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Thermodynamics of charged interfaces

  • Part II Plenary Lectures
  • Conference paper
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Capillarity Today

Part of the book series: Lecture Notes in Physics ((LNP,volume 386))

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Abstract

Electrical double layers on rutile (TiO2) and haematite (α-Fe2O3) are studied thermodynamically. Surface charges and enthalpies of double layer formation, measured as a function of pH, salt concentration and temperature are the basic data. In the analysis, distinction is made between specific and generic observations. Consistent enthalpies of proton adsorption have been established. For the oxides mentioned, the electrical contribution to the enthalpy of double layer formation is negligibly small.

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References

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Authors and Affiliations

  1. Department of Physical and Colloid Chemistry, Dreijenplein 6, 6603, HB Wageningen, The Netherlands

    prof. J. Lyklema

Authors
  1. prof. J. Lyklema
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Editor information

G. Pétré A. Sanfeld

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© 1991 Springer-Verlag

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Lyklema, J. (1991). Thermodynamics of charged interfaces. In: Pétré, G., Sanfeld, A. (eds) Capillarity Today. Lecture Notes in Physics, vol 386. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-54367-8_50

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  • DOI: https://doi.org/10.1007/3-540-54367-8_50

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-54367-1

  • Online ISBN: 978-3-540-47585-9

  • eBook Packages: Springer Book Archive

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