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Chelation-Assisted Arylation via C–H Bond Cleavage

  • Lutz AckermannEmail author
Chapter
First Online:
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 24)

Abstract

Regioselectivity was achieved in transition-metal-catalyzed arylation reactions via C–H bond cleavage through the use of chelation-assistance. Palladium, rhodium, and ruthenium complexes proved useful for the development of broadly applicable methodologies for intermolecular direct arylation reactions. These include protocols for direct arylation reactions using aryl chlorides and tosylates as well as transformations that proceed through the cleavage of unactivated C(sp3)–H bonds.

Arylation Chelation Palladium Rhodium Ruthenium 
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© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  1. 1.Institut für Organische und Biomolekulare ChemieGeorg-August-Universität GöttingenGöttingenGermany

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