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Photoinduced Electron Transfer III pp 219–255Cite as

Contact and solvent-separated radical ion pairs in organic photochemistry

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Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 159))

Abstract

Radical ion pairs play an important role in photoinduced electron transfer (PET) processes. Several types of them may exist and it will be shown in this article that contact ion pairs (CIPs) and solvent-separated ion pairs (SSIPs) can be differentiated by various experimental methods. Moreover, their controlled formation facilitates the control of chemical reactions. Although this review is by no means exhaustive, it is hoped that interest in the fundamental mechanistic aspects of PET processes in homogeneous media as well as in their synthetic applications will arise.

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  1. Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Orléansring 23, D-4400, Münster

    Jochen Mattay & Martin Vondenhof

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  1. Jochen Mattay
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Mattay, J., Vondenhof, M. (1991). Contact and solvent-separated radical ion pairs in organic photochemistry. In: Mattay, J. (eds) Photoinduced Electron Transfer III. Topics in Current Chemistry, vol 159. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-53257-9_5

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