes

Acknowledgments

M. A. thanks the UNAM IQ for support. D. M-M. gratefully acknowledges the support and enthusiasm of former and current group members and colleagues. The research from our group described in this paper is supported by CONACYT and PAPIIT-DGAPA-UNAM.

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Copyright information

© Springer International Publishing Switzerland 2015

Authors and Affiliations

  1. 1.Instituto de QuímicaUniversidad Nacional Autónoma de MéxicoMexicoMexico

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