Abstract
During the past decade, atom transfer radical polymerization (ATRP) has had a tremendous impact on the synthesis of macromolecules with well-defined compositions, architectures, and functionalities. Structural features of copper(I) and copper(II) complexes with bidentate, tridentate, tetradentate, and multidentate nitrogen-based ligands commonly utilized in ATRP are reviewed and discussed. Additionally, recent advances in mechanistic understanding of copper-mediated ATRP are outlined.
Key Words
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Abbreviations
- ATRA:
-
Atom transfer radical addition
- TMC ATRA:
-
Transition metal-catalyzed atom transfer radical addition
- ATRP:
-
Atom transfer radical polymerization
- K ATRP :
-
Equilibrium constant for atom transfer
- k a :
-
Activation rate constant for atom transfer
- k d :
-
Deactivation rate constant for atom transfer
- bpy:
-
2,2'-Bipyridine
- dNbpy:
-
4,4'-Di(5-nonyl)-2,2'-bipyridine
- NPrPMI:
-
N-propyl(2-pyridyl)methanimine
- tpy:
-
2,2':6',2''-Terpyridine
- tNtpy:
-
4,4',4''-Tris(5-nonyl)-2,2':6',2''-terpyridine
- PMDETAN :
-
, N, N', N'', N''-Pentamethyldiethyelenetriamine
- HMTETA:
-
1,1,4,7,10,10-Hexamethyltriethylenetetramine
- Me6TREN:
-
Tris[2-(dimethylaminoethyl]amine
- TPMA:
-
Tris[(2-pyridyl)methyl]amine
- Me4CYCLAM:
-
1,4,8,11-Tetraaza-1,4,8,11-tetramethylcyclotetradecane
- TPEDAN :
-
, N, N', N'-Tetrakis(2-pyridylmethyl)ethylenediamine
- DMCBCy:
-
Dimethylated 1,8-ethylene cross-bridged 1,4,8,11-tetraazacyclotetradecane
- Sn(EH)2 :
-
Tin(II) 2-ethylhexanote
- MA:
-
Methyl acrylate
- Sty:
-
Styrene
- n-BAn :
-
-Butyl acrylate
- EBrIB:
-
Ethyl 2-bromoisobutyrate
- PEBr:
-
1-(Bromoethyl)benzene
- PECl:
-
1-(Chloroethyl)benzene
- BzBr:
-
Benzyl bromide
- MBrP:
-
Methyl 2-bromopropionate
- MClP:
-
Methyl 2-chloropropionate
- MClAc:
-
Methyl chloroacetate
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Pintauer, T., Matyjaszewski, K. (2009). Structural and Mechanistic Aspects of Copper Catalyzed Atom Transfer Radical Polymerization. In: Topics in Organometallic Chemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_2008_8
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DOI: https://doi.org/10.1007/3418_2008_8
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