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Iron Catalysis II pp 145–171Cite as

High-Valent Iron in Biomimetic Alkane Oxidation Catalysis

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 50))

Abstract

The combination of iron salts or complexes with strong oxidants such as hydrogen peroxide results in the formation of high-valent iron oxo species, the nature of which has been under discussion in the chemical literature for more than a century. Recent advances in the design and development of molecular iron-based oxidation catalysts and their mechanistic understanding are summarised in this chapter, in particular iron complexes featuring tetradentate and pentadentate ligands. Inspired by enzymatic systems based on heme and nonheme ligand environments, the development of biomimetic iron-based catalysts for the selective oxidation of alkanes and alkenes can potentially be applied in a range of areas, from late stage functionalisation of natural product synthesis to large-scale oxidation of hydrocarbons.

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Abbreviations

BLM:

Bleomycin

DFT:

Density functional theory

DNA:

Deoxyribonucleic acid

EPR:

Electron paramagnetic resonance

HAT:

Hydrogen atom transfer

His:

Histidine

KIE:

Kinetic isotope effect

MMO:

Methane monooxygenase

NMR:

Nuclear magnetic resonance

PCET:

Proton-coupled electron transfer

RC:

Retention of configuration

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Authors and Affiliations

  1. Department of Chemistry, Imperial College London, Exhibition Road, London, SW7 2AY, UK

    Michaela Grau & George J. P. Britovsek

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  1. Michaela Grau
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  1. Dept. of Chemistry and Biochemistry, University of Missouri - St. Louis, One University Boulevard, St. Louis, Missouri, USA

    Eike Bauer

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Grau, M., Britovsek, G.J.P. (2015). High-Valent Iron in Biomimetic Alkane Oxidation Catalysis. In: Bauer, E. (eds) Iron Catalysis II. Topics in Organometallic Chemistry, vol 50. Springer, Cham. https://doi.org/10.1007/3418_2015_100

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