Abstract
This review is concerned with the syntheses, electronic and molecular structures, and properties of all types of presently known technetium cluster compounds with acido-ligands. Examination of the literature shows that technetium is not only a typical cluster-forming agent, but also has a number of specific “anomalous” cluster-forming properties. These properties may be interpreted in terms of a greater ability of the outer diffuse 5s(5p)-AO's to participate in additional M-M bonding in technetium acido-clusters, compared to the situation in analogous clusters of other d-transition elements. Theoretical interpretations of the electronic and molecular structures and properties of technetium clusters are supported by experimental data (X-ray diffraction analysis, magnetochemistry, and optical, ESR, X-ray emission, and X-ray photoelectron spectroscopies). The observed increased stability of technetium clusters with an odd number of “metallic” electrons and a decrease in the effective charge on technetium atoms upon formation of M-M bonds are discussed.
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8 References
Cotton FA, Walton RA (1982) Multiple Bonds between Metal Atoms. Wiley, New York
Spitsyn VI, Kuzina AF (1981) Tekhnetsiy Nauka, Moscow
Deutsch E (1989) J Nuclear Medicine 33: 279
Deutsch E, Libson K, Vanderheyden J-L (1990) in: Nicolini M, Bandoli G, Mazzi U (eds) Technetium and rhenium in chemistry and nuclear medicine, vol 3. Raven Press, New York, p 13
Johnson BFG (ed) (1980) Transition Metal Clusters. Wiley, New York
Gubin SP (1984) Vestnik Akad Nauk SSSR 1: 55
Gubin SP (1987) Zhurn Mendeleev Vses Khim Obsh 32: 3
Gubin SP (1987) Khimiya klasterov. Nauka, Moscow, p 263
Kryutchkov SV (1983) Phisico-khimicheskie svoystva soedineniy technetsiya. Doctor Thesis, Institute of Physical Chemistry, USSR Academy of Sciences, Moscow
Kryutchkov SV (1985) Koord Khimiya 11: 631
Spitsyn VI, Kuzina AF, Kryutchkov SV (1985) Uspekhi Khimii 54: 637
Kryutchkov SV, Grigoriev MS, German KE (1990) in: Nicolini M, Bandoli G, Mazzi U (eds) Technetium and rhenium in chemistry and nuclear medicine, vol 3. Raven Press, New York, p 253
Kryutchkov SV, Kuzina AF, German KE (1990) in: Nicolini M, Bandoli G, Mazzi U (eds) Technetium and rhenium in chemistry and nuclear medicine, vol 3. Raven Press, New York, p 275
Kryutchkov SV (1990) in: Abstracts of posters of XXIII Intern conf coord chem 13–18 August 1990, Gera, DDR, vol 1 P 5–7
Kryutchkov SV (1991) Khimiya klasternikh soedineniy technetsiya. Second Doctoral Thesis, Institute of Physical Chemistry, Russian Academy of Sciences, Moscow
Tronev VG, Bondin SM (1952) Dokl Akad Nauk SSSR 86: 87
Kotel'nikova AS, Tronev VG (1958) Zhurn Neorgan Khimii 3: 1008
Babeshkina GK, Tronev VG (1962) Zhurn Neorgan Khimii 7: 215
Kotel'nikova AS, Vinogradova GA (1963) Dokl Akad Nauk SSSR 152: 621
Koz'min PA, Kuznetsov VG (1963) in: IV Vsesoyuznoe soveshanie po kristallokhimii, 19–23 December 1961, Abstracts of Papers, Shtiintsa, Kishinev, p 74
Kuznetsov VG, Koz'min PA (1963) Zhurn Strukt Khimii 4: 55
Glinkina MI, Kuzina AF, Spitsyn VI (1973) Zhurn Neorgan Khimii 18: 403
Bertrand JA, Cotton FA, Dollase WA (1963) J Am Chem Soc 85: 1349
Eakins JD, Huphreys DG, Mellish CE (1963) J Chem Soc 6012
Robinson WT, Fergusson JE, Penfold BR (1963) Proc Chem Soc 116
Cotton FA, Curtis NF, Harris CB, Johnson BFG, Lippard SJ, Mague JT, Robinson WR, Wood JS (1964) Science 145(3638): 1305
Cotton FA, Haas TE (1964) Inorg Chem 3: 10
Cotton FA, Curtis NF, Johnson BFG, Robinson WR (1965) Inorg Chem 4: 326
Cotton FA (1969) Accounts Chem Res 2: 240
Cotton FA, Pedersen E (1975) Inorg Chem 14: 383
Cotton FA (1975) Chem Soc Rev 4: 27
Schwochau K, Hedwig K, Schenk HJ (1977) Inorg Nucl Chem Letters 13: 77
Cotton FA (1978) Accounts Chem Res 11: 225
Preetz W, Peters G (1980) Z Naturforsch 35b: 797
Cotton FA, Daniels L, Davison A, Orvig C (1981) Inorg Chem 20: 3051
Kotel'nikova AS, Misailova TV, Babichevskaya IZ, Lebedev VG (1978) Zhurn Neorgan Khimii 23: 2402
Koz'min PA, Surazhskaya MD, Larina TB, Kotel'nikova AS, Ahmedov EF (1979) Zhurn Neorgan Khimii 24: 3383
Shtemenko AV, Kotel'nikova AS, Koz'min PA, Surazhskaya MD, Larina TB (1980) Zhurn Neorgan Khimii 25: 2300
Ahmetov EL, Kotel'nikova AS, Efstaf'eva ON (1981) Koord Khimiya 7: 568
Koz'min PA, Surazhskaya MD, Larina TB, Shtemenko AV, Golovaneva NF (1981) Koord Khimiya 7: 792
Koz'min PA, Surazhskaya MD, Larina TB, Shtemenko AV, Kotel'nikova AS (1981) Koord Khimiya 7: 1271
Spitsyn VI, Kuzina AF, Oblova AA, Belyaeva LI (1977) Dokl Akad Nauk SSSR 237: 1126
Spitsyn VI, Kuzina AF, Oblova AA, Kryutchkov SV, Belyaeva LI (1977) Dokl Akad Nauk SSSR 237: 1412
Spitzin VI, Kryutchkov SV, Grigoriev MS, Kuzina AF (1988) Z anorg allg Chem 563: 136
Cotton FA, Gage LD (1977) Nouv J Chim 1: 441
Cotton FA, Fanwick PE, Gage LD (1980) J Am Chem Soc 102: 1570
Zaytseva LL, Kotel'nikova AS, Rezvov AA (1980) Zhurn Neorgan Khimii 25: 2624
Spitsyn VI, Bairl B, Kryutchkov SV, Kuzina AF, Varen M (1981) Dokl Akad Nauk SSSR 256: 608
Kryutchkov SV, Kuzina AF, Spitsyn VI (1982) Dokl Akad Nauk SSSR 266: 127
Kryutchkov SV, Grigoriev MS, Yanovskiy AI, Struchkov YuT, Spitsyn VI (1987) Dokl Akad Nauk SSSRI 297: 867
Spitsyn VI, Kuzina AF, Oblova AA, Kryutchkov SV, German KE, Belyaeva LI (1982) in: Abstracts of Papers XXII International Conference on Coordination Chemistry, 1982, Budapest, p 811
Spitsyn VI, Kuzina AF, Kryutchkov SV (1980) Zhurn Neorgan Khimii 25: 741
Kryutchkov SV, Kuzina AF, Spitzin VI (1988) Z anorg allg Chem 563: 153
Bürgi HB, Anderegg G, Blauenstein P (1981) Inorg Chem 20: 3829
Anderegg G, Muller E, Zollinger K, Burgi HB (1983) Helv Chim Acta 66: 1593
Colmanet SF, Mackay MF (1987) J Chem Soc, Chem Commun 705
Linder KE, Dewan JC, Davison A (1989) Inorg Chem 28: 3820
Baturin NA, German KE, Grigoriev MS, Kryutchkov SV (1991) Koord Khimiya 17: 1375
Kryutchkov SV, Simonov AE (1990) Koord Khimiya 16: 339
Cotton FA, Shive LW (1975) Inorg Chem 14: 2032
Cotton FA, Bratton WK (1965) J Am Chem Soc 87: 921
Bratton WK, Cotton FA (1970) Inorg Chem 9: 780
Cotton FA, Davison A, Day VW, Fredich MF, Orvig C, Swanson R (1982) Inorg Chem 21: 1211
Grigoriev MS, Kryutchkov SV, Struchkov YuT, Yanovskiy AI (1990) Koord Khimiya 16: 90
Koz'min PA, Larina TB, Surazhskaya MD (1981) Koord Khimiya 7: 1719
Koz'min PA, Larina TB, Surazhskaya MD (1982) Koord Khimiya 8: 851
Koz'min PA, Larina TB, Surazhskaya MD (1983) Koord Khimiya 9: 1114
Kryutchkov SV, Grigoriev MS, Kuzina AF, Gulev BF, Spitsyn VI (1986) Dokl Akad Nauk SSSR 288: 389
Cotton FA, Daniels LM, Falvello LR, Grigoriev MS, Kryutchkov SV (1991) Inorg Chim Acta 189: 53
Koz'min PA, Larina TB, Surazhskaya MD (1983) Dokl Akad Nauk SSSR 271: 1157
Koz'min PA, Surazhskaya MD, Larina TB (1985) Koord Khimiya 11: 1559
German KE, Kryutchkov SV, Kuzina AF, Spitsyn VI (1986) Dokl Akad Nauk SSSR 288: 381
Kryutchkov SV, Grigoriev MS, Kuzina AF, Gulev BF, Spitsyn VI (1986) Dokl Akad Nauk SSSR 288: 893
Koz'min PA, Larina TB, Surazhskaya MD (1987) Koord Khimiya 13: 415
Kryutchkov SV, Grigoriev MS, Yanovskiy AI, Struchkov YuT., Spitsyn VI (1988) Dokl Akad Nauk SSSR 301: 618
Kryutchkov SV, Grigoriev MS, Kuzina AF, Gulev BF, Spitsyn VI (1986) Dokl Akad Nauk SSSR 290: 865
Grigoriev MS, Kryutchkov SV (1993) Radiochim Acta 63: 187
Hileman JC, Huggins DK, Kaesz HD (1961) J Am Chem Soc 63: 2953
Cotton FA, Pedersen E (1975) Inorg Chem 14: 383
Kryutchkov SV, Kuzina AF, Spitsyn VI (1983) Zhurn Neorgan Khimii 28: 1984
Koz'min PA, Novitskaya GN (1972) Zhurn Neorgan Khimii 17: 3138
Koz'min PA, Novitskaya GN (1975) Koord Khimiya 1: 248
Yukhnevich GV (1965) in: Trudy komissii po spectroscopii AN SSSR, vol 1. VINITY, Moscow, p 235
Basile A, La Bonville P, Ferraro JR, Williams J (1974) J Chem Phys 60: 1981
Izmaylov NA (1961) Elektrokhimiya rastvorov, Khimiya, Moscow
Lundren JO, Williams JM (1973) J Chem Phys 58: 788
Kryutchkov SV, Simonov AE (1987) Izvestiya AN SSSR, ser. Khim 2140
Cotton FA, Gage LD (1979) Inorg Chem 18: 1716
Koz'min PA, Surazhskaya MD (1980) Koord Khimiya 6: 653
Koz'min PA (1981) Koord Khimiya 7: 659
Koz'min PA, Surazhskaya MD, Larina TB, Kotel'nikova AS, Misailova TV (1980) Koord Khimiya 6: 1256
German KE, Grigoriev MS, Kuzina AF, Spitsyn VI (1987) Zhurn Neorgan Khimii 32: 1089
Spitsyn VI, Kuzina AF, German KE, Grigoriev MS (1987) Dokl Akad Nauk SSSR 293: 101
Meyer G, Hoppe R (1976) Z anorg allgew Chem 420: 40
German KE, Grigoriev MS, Kuzina AF, Gulev BF, Spitsyn VI (1986) Dokl Akad Nauk SSSR 287: 650
Cotton FA, Frenz BA, Shive W (1975) Inorg Chem 14: 649
Calvo C, Jayadevan NC, Lock CJL, Restivo R (1970) Canad J Chem 48: 219
Kannellakopulos B, Nuber B, Raptis K, Ziegler ML (1989) Angew Chem 101: 1055
Kannellakopulos B, Nuber B, Raptis K, Ziegler ML (1989) Angew Chem Int Ed Engl 28: 1055
Magneli A, Andersson G (1955) Acta Chem Scand 9: 1378
Koz'min PA, Larina TB, Surazhskaya MD (1982) Dokl Akad Nauk SSSR 265: 1420
Gerasimov VN, Kryutchkov SV, Kuzina AF, Kulakov VM, Pirozhkov SV, Spitsyn VI (1982) Dokl Akad Nauk SSSR 286: 148
Gerasimov VN, Kryutchkov SV, German KE, Kulakov VM, Kuzina AF (1990) in: Nicolini M, Bandoli G, Mazzi U (eds) Technetium and rhenium in chemistry and nuclear medicine, vol 3. Raven Press, New York, p 231
Kryutchkov SV, Grigoriev MS, Kuzina AF, Spitsyn VI (1987) Zhurn Neorgan Khimii 32: 2944
Kryutchkov SV, Grigoriev MS, Kuzina AF, Spitsyn VI (1987) Zhurn Neorgan Khimii 32: 2953
Wheeler R, Hoffmann R (1986) Angew Chem Int Ed Engl 25: 822
Wheeler R, Hoffmann R (1986) J Am Chem Soc 108: 6605
Antipov VN, Kryutchkov SV, Gerasimov VN, Grigoriev MS, Kazin PE, Kharitonov VV, Maksimov VG, Moisa VS, Sergeev VV, Yurik TK (1994) Radiochim Acta 64: 191
Koz'min PA, Kotel'nikova AS, Larina TB, Mekhtiev MM, Surazhskaya MD, Bagirov ShA, Osmanov NS (1987) Dokl Akad Nauk SSSR 295: 647
Koz'min PA, Kotel'nikova AS, Surazhskaya MD, Osmanov RS, Larina TB, Abbassova TA, Mekhtiev MM (1989) Koord Khimiya 15: 1216
Koz'min PA, Osmanov RS, Larina TB, Kotel'nikova AS, Surazhskaya MD, Abbassova TA (1989) Dokl Akad Nauk SSSR 306: 378
Osmanov RS, Kotel'nikova AS, Surazhskaya MD, Larina TB, Abbassova TA, Koz'min PA (1989) Koord Khimiya 15: 1340
Kryutchkov SV, Rakytin YuV, Kazin PE, Zhirov AI, Konstantinov NYu (1990) Koord Khimiya 16: 1230
Koltunov VS, Gomonova TV, Shapovalov MP, Abramova IG (1988) Radiokhimiya 30: 751
Huber EW, Heinemen WR, Deutsch E (1987) Inorg Chem 26: 3718
Chisholm MH, Cotton FA (1978) Accounts Chem Res 11: 356
Chisholm MH, Kirpatrick CE, Huffman JC (1981) Inorg Chem 20: 871
Kryutchkov SV, Kuzina AF, Spitsyn VI (1986) Dokl Akad Nauk SSSR 287: 1400
McGinnis RN, Ryan TR, McCarley RE (1978) J Am Chem Soc 100: 7900
Aufdembrink BA, McCarley RE (1986) J Am Chem Soc 108: 2474
Oblova AA, Kuzina AF, Belyaeva LI, Spitsyn VI (1982) Zhurn Neorgan Khimii 27: 2814
Simonov AE (1986) in: I Moskovskaya konferentsiya molodich uchenich po radiokhimii, May 1986, Abstracts of Papers, Inst Phys Chem Russian Acad. Sci., Moscow, p 36
Spitsyn VI, Kuzina AF, Kryutchkov SV, Simonov AE (1987) Zhurn Neorgan Khimii 32: 2180
Kryutchkov SV, German KE, Simonov AE (1991) Koord Khimiya 17: 480
Vinogradov IV, Zaytseva LL, Konarev MN, Shepel'kov SV (1980) in: I Vsesoyuznoye soveshanie “Poluchenie i videlenie radioaktivnikh izotopov” (July 1980, Tashkent). Press FAN, Tashkent, p 33
Vinogradov IV, Konarev MN, Zaytseva LL, Shepel'kov SV (1976) Zhurn Neorgan Khimii 21: 131
Makarov LL, Kryutchkov SV, Zaytsev YuM, Sablina NO, German KE, Kuzina AF (1990) in: Nicolini M, Bandoli G, Mazzi U (eds) Technetium and rhenium in chemistry and nuclear medicine, vol 3. Raven Press, New York, p 265
Antipov VN, Kryutchkov SV, Gerasimov VN, Grigoriev MS, Kazin PE, Kharitonov VV, Maksimov VG, Moisa VS, Sergeev VV, Yurik TK (1993) in: Abstracts of Reports of Topical Symposium on the Behavior and Utilisation of Technetium'93, 18–20 March 1993, Tohoku University, Sendai, Japan, report No 1-P-24, p 56
Grigoriev MS, Kryutchkov SV (1993) in: Abstracts of Reports of Topical Symposium on the Behavior and Utilisation of Technetium'93, 18–20 March 1993, Tohoku University, Sendai, Japan, report No 3-I-2, p 23
Huber H, Kundig EP, Moskovits M, Ozin GA (1975) J Am Chem Soc 97: 2097
Kundig EP, Moskovits M, Ozin GA (1975) Nature 254(5500): 503
Busby R, Klotzbucher W, Ozin GA (1976) J Am Chem Soc 98: 4013
Ozin GA (1976) Appl Spectrosc 30: 573
Ford TA, Huber H, Klotzbucher W, Kundig EP, Moskovits M, Ozin GA (1977) J Chem Phys 66: 524
Klotzbucher W, Ozin GA (1977) Inorg Chem 16: 984
Klyagina AP, Gutsev GL, Fursova VD, Levin AA (1984) Zhurn Neorgan Khimii 29: 2765
Klyagina AP, Levin AA (1984) Koord Khimiya 10: 579
Weltner W, Van Zee RJ (1984) Ann Rev Phys Chem 35: 291
Kostikova GP, Korol'kov DV (1985) Uspekhi Khimii 54: 591
Morse MD (1986) Chem Rev 86: 1049
Klyagina AP, Fursova VD, Levin AA, Gutsev GL (1987) Dokl Akad Nauk SSSR 292: 122
Kryutchkov SV, Mironov VS, Antipov BG, Plekhanov YuV (1991) Metallorgan Khimiya 14: 26
Kostikova GP, Kostikova YuP, Troyanov SI, Korol'kov DV (1978) Inorg Chem 17: 2279
Bursten BE, Cotton FA (1980) Faraday Discuss R Chem Soc Faraday Symp (No 14) 180
Bursten BE, Cotton FA, Hall MB (1980) J Am Chem Soc 102: 6348
Voronovitch NS, Zacheslavskaya RH, Korol'kov DV (1977) Vestnik LGU, ser Phys khim (No 4) 69
Rakytin YuV, Kryutchkov SV, Alexandrov AI, Kuzina AF, Nemtsev NV, Ershov BG, Spitsyn VI (1983) Dokl Akad Nauk SSSR 269: 1123
Rakytin YuV, Nefedov VI (1985) Zhurn Neorgan Khimii 29: 510
Cotton FA, Kalbacher B (1977) Inorg Chem 16: 2386
Nefedov VI, Kozmin PA (1982) Inorg Chim Acta Letters 64: L177
Cotton FA, Fanwick PE, Gage LD, Kalbacher B, Martin DS (1977) J Am Chem Soc 99: 5642
Noodleman L, Norman JG (1979) J Chem Phys 70: 4903
Benard M (1978) J Am Chem Soc 100: 2354
Mello PC, Edwards WD, Zarner MC (1982) J Am Chem Soc 104: 1440
Etkins P (1977) Kvanty. Spravochnik kontseptsiy. Mir, Moscow
Norman JG, Kolari HJ, Gray HB, Trogler WC (1977) Inorg Chem 16: 987
Burstein BE, Cotton FA, Fanwick PE, Stanley GG, Walton RA (1983) J Am Chem Soc 105: 2606
German KE, Mironov VS (1986) in: I Moskovskaya konferentsiya molodich uchenich po radiokhimii, May 1986, Abstracts of Papers, Inst Phys Chem, Russian Acad Sci, Moscow, p 34
Cotton FA, Frenz BA, Ebner JR, Walton RA (1976) Inorg Chem 15: 1630
Cotton FA, Dunbar KR, Falvello LR, Tomas M, Walton RA (1983) J Am Chem Soc 105: 4950
Cotton FA, Stanley GG, Walton RA (1978) Inorg Chem 17: 2099
Cotton FA, Extine MW (1978) J Am Chem Soc 100: 3788
Cotton FA, Ilsley WH, Kaim W (1980) J Am Chem Soc 102: 1918
Cotton FA, Thompson JL (1980) Inorg Chim Acta Letters 44: L247
Cotton FA, Thompson JL (1980) J Am Chem Soc 102: 6437
Fanwick PE, King MK, Tetrick SM, Walton RA (1985) J Am Chem Soc 107: 5009
Cotton FA (1983) Chem Soc Rev (London) 12: 35
Missner H, Korol'kov DV (1972) Zhurn Strukt Khimii 13: 689
Shustorovich EM, Korol'kov DV (1972) Zhurn Strukt Khimii 13: 682
Shaik S, Hoffmann R, Fisel CR, Summerville RH (1980) J Am Chem Soc 102: 4555
Spitsyn VI, Kazin PE, Subbotin MYu, Aslanov LA, Zelentsov VV, Zhirov AI, Felin MG (1986) Dokl Akad Nauk SSSR 287: 134
Kalinnikov VT, Rakytin YuV (1980) Vvedenie v magnetokhimiyu. Metod staticheskoy magnitnoy vospriimchvosty. Nauka, Moscow
Bursten BE, Cotton FA, Stanley GG (1980) Israel J Chem 19: 132
Manning MC, Trogler WC (1981) Coord Chem Rev 38: 89
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Kryutchkov, S.V. (1996). Chemistry of technetium cluster compounds. In: Yoshihara, K., Omori, T. (eds) Technetium and Rhenium Their Chemistry and Its Applications. Topics in Current Chemistry, vol 176. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-59469-8_7
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