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Pincer Complexes with Thione Sulfur Donors

  • Diana V. AleksanyanEmail author
  • Vladimir A. Kozlov
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 54)

Abstract

Rapid development of pincer chemistry over the last several decades made a substantial contribution in extension of theoretical and practical organometallic chemistry as well as organic synthesis, catalysis, and materials science. This review is devoted to relatively new types of nonclassical pincer compounds bearing thione sulfur donors incorporated into thiophosphoryl and/or thioamide groups. The discussion is focused on synthetic aspects and structural features of symmetrical and hybrid S,C,S-pincer ligands and complexes with particular attention to the practically valuable properties.

Keywords

Catalysis Cyclometallation Luminescence Organothiophosphorus compounds Pincer complexes Sulfur donors Thioamides 

Notes

Acknowledgments

The authors are grateful to the Russian Foundation for Basic Research (project no. 14-03-31237-mol-a) and Council on Grants of the President of the Russian Federation (project no. MK-382.2014.3) for financial support.

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Copyright information

© Springer International Publishing Switzerland 2015

Authors and Affiliations

  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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