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PlatinumII Acetylide Photophysics

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Book cover Photophysics of Organometallics

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 29))

Abstract

The photophysics of PtII acetylide chromophores represents an important emergent area of research and development. The present review exclusively deals with photophysical processes in square planar PtII complexes of the general formulae: Pt(N^N)(C≡CR)2, [Pt(N^N^N)(C≡CR)]+, Pt(N^N^C)(C≡CR), trans-Pt(PR3)2(C≡CR)2, and cis-Pt(P^P)(C≡CR)2, where N^N is a bidentate 2,2’-bipyridine, N^N^N and N^N^C are tridentate polypyridines, PR3 is a monodentate phosphine and P^P is a bidentate phosphine ligand. These molecules exhibit a range of photophysical attributes depending upon the nature of the lowest electronic triplet excited state(s) which are either charge-transfer, ligand-localized, or an admixture of the two. Under special circumstances, intermolecular interactions further complicate the electronic structures of the ground and excited states and the resulting spectroscopy. Recent computational approaches emphasizing the successful application of DFT and TD-DFT methods towards understanding the absorption and emission processes of these chromophores are also presented.

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Acknowledgments

We gratefully acknowledge the following agencies for their generous support of our own research projects relevant to this review in PtII acetylide photophysics: the NSF (CAREER Award CHE-0134782, CHE-0719050, CBET-0731153), the AFOSR (FA9550-05-1-0276), the ACS-PRF (44138-AC3 and 36156-G6), and Bowling Green State University. We would also like to thank all of our collaborators worldwide for their intensity and strong intellectual contributions for work related to PtII acetylide photophysics. These individuals include Prof. Christopher J. Adams (Univ. Bristol), Prof. John R. Cable (BGSU), Dr. Thomas Cooper (AFRL), Dr. Evgeny Danilov (BGSU), Prof. Richard Eisenberg (Univ. Rochester), Prof. Joseph T. Hupp (Northwestern), Prof. David R. McMillin (Purdue), Prof. Alan A. Pinkerton (Univ. Toledo), Prof. Kirk S. Schanze (Univ. Florida), Prof. Julia A. Weinstein (Univ. Sheffield), and Dr. Raymond Ziessel (Strasbourg).

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Authors and Affiliations

  1. Department of Chemistry and Center for Photochemical Sciences, Bowling Green State University, Bowling Green, OH, 43403, USA

    Maria L. Muro, Aaron A. Rachford, Xianghuai Wang & Felix N. Castellano

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  1. Maria L. Muro
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  2. Aaron A. Rachford
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  3. Xianghuai Wang
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  4. Felix N. Castellano
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Correspondence to Maria L. Muro .

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Editors and Affiliations

  1. Dept. Chemistry, State University of New York, Binghamton, Binghamton, 13902-6016, U.S.A.

    Alistair J. Lees

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Muro, M.L., Rachford, A.A., Wang, X., Castellano, F.N. (2009). PlatinumII Acetylide Photophysics. In: Lees, A. (eds) Photophysics of Organometallics. Topics in Organometallic Chemistry, vol 29. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_2009_1

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