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Flow of polymerizing liquids

  • A. Ya. Malkin
  • P. V. Zhirkov
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 95)

Abstract

The present work is a review of a particular field of polymer science which is developing fast and is at the interface of rheology, chemical hydrodynamics, macrokinetics, and the kinetics of polymerization processes. It involves the analysis of the way the viscosity growth affects a chemical reaction, i.e. the hydrodynamic, thermal, and concentration fields during polymerization.

In this review, the rheokinetic approach is presented, complete mathematical and physical statements of the problem are given, and the operation of a tubular polymerization reactor is analyzed as an example. The fundamental necessity of using the rheokinetic approach, whenever there is a sharp growth in the viscosity, is demonstrated. The trends of further investigation are presented.

Keywords

Flow Velocity Pressure Drop Polymerization Process Stir Tank Reactor Tubular Reactor 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1990

Authors and Affiliations

  • A. Ya. Malkin
    • 1
  • P. V. Zhirkov
    • 2
  1. 1.Research Institute of Plastics, USSR 111 112Moscow
  2. 2.Academy of Sciences of USSR, Institute of Structural Macrokinetics, USSRMoscow District, Chernogolovka

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