Skip to main content
SpringerLink
Log in
Book cover

Photophysics of Organometallics pp 115–158Cite as

Ultrafast Excited-State Processes in Re(I) Carbonyl-Diimine Complexes: From Excitation to Photochemistry

  • Chapter
  • First Online:

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 29))

Abstract

Rhenium(I) carbonyl-diimines are chemically robust and synthetically flexible photo- and redox active compounds that can be incorporated into supramolecular systems, polymers or biomolecules. They can be used as efficient and fast photosensitizers. In this chapter, we will follow excited-state evolution of ReI complexes from the instant of photon absorption through intersystem crossing, relaxation of “hot” triplet states, to their decay either to the ground state or to photoproducts. Out of many decay pathways, we concentrate on nonradiative decay following the energy gap law, excited-state electron- and energy transfer and ligand isomerization. Characterization of the lowest excited state by ultrafast IR spectroscopy and DFT calculations are discussed in detail. It is shown that excited-state properties are much influenced by mixing of Re(CO)3→diimine, L→diimine CT and intraligand ππ* excitations.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   259.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Abbreviations

*:

In front of a formula denotes electronic excitation

bpy:

2,2′-Bipyridine

CT:

Charge-transfer transition, excitation or excited state. Detailed character (herein MLCT, XLCT, or LLCT) not specified

DFT:

Density functional theory

dmb:

4,4′-Me2–2,2′-bpy

dppz:

Dipyrido[3,2-a:2′,3′-c]phenazine

EFFF:

Energy factored force field

ET:

Electron transfer

EnT:

Energy transfer

Etpy:

4-Ethyl-pyridine

IL:

Intraligand, localization on a particular ligand may be specified in brackets: IL(N,N) or IL(L)

ILCT:

Intraligand charge transfer

im:

Imidazole

L:

Axial ligand

LLCT:

Ligand-to-ligand charge transfer, herein L®N,N

MLCT:

Metal-to-ligand charge transfer

MLLCT:

Metal–ligand-to-ligand charge transfer, herein Re(L)(CO)3®N,N. A general abbreviation replacing MLCT/LLCT and MLCT/XLCT

MQ+ :

N-methyl-4,4′-bipyridinium

ν(CO):

CºO stretching vibration of a carbonyl ligand

N,N:

α-Diimine or polypyridine ligand

phen:

1,10-Phenanthroline

PTZ:

Phenothiazine, an electron donor

py:

Pyridine

SBLCT:

Sigma bond-to-metal charge transfer

TD-DFT:

Time-dependent DFT

TR2 :

Transient resonance Raman

TR3 :

Time-resolved resonance Raman

TRIR:

Time-resolved IR absorption

2D-TRIR:

Two-Dimensional TRIR

trp:

Tryptophan

tyr:

Tyrosine

UKS:

Unrestricted Kohn–Sham approach

X:

Halide axial ligand

XLCT:

X→N,N charge transfer, a kind of LLCT for L= halide

ZFS:

Zero-field splitting

References

  1. Stufkens DJ, Vlček A Jr (1998) Coord Chem Rev 177:127

    CAS  Google Scholar 

  2. Stufkens DJ, Aarnts MP, Nijhoff J, Rossenaar BD, Vlček A Jr (1998) Coord Chem Rev 171:93

    CAS  Google Scholar 

  3. Stufkens DJ, Aarnts MP, Rossenaar BD, Vlček A Jr (1997) Pure Appl Chem 69:831

    CAS  Google Scholar 

  4. Stufkens DJ (1992) Comments Inorg Chem 13:359

    CAS  Google Scholar 

  5. Vlček A Jr (2001) In: Balzani V, Astruc D (eds) Electron transfer in chemistry, vol 2. Wiley, Weinheim, p 804

    Google Scholar 

  6. Stor GJ, Hartl F, van Outersterp JWM, Stufkens DJ (1995) Organometallics 14:1115

    CAS  Google Scholar 

  7. Klein A, Vogler C, Kaim W (1996) Organometallics 15:236

    CAS  Google Scholar 

  8. Paolucci F, Marcaccio M, Paradisi C, Roffia S, Bignozzi CA, Amatore C (1998) J Phys Chem B 102:4759

    CAS  Google Scholar 

  9. Juris A, Campagna S, Bidd I, Lehn J-M, Ziessel R (1988) Inorg Chem 27:4007

    CAS  Google Scholar 

  10. Cannizzo A, Blanco-Rodríguez AM, Nahhas A, Šebera J, Záliš S, Vlček A Jr, Chergui M (2008) J Am Chem Soc 130:8967

    CAS  Google Scholar 

  11. Vlček A Jr, Záliš S (2007) Coord Chem Rev 251:258

    Google Scholar 

  12. Blanco-Rodríguez AM, Gabrielsson A, Motevalli M, Matousek P, Towrie M, Šebera J, Záliš S, Vlček A Jr (2005) J Phys Chem A 109:5016

    Google Scholar 

  13. Gabrielsson A, Busby M, Matousek P, Towrie M, Hevia E, Cuesta L, Perez J, Záliš S, Vlček A Jr (2006) Inorg Chem 45:9789

    CAS  Google Scholar 

  14. Bossert J, Daniel C (2006) Chem Eur J 12:4835

    CAS  Google Scholar 

  15. Rossenaar BD, Stufkens DJ, Vlček A Jr (1996) Inorg Chem 35:2902

    CAS  Google Scholar 

  16. Villegas JM, Stoyanov SR, Huang W, Rillema DP (2005) Inorg Chem 44:2297

    CAS  Google Scholar 

  17. Villegas JM, Stoyanov SR, Huang W, Rillema DP (2005) Dalton:1042

    Google Scholar 

  18. Stufkens DJ, Vlček A Jr (1996) Spectrum 9:2

    Google Scholar 

  19. Stufkens DJ (1990) Coord Chem Rev 104:39

    CAS  Google Scholar 

  20. Lees AJ (1987) Chem Rev 87:711

    CAS  Google Scholar 

  21. Kalyanasundaram K (1986) J Chem Soc Faraday Trans 2 82:2401

    CAS  Google Scholar 

  22. Hino JK, Della Ciana L, Dressick WJ, Sullivan BP (1992) Inorg Chem 31:1072

    CAS  Google Scholar 

  23. van Slageren J, Klein A, Záliš S, Stufkens DJ (2001) Coord Chem Rev 219-221:937

    CAS  Google Scholar 

  24. Stor GJ, Stufkens DJ, Oskam A (1992) Inorg Chem 31:1318

    CAS  Google Scholar 

  25. Smothers WK, Wrighton MS (1983) J Am Chem Soc 105:1067

    CAS  Google Scholar 

  26. Lewis JD, Perutz RN, Moore JN (2004) J Phys Chem A 108:9037

    CAS  Google Scholar 

  27. Lewis JD, Clark IP, Moore JN (2007) J Phys Chem A 111:50

    CAS  Google Scholar 

  28. Flood A, Girling RB, Gordon KC, Hester RE, Moore JN, Polson MIJ (2002) J Raman Spectrosc 33:434

    CAS  Google Scholar 

  29. Walsh PJ, Gordon KC, Lundin NJ, Blackman AG (2005) J Phys Chem A 109:5933

    CAS  Google Scholar 

  30. Busby M, Hartl F, Matousek P, Towrie M, Vlček A Jr (2008) Chem Eur J 14:6912

    CAS  Google Scholar 

  31. Busby M, Matousek P, Towrie M, Vlček A Jr (2005) J Phys Chem A 109:3000

    CAS  Google Scholar 

  32. Busby M, Matousek P, Towrie M, Vlček A Jr (2007) Inorg Chim Acta 360:885

    CAS  Google Scholar 

  33. Vlček A Jr, Záliš S (2005) J Phys Chem A 109:2991

    Google Scholar 

  34. Katz NE, Mecklenburg SL, Graff DK, Chen P, Meyer TJ (1994) J Phys Chem 98:8959

    CAS  Google Scholar 

  35. Salassa L, Garino C, Albertino A, Volpi G, Nervi C, Gobetto R, Kenneth I Hardcastle KI (2008) Organometallics 27:1427–1435

    CAS  Google Scholar 

  36. Garino C, Ruiu T, Salassa L, Albertino A, Volpi G, Nervi C, Gobetto R, Hardcastle KI (2008) Eur Inorg Chem:3587

    Google Scholar 

  37. Liard DJ, Busby M, Matousek P, Towrie M, Vlček A Jr (2004) J Phys Chem A 108:2363

    CAS  Google Scholar 

  38. Turro NJ (1978) Modern molecular photochemistry. Benjamin, Menlo Park

    Google Scholar 

  39. Cannizzo A, van Mourik F, Gawelda W, Zgrablic G, Bressler C, Chergui M (2006) Angew Chem Int Ed 45:3174

    CAS  Google Scholar 

  40. Bhasikuttan AC, Okada T (2004) J Phys Chem B 108:12629

    CAS  Google Scholar 

  41. Gawelda W, Cannizzo A, Pham V-T, van Mourik F, Bressler C, Chergui M (2007) J Am Chem Soc 129:8199

    CAS  Google Scholar 

  42. Wang Y, Asbury JB, Lian T (2000) J Phys Chem A 104:4291

    CAS  Google Scholar 

  43. Shih C, Museth AK, Abrahamsson M, Blanco-Rodriguez AM, Di Bilio AJ, Sudhamsu J, Crane BR, Ronayne KL, Towrie M, Vlček A Jr, Richards JH, Winkler JR, Gray HB (2008) Science 320:1760

    CAS  Google Scholar 

  44. Wrighton MS, Morse DL (1974) J Am Chem Soc 96:998

    CAS  Google Scholar 

  45. Geoffroy GL, Wrighton MS (1979) Organometallic photochemistry. Academic, New York

    Google Scholar 

  46. Striplin DR, Crosby GA (2001) Coord Chem Rev 211:163

    CAS  Google Scholar 

  47. Schoonover JR, Strouse GF, Dyer RB, Bates WD, Chen P, Meyer TJ (1996) Inorg Chem 35:273

    CAS  Google Scholar 

  48. Dyer J, Blau WJ, Coates CG, Creely CM, Gavey JD, George MW, Grills DC, Hudson S, Kelly JM, Matousek P, McGarvey JJ, McMaster J, Parker AW, Towrie M, Weinstein JA (2003) Photochem Photobiol Sci 2:542

    CAS  Google Scholar 

  49. Giordano PJ, Wrighton MS (1979) J Am Chem Soc 101:2888

    CAS  Google Scholar 

  50. Wallace L, Rillema DP (1993) Inorg Chem 32:3836

    CAS  Google Scholar 

  51. Giordano PJ, Fredericks SM, Wrighton MS, Morse DL (1978) J Am Chem Soc 100:2257

    CAS  Google Scholar 

  52. Fredericks SM, Luong JC, Wrighton MS (1979) J Am Chem Soc 101:7415

    CAS  Google Scholar 

  53. Luong JC, Faltynek RA, Wrighton MS (1980) J Am Chem Soc 102:7892

    CAS  Google Scholar 

  54. Yersin H, Finkenzeller WJ (2008) In: Yersin H (ed) Highly efficient OLEDs with phosphorescent materials. Wiley, Weinheim, p 1

    Google Scholar 

  55. Striplin DR, Crosby GA (1994) Chem Phys Lett 221:426

    CAS  Google Scholar 

  56. Záliš S, Ben Amor N, Daniel C (2004) Inorg Chem 43:7978

    Google Scholar 

  57. Turki M, Daniel C, Záliš S, Vlček A Jr, van Slageren J, Stufkens DJ (2001) J Am Chem Soc 123:11431

    CAS  Google Scholar 

  58. Gamelin DR, George MW, Glyn P, Grevels F-W, Johnson FPA, Klotzbücher W, Morrison SL, Russell G, Schaffner K, Turner JJ (1994) Inorg Chem 33:3246

    CAS  Google Scholar 

  59. Bredenbeck J, Helbing J, Hamm P (2004) J Am Chem Soc 126:990

    CAS  Google Scholar 

  60. Dattelbaum DM, Omberg KM, Schoonover JR, Martin RL, Meyer TJ (2002) Inorg Chem 41:6071

    CAS  Google Scholar 

  61. Dattelbaum DM, Omberg KM, Hay PJ, Gebhart NL, Martin RL, Schoonover JR, Meyer TJ (2004) J Phys Chem A 108:3527

    CAS  Google Scholar 

  62. Glyn P, George MW, Hodges PM, Turner JJ (1989) J Chem Soc Chem Commun:1655

    Google Scholar 

  63. Dattelbaum DM, Martin RL, Schoonover JR, Meyer TJ (2004) J Phys Chem A 108:3518

    Google Scholar 

  64. Cotton FA, Kraihanzel CS (1962) J Am Chem Soc 84:4432

    CAS  Google Scholar 

  65. Kraihanzel CS, Cotton FA (1963) Inorg Chem 2:533

    CAS  Google Scholar 

  66. Cotton FA (1964) Inorg Chem 3:702

    CAS  Google Scholar 

  67. Braterman PS (1975) Metal carbonyl spectra. Academic, London

    Google Scholar 

  68. George MW, Johnson FPA, Westwell JR, Hodges PM, Turner JJ (1993) J Chem Soc Dalton Trans:2977

    Google Scholar 

  69. George MW, Turner JJ (1998) Coord Chem Rev 177:201

    CAS  Google Scholar 

  70. Clark IP, George MW, Johnson FPA, Turner JJ (1996) Chem Commun:1587

    Google Scholar 

  71. Busby M, Gabrielsson A, Matousek P, Towrie M, Di Bilio AJ, Gray HB, Vlček A Jr (2004) Inorg Chem 43:4994

    CAS  Google Scholar 

  72. Busby M, Matousek P, Towrie M, Clark IP, Motevalli M, Hartl F, Vlček A Jr (2004) Inorg Chem 43:4523

    CAS  Google Scholar 

  73. Gabrielsson A, Blanco-Rodríguez AM, Matousek P, Towrie M, Vlček A Jr (2006) Organometallics 25:2148

    CAS  Google Scholar 

  74. Gabrielsson A, Matousek P, Towrie M, Hartl F, Záliš S, Vlček A Jr (2005) J Phys Chem A 109:6147

    CAS  Google Scholar 

  75. Blanco-Rodríguez AM, Busby M, Grídinaru C, Crane BR, Di Bilio AJ, Matousek P, Towrie M, Leigh BS, Richards JH, Vlček A Jr, Gray HB (2006) J Am Chem Soc 128:4365

    Google Scholar 

  76. Blanco-Rodríguez AM, Ronayne KL, Záliš S, Sýkora J, Hof M, Vlček A Jr (2008) J Phys Chem A 112:3506

    Google Scholar 

  77. Lewis JD, Towrie M, Moore JN (2008) J Phys Chem A 112:3852

    CAS  Google Scholar 

  78. Vlček A Jr, Farrell IR, Liard DJ, Matousek P, Towrie M, Parker AW, Grills DC, George MW (2002) J Chem Soc Dalton Trans:701

    Google Scholar 

  79. Liard DJ, Busby M, Farrell IR, Matousek P, Towrie M, Vlček A Jr (2004) J Phys Chem A 108:556

    CAS  Google Scholar 

  80. Rossenaar BD, George MW, Johnson FPA, Stufkens DJ, Turner JJ, Vlček A Jr (1995) J Am Chem Soc 117:11582

    CAS  Google Scholar 

  81. Caspar JV, Westmoreland TD, Allen GH, Bradley PG, Meyer TJ, Woodruff WH (1984) J Am Chem Soc 106:3492

    CAS  Google Scholar 

  82. Schoonover JR, Bates WD, Meyer TJ (1995) Inorg Chem 34:6421

    CAS  Google Scholar 

  83. Kotch TG, Lees AJ, Fuerniss SJ, Papathomas KI, Snyder RW (1993) Inorg Chem 32:2570

    CAS  Google Scholar 

  84. Lees AJ (1998) Coord Chem Rev 177:3

    CAS  Google Scholar 

  85. Horng ML, Gardecki JA, Papazyan A, Maroncelli M (1995) J Phys Chem 99:17311

    CAS  Google Scholar 

  86. Blanco-Rodríguez AM, Towrie M, Collin J-P, Záliš S, Vlček A Jr (2009) Dalton Trans in press

    Google Scholar 

  87. Asbury JB, Wang Y, Lian T (2002) Bull Chem Soc Jpn 75:973

    CAS  Google Scholar 

  88. Lenchenkov VA, She C, Lian T (2004) J Phys Chem B 108:16194

    CAS  Google Scholar 

  89. Asher SA, Murtaugh J (1983) J Am Chem Soc 105:7244

    CAS  Google Scholar 

  90. Kang YK, Duncan TV, Therien MJ (2007) J Phys Chem B 111:6829

    CAS  Google Scholar 

  91. Chen P, Meyer TJ (1998) Chem Rev 98:1439

    CAS  Google Scholar 

  92. Claude JP, Omberg KM, Williams DS, Meyer TJ (2002) J Phys Chem A 106:7795

    CAS  Google Scholar 

  93. Allen GH, White RP, Rillema DP, Meyer TJ (1984) J Am Chem Soc 106:2613

    CAS  Google Scholar 

  94. Caspar JV, Meyer TJ (1983) Inorg Chem 22:2444

    CAS  Google Scholar 

  95. Caspar JV, Meyer TJ (1983) J Am Chem Soc 105:5583

    CAS  Google Scholar 

  96. Worl LA, Duesing R, Chen P, Della Ciana L, Meyer TJ (1991) J Chem Soc Dalton Trans:849

    Google Scholar 

  97. Baiano JA, Kessler RJ, Lumpkin RS, Munley MJ, Murphy WR Jr (1995) J Phys Chem 99:17680

    CAS  Google Scholar 

  98. Chen P, Duesing R, Graff DK, Meyer TJ (1991) J Phys Chem 95:5850

    CAS  Google Scholar 

  99. Englman R, Jortner J (1970) Mol Phys 18:145

    CAS  Google Scholar 

  100. Kober EM, Caspar JV, Lumpkin RS, Meyer TJ (1986) J Phys Chem 90:3722

    CAS  Google Scholar 

  101. Caspar JV, Meyer TJ (1983) J Phys Chem 87:952

    CAS  Google Scholar 

  102. Sato S, Sekine A, Ohashi Y, Ishitani O, Blanco-Rodríguez AM, Vlček A Jr, Unno T, Koike K (2007) Inorg Chem 46:3531

    CAS  Google Scholar 

  103. Sato S, Morimoto T, Ishitani O (2007) Inorg Chem 46:9051

    CAS  Google Scholar 

  104. Rossenaar BD, Kleverlaan CJ, van de Ven MCE, Stufkens DJ, Vlček A Jr (1996) Chem Eur J 2:228

    CAS  Google Scholar 

  105. Rossenaar BD, Lindsay E, Stufkens DJ, Vlček A Jr (1996) Inorg Chim Acta 250:5

    CAS  Google Scholar 

  106. Kleverlaan CJ, Martino DM, van Willigen H, Stufkens DJ, Oskam A (1996) J Phys Chem 100:18607

    CAS  Google Scholar 

  107. Aarnts MP, Wilms MP, Stufkens DJ, Baerends EJ, Vlček A Jr (1997) Organometallics 16:2055

    CAS  Google Scholar 

  108. Kleverlaan CJ, Stufkens DJ, Clark IP, George MW, Turner JJ, Martino DM, van Willigen H, Vlček A Jr (1998) J Am Chem Soc 120:10871

    CAS  Google Scholar 

  109. Kleverlaan CJ, Martino DM, van Slageren J, van Willigen H, Stufkens DJ, Oskam A (1998) Appl Magn Reson 15:203

    CAS  Google Scholar 

  110. Kleverlaan CJ, Stufkens DJ (1999) Inorg Chim Acta 284:61

    CAS  Google Scholar 

  111. Farrell IR, Matousek P, Kleverlaan CJ, Vlček A Jr (2000) Chem Eur J 6:1386

    CAS  Google Scholar 

  112. Daniel C (2002) Coord Chem Rev 230:65

    CAS  Google Scholar 

  113. Bruand-Cote I, Daniel C (2002) Chem Eur J 8:1361

    CAS  Google Scholar 

  114. Guillaumont D, Daniel C (1999) J Am Chem Soc 121:11733

    CAS  Google Scholar 

  115. Vlček A Jr, Busby M (2006) Coord Chem Rev 250:1755–1762

    Google Scholar 

  116. Yam VW-W, Lau VC-Y, Wu L-X (1998) J Chem Soc Dalton Trans:1461

    Google Scholar 

  117. Wrighton MS, Morse DL, Pdungsap L (1975) J Am Chem Soc 97:2073

    CAS  Google Scholar 

  118. Sun S-S, Robson E, Dunwoody N, Silva AS, Brinn IM, Lees AJ (2000) Chem Commun:201

    Google Scholar 

  119. Dattelbaum DM, Itokazu MK, Iha NYM, Meyer TJ (2003) J Phys Chem A 107:4092

    CAS  Google Scholar 

  120. Lewis JD, Perutz RN, Moore JN (2000) Chem Commun:1865

    Google Scholar 

  121. Sun S-S, Lees AJ (2002) Organometallics 21:39

    CAS  Google Scholar 

  122. Itokazu MK, Polo AS, de Faria DLA, Bignozzi CA, Iha NYM (2001) Inorg Chim Acta 313:149

    CAS  Google Scholar 

  123. Wenger OS, Henling LM, Day MW, Winkler JR, Gray HB (2004) Inorg Chem 43:2043

    CAS  Google Scholar 

  124. Yam VW-W, Yang Y, Zhang J, Chu BW-K, Zhu N (2001) Organometallics 20:4911

    CAS  Google Scholar 

  125. Sarto Polo AS, Itokazu MK, Frin KM, de Toledo Patrocinio AO, Iha NYM (2006) Coord Chem Rev 250:1669–1680

    Google Scholar 

  126. Sun S-S, Lees AJ (2000) J Am Chem Soc 122:8956

    CAS  Google Scholar 

  127. Blanco-Rodríguez AM, Towrie M, Vlček A Jr (2009) Dalton Trans. in press

    Google Scholar 

  128. Ko C-C, Kwok W-M, Yam VW-W, Phillips DL (2006) Chem Eur J 12:5840

    CAS  Google Scholar 

  129. MacQueen DB, Eyler JR, Schanze KS (1992) J Am Chem Soc 114:1897

    CAS  Google Scholar 

  130. Mecklenburg SL, Opperman KA, Chen P, Meyer TJ (1996) J Phys Chem 100:15145

    CAS  Google Scholar 

  131. Kalyanasundaram K, Grätzel M, Nazeeruddin MK (1992) Inorg Chem 31:5243

    CAS  Google Scholar 

  132. Bignozzi CA, Argazzi R, Garcia CG, Scandola F (1992) J Am Chem Soc 114:8727

    CAS  Google Scholar 

  133. Wang Y, Schanze KS (1994) Inorg Chem 33:1354

    CAS  Google Scholar 

  134. Luong JC, Nadjo L, Wrighton MS (1978) J Am Chem Soc 100:5790

    CAS  Google Scholar 

  135. Partigianoni CM, Chodorowski-Kimmes S, Treadway JA, Striplin D, Trammell SA, Meyer TJ (1999) Inorg Chem 38:1193

    CAS  Google Scholar 

  136. Batey HD, Whitwood AC, Duhme-Klair A-K (2007) Inorg Chem 46:6516

    CAS  Google Scholar 

  137. Reece SY, Seyedsayamdost MR, Stubbe J, Nocera DG (2006) J Am Chem Soc 128:13654

    CAS  Google Scholar 

  138. Reece SY, Nocera DG (2005) J Am Chem Soc 127:9448

    CAS  Google Scholar 

  139. Chen P, Curry M, Meyer TJ (1989) Inorg Chem 28:2271

    CAS  Google Scholar 

  140. Westmoreland TD, Le Bozec H, Murray RW, Meyer TJ (1983) J Am Chem Soc 105:5952

    Google Scholar 

  141. Chen P, Danielson E, Meyer TJ (1988) J Phys Chem 92:3708

    CAS  Google Scholar 

  142. Liard DJ, Vlček A Jr (2000) Inorg Chem 39:485

    CAS  Google Scholar 

  143. Liard DJ, Kleverlaan CJ, Vlček A Jr (2003) Inorg Chem 42:7995

    CAS  Google Scholar 

  144. She C, Guo J, Lian T (2007) J Phys Chem B 111:6903

    CAS  Google Scholar 

  145. Asbury JB, Hao E, Wang Y, Ghosh HN, Lian T (2001) J Phys Chem B 105:4545

    CAS  Google Scholar 

  146. Chen P, Westmoreland TD, Danielson E, Schanze KS, Anthon D, Neveux PE Jr, Meyer TJ (1987) Inorg Chem 26:1116

    CAS  Google Scholar 

  147. Chen P, Mecklenburg SL, Meyer TJ (1993) J Phys Chem 97:13126

    CAS  Google Scholar 

  148. Chen P, Mecklenburg SL, Duesing R, Meyer TJ (1993) J Phys Chem 97:6811

    CAS  Google Scholar 

  149. Ziessel R, Juris A, Venturi M (1997) Chem Commun:1593

    Google Scholar 

  150. Ziessel R, Juris A, Venturi M (1998) Inorg Chem 37:5061

    CAS  Google Scholar 

  151. Wang Y, Hauser BT, Rooney MM, Burton RD, Schanze KS (1993) J Am Chem Soc 115:5675

    CAS  Google Scholar 

  152. Wang Y, Schanze KS (1996) J Phys Chem 100:5408

    CAS  Google Scholar 

  153. Lucia LA, Wang Y, Nafisi K, Netzel TL, Schanze KS (1995) J Phys Chem 99:11801

    CAS  Google Scholar 

  154. Wang Y, Lucia LA, Schanze KS (1995) J Phys Chem 99:1961

    CAS  Google Scholar 

  155. Trammell S, Goodson PA, Sullivan BP (1996) Inorg Chem 35:1421

    CAS  Google Scholar 

  156. Lewis JD, Bussotti L, Foggi P, Perutz RN, Moore JN (2002) J Phys Phem A 106:12202

    CAS  Google Scholar 

  157. Lewis JD, Moore JN (2004) Dalton Trans:1376

    Google Scholar 

  158. Peacock AFA, Batey HD, Raendler C, Whitwood AC, Perutz RN, Duhme-Klair A-K (2005) Angew Chem Int Ed 44:1712 –1714

    CAS  Google Scholar 

  159. Blanco-Rodríguez AM, Gabrielsson A, Towrie M, Vlček A Jr manuscript in preparation

    Google Scholar 

  160. Towrie M, Parker AW, Vlček A Jr, Gabrielsson A, Blanco Rodriguez AM (2005) Appl Spectrosc 59:467

    CAS  Google Scholar 

  161. Reece SY, Seyedsayamdost MR, Stubbe J, Nocera DG (2007) J Am Chem Soc 129:13828

    CAS  Google Scholar 

  162. Patrocinio AOT, Iha NYM (2008) Inorg. Chem. 47: 10851

    Google Scholar 

  163. Kuimova MK, Alsindi WZ, Blake AJ, Davies ES, Lampus DJ, Matousek P, McMaster J, Parker AW, Towrie M, Sun X-Z, Wilson C, George MW (2008) Inorg. Chem. 47: 9857

    Google Scholar 

  164. Easun TL, Alsindi WZ, Towrie M, Ronayne KL, Sun X-Z, Ward MD, George MW (2008) Inorg. Chem. 47: 5071

    Google Scholar 

  165. Knight TE, Guo D, Claude JP, McCusker JK (2008) Inorg. Chem. 47: 7249

    Google Scholar 

Download references

Acknowledgments

The scientific contributions of all coworkers and collaborators involved in our research on rhenium photophysics and photochemistry is much appreciated: Ana Maria Blanco Rodríguez, Michael Busby, Anders Gabrielsson, Davina Liard, Ian Farrel (QMUL), Pavel Matousek and Mike Towrie (Rutherford Appleton Lab), Franti Hartl (Univ. Reading, UK and Univ. Amsterdam), the late Derk J. Stufkens (Univ. Amsterdam), Chantal Daniel (CNRS Strasbourg), Stanislav Záliš, Martin Hof and Jan Sýkora (J. Heyrovský Institute of Physical Chemistry, Prague), Majed Chergui and Andrea Cannizzo (EPFL, Switzerland), Harry B. Gray, Jay R. Winkler, Crystal Shih and Anna Katrine Museth (California Institute of Technology).Funding was provided by EPSRC, QMUL, STFC (CMSD43), European collaboration program COST D35, ESF-DYNA, and the Ministry of Education of the Czech Republic (1P05OC068).

Author information

Authors and Affiliations

  1. School of Biological and Chemical Sciences, Queen Mary, University of London, Mile End Road, London, E1 4NS, UK

    Antonín Vlček Jr

  2. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, Prague, Czech Republic

    Antonín Vlček Jr

Authors
  1. Antonín Vlček Jr
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Antonín Vlček Jr .

Editor information

Editors and Affiliations

  1. Dept. Chemistry, State University of New York, Binghamton, Binghamton, 13902-6016, U.S.A.

    Alistair J. Lees

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Vlček, A. (2009). Ultrafast Excited-State Processes in Re(I) Carbonyl-Diimine Complexes: From Excitation to Photochemistry. In: Lees, A. (eds) Photophysics of Organometallics. Topics in Organometallic Chemistry, vol 29. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_2009_4

Download citation

Publish with us

Policies and ethics

Search

Navigation