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Catalytic Arylation and Vinylation Reactions Directed by Anionic Oxygen Functions via Cleavage of C – H and C – C Bonds

  • Tetsuya SatohEmail author
  • Masahiro MiuraEmail author
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 24)

Abstract

Aromatic compounds having oxygen-containing substituents such as phenols, phenyl ketones, benzyl alcohols, and benzoic acids undergo regioselective arylation and vinylation via C–H bond cleavage in the presence of transition-metal catalysts. The latter two substrates are also arylated and vinylated via C–C bond cleavage accompanied by liberation of ketones and CO2, respectively. Coordination of their anionic oxygen to the metal center is the key to activate the inert bonds effectively and regioselectively. The recent progress of these oxygen-directed reactions is summarized herein.

Arylation C–C bond cleavage C–H bond cleavage Palladium Vinylation 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  1. 1.Department of Applied Chemistry, Faculty of EngineeringOsaka UniversityOsaka 565-0871Japan

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