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Palladium Catalyzed Cascade Reactions Involving π-Allyl Palladium Chemistry

  • Nitin T. Patil
  • Yoshinori YamamotoEmail author
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 19)

Abstract

Palladium-catalyzed cascade reactions have gained steadily increasing importance over the last decade. The important factor in these reactions is the catalytic generation of π-allyl palladium intermediates which further undergo a variety of reactions. π-Allyl palladium complexes can be easily formed by the treatment of allylic substrates with Pd(0). A π-allyl palladium complexes on treatment with allylic metal species produce bis π-allyl palladium complex. In this review, the palladium catalyzed cascade reactions involving π-allyl palladium chemistry is described. The first part deals with catalytic reactions involving π-allyl palladium complexes as an intermediate, while the second part features catalytic reactions involving bis π-allyl palladium complex as an intermediate.

Cascade reaction Palladium π-Allyl palladium complex Bis π-allyl palladium complex Synthetic strategies Heterocycles 

Abbreviations

Ac

acetyl

Ar

aryl

dba

dibenzylideneacetone

dppf

1,1′-bis(diphenylphosphino)ferrocene

dppp

1,3-bis(diphenylphosphino)propane

dppe

1,2-bis(diphenylphosphino)ethane

ee

enantiomer excess

TBAB

tetrabutylammonium bromide

THF

tetrahydrofuran

TMS

trimethylsilyl

Ts

tosyl

rt

room temperature

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Authors and Affiliations

  1. 1.Department of Chemistry, Graduate School of ScienceTohoku UniversitySendaiJapan

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