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Ruthenium in Catalysis pp 289–318Cite as

C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 48))

Abstract

Electron-rich ruthenium(II) catalysts of type (C5R5)XRuL n are used to perform selective carbon–carbon bond formation by combination of simple substrates such as the coupling of functional alkynes and alkenes with a variety of unsaturated molecules (alkynes, diynes, alkenes, dienes) or non-unsaturated molecules such as alcohols or water, often with atom economy. Various selective transformations are developed and can provide access to high multifunctional molecules. These reactions often proceed via an initial oxidative coupling leading to a ruthenacycle intermediate.

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Authors and Affiliations

  1. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes1, Organométalliques : Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes, France

    Sylvie Dérien

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  1. Sylvie Dérien
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Correspondence to Sylvie Dérien .

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Editors and Affiliations

  1. Inst. des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université Rennes1, Rennes, France

    Pierre H. Dixneuf

  2. Inst. des Sciences Chimiques de Rennes, UMR 6226-CNRS-Université de Rennes1, Rennes, France

    Christian Bruneau

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Dérien, S. (2014). C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts. In: Dixneuf, P., Bruneau, C. (eds) Ruthenium in Catalysis. Topics in Organometallic Chemistry, vol 48. Springer, Cham. https://doi.org/10.1007/3418_2014_82

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