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Catalytic Addition of C – H Bonds to C – C Multiple Bonds

  • Fumitoshi Kakiuchi
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 24)

Abstract

During the last decade, catalytic functionalization of C–H bonds has become one of the most attractive research areas in modern organic synthesis. To date, many efficient catalytic reactions have been reported. In almost all of these reactions, heteroatom-directed C–H bond cleavage and/or C–C bond formation are quite important for attaining high regioselectivity and efficiency. In this chapter, several representative results concerning transition metal-catalyzed alkylation of C–H bonds with olefins, alkenylation with acetylenes, and carbonylation with olefins and carbon monoxides will be briefly reviewed.

Alkenylation Alkylation Carbonylation C–H bond cleavage Conversion of C–H to C–C 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  • Fumitoshi Kakiuchi
    • 1
  1. 1.Department of Chemistry, Faculty of Science and TechnologyKeio UniversityKanagawaJapan

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