Abstract
Random mixing solution and organized solution are entirely different in many respects. Ideal solution is the ideal case of randomly mixed solutions but not organized solution. There is a need to introduce a new concept “Ideal Organized Solution” as an ideal case of organized solution. If solute satisfies the necessary and sufficient conditions for organization, it will be self-organized from the beginning. Classical thermodynamics will well explain self-organized systems.
I would like to quote Albert Einstein's saying20 “A theory is the more impressive the greater the simplicity of its premises, the more different kinds of things it relates, and the more extended its area of applicability. Therefore the deep impression that classical thermodynamics made upon me. It is the only physical theory of universal content which I am convinced will never be overthrown, within the framework of applicability of its basic concepts.”
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References
Shinoda, K. J. Phys. Chem. 1985, 89, 2429.
Jonsson, B.; Wennerstrom, H. J. Phys. Chem, 1987, 91, 338.
Stilbs, P.; Lindman, B. Progr. Colloid Polymer Sci. 1984, 69, 39.
Lindman, B.; Stilbs, P. Chapter 7 in Microemulsion Systems Edited by Rosano, H. L.; Clausse Marc, Marcel Dekker, Inc. 1987, 129–143.
Lindblom, G.; Larsson, K.; Johansson, L.; Fontell, K.; Forsen, S. J. Am. Chem. Soc. 1979, 101, 5465.
Friberg, S.; Larsson, K. “Advances in Liquid Crystals” 1976, 12, 173.
Andersson, S.; Hyde, S. T.; Larsson, K.; Lidin, S. Chemical Review, 1988, 88, 221.
Larsson, K. J. Phys. Chem. 1989, 93, 7304.
Shinoda, K. Pure & Appl. Chem.. 1988, 60, No 10, 1493.
Miller, D. D.; Bellare, J. R.; Evans, D. F.; Talmon, Y.; Ninham, B. W. J. Phys. Chem.. 1987, 91, 674.
Evans, D.F. Langmuir, 1988, 4, 3.
Shinoda, K. J. Phys. Chem. 1977, 81, 1300.
Kodama, M. Thermochimica Acta, 1986, 109, 81.
Kodama, M.; Seki, S. Progr. Colloid Polymer Sci. 1983, 68, 158.
Hill T. L. ”Thermodynamics of Small Systems, Vol. 1 & 2, Benjamin, New York, 1963 & 1964.
Hall, D. G.; Pethica, B., Chapter 16 in “Non-ionic Surfactants” edited by Schick M. J. Marcel Dekker Inc. 1967.
Fig. 3 in Ref. 1.
Clunie, J. S.; Goodman, J. F.; Symons, P. C. Trans. Faraday Soc. 1969, 65, 287.
Shinoda, K. J.Colloid & Interface Sci., 1971, 34, 278.
Einstein, A. “Autobiographisches” in “Albert Einstein: Philosopher Scientist” edit. P. A. Schilpp Tutor Publ. Co.N.Y. 2nd Edition 1951.
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© 1991 Springer-Verlag
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Shinoda, K. (1991). The necessity of ideal organized solution concept: The comparison of ideal solution and ideal organized solution. In: Pétré, G., Sanfeld, A. (eds) Capillarity Today. Lecture Notes in Physics, vol 386. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-54367-8_48
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DOI: https://doi.org/10.1007/3-540-54367-8_48
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