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Hydroxy- and Alkoxycarbonylations of Alkenes and Alkynes

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Catalytic Carbonylation Reactions

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 18))

Abstract

The use of Co building block in presence of water or an alcohol to functionalise alkenes by hydroxycarbonylation or alkoxycarbonylation reactions is reviewed in this chapter. The hydroxyl groups can be present in the substrate itself so cascade reactions can occur. Palladium precursors are largely involved in these reactions and this analysis of the literature focuses on the mechanisms involving Pd(0), Pd(H)(X)L2, PdX2 and an oxidant like CuCl systems. Introduction of chiral L or L2 ligands or even the presence of chiral carbon atoms in the substrate lead to asymmetric carbonylation reactions.

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  1. Laboratoire de Catalyse Chimie Fine et Polymères, Ecole Nationale Supérieure d'Ingénieurs en Arts Chimiques Et Technologiques (ENSIACET), 118 Route de Narbonne, 31077, Toulouse cedex, France

    Philippe Kalck, Martine Urrutigoïty & Odile Dechy-Cabaret

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  1. Philippe Kalck
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  2. Martine Urrutigoïty
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  3. Odile Dechy-Cabaret
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Correspondence to Philippe Kalck .

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Kalck, P., Urrutigoïty, M., Dechy-Cabaret, O. (2006). Hydroxy- and Alkoxycarbonylations of Alkenes and Alkynes. In: Beller, M. (eds) Catalytic Carbonylation Reactions. Topics in Organometallic Chemistry, vol 18. Springer, Berlin, Heidelberg . https://doi.org/10.1007/3418_018

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