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Recent Advances in the Study of Synthetic Polyampholytes in Solutions

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Polymer Latexes - Epoxide Resins - Polyampholytes

Part of the book series: Advances in Polymer Science ((POLYMER,volume 144))

Abstract

This article reviews the theoretical and experimental material accumulated in recent years on water-soluble and water-swelling polyampholytes of integral and pendant types. The theory of polyampholytes in comparison with experimental results, acid-base equilibrium, hydrodynamic, conformational, and the molecular and colloidal properties of amphoteric copolymers are considered. The responsibility of Coulomb forces, hydrogen bonds and hydrophobic interactions in the formation of compact structures is shown. Basic attention is paid to the specific structure and behaviour of polyampholytes at or near the isoelectric point (IEP), in particular to the “forcing out” phenomenon found at the IEP. The ability of polyampholytes to associate with various low- and high-molecular-weight substances as well as to be absorbed on dispersed particles is discussed. An attempt to show the closeness of structural organization or molecular recognition of synthetic polyampholytes to natural ones is undertaken.

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  1. Department of High Molecular Compounds, Faculty of Chemistry, Kazak State National University, Karasai Batyra Str.95, 480012, Almaty, Republic of Kazakhstan

    Sarkyt E. Kudaibergenov

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Kudaibergenov, S.E. (1999). Recent Advances in the Study of Synthetic Polyampholytes in Solutions. In: Polymer Latexes - Epoxide Resins - Polyampholytes. Advances in Polymer Science, vol 144. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68384-4_3

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