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Metallodendritic Exo-Receptors for the Redox Recognition of Oxo-Anions and Halides

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Dendrimer Catalysis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 20))

Abstract

Metallodendrimers terminated by redox-active transition-metal sandwiches or iron cluster groups are efficient redox exo-receptors for the recognition and sensing of various anions including oxo-anions and halides. The large size of higher-generation dendrimers ensures optimal adsorption on surfaces, a property that is used to derivatize Pt electrodes and provide re-usable sensors subsequent to washing the salt containing the anion bound by weak supramolecular interactions.

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Acknowledgments

This feature article is dedicated to the unforgettable memory of Professor Olivier Kahn, our distinguished friend and colleague from the University Bordeaux I who passed away in December 1999. The chemistry carried out in our laboratory and reviewed in this article was possible thanks to the ideas and efforts of the students and colleagues cited in the references. Financial support from the Institut Universitaire de France (DA, IUF), the Centre National de la Recherche Scientifique (CNRS), the University Bordeaux I and the Ministère de la Recherche et de la Technologie (M-C D, MRT, thesis grant) is also gratefully acknowledged.

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  1. Nanosciences and Catalysis Group, LCOO, UMR CNRS No. 5802, Université Bordeaux I, 351 Cours de la Libération, 33405, Talence Cedex, France

    Didier Astruc, Marie-Christine Daniel & Jaime Ruiz

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  1. Didier Astruc
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  2. Marie-Christine Daniel
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Correspondence to Didier Astruc .

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Lutz H. Gade

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Astruc, D., Daniel, MC., Ruiz, J. (2006). Metallodendritic Exo-Receptors for the Redox Recognition of Oxo-Anions and Halides. In: Gade, L.H. (eds) Dendrimer Catalysis. Topics in Organometallic Chemistry, vol 20. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_034

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