Abstract
The formation of carbon–heteroatom bonds (C–X bonds with X=N, S, P) upon addition of X-nucleophiles or X-electrophiles to unsaturated alkynes and alkenes, cross-coupling reactions, cycloadditions, tandem or consecutive reactions, or C–H functionalization is an attractive strategy in organic synthesis and is an intensive research area. Many organometallic species, more specifically palladium, nickel, and rhodium complexes, have paved the way to useful synthetic applications in this field. This chapter will cover iron-catalyzed bond-forming reactions between carbon and a heteroatom.
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- AIBN:
-
Azobisisobutyronitrile
- BINAP:
-
2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
- cod:
-
1,5-Cyclooctadiene
- DCIB:
-
1,2-Dichloroisobutane
- DDQ:
-
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone
- DMEDA:
-
N,N′-Dimethylethylenediamine
- DMSO:
-
Dimethyl sulfoxide
- dppe:
-
1,2-Bis(diphenylphosphino)ethane
- dppf:
-
1,1′-Bis(diphenylphosphino)ferrocene
- dppp:
-
1,3-Bis(diphenylphosphino)propane
- DTBP:
-
Di-tert-butyl peroxide
- 4-F-dppbz:
-
Bis(4-fluorophenyl)phosphinobenzene
- HDA:
-
Hetero-Diels–Alder reaction
- HMDS:
-
Bis(trimethylsilyl)amine
- NBS:
-
N-Bromosuccinimide
- Pc:
-
Phthalocyaninato
- TBHP:
-
tert-Butyl hydroperoxide, tBuOOH
- TEMPO:
-
(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl
- terpy:
-
Terpyridine ligand
- triflate:
-
OTf, Trifluoromethanesulfonate, CF3SO3 −
- TMSCl:
-
Trimethylsilyl chloride
- TPP:
-
Tetraphenylporphyrin
- TTN:
-
Total turnover number
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Renaud, JL., Gaillard, S. (2015). Iron-Catalyzed Carbon–Nitrogen, Carbon–Phosphorus, and Carbon–Sulfur Bond Formation and Cyclization Reactions. In: Bauer, E. (eds) Iron Catalysis II. Topics in Organometallic Chemistry, vol 50. Springer, Cham. https://doi.org/10.1007/3418_2015_103
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