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Flow of polymerizing liquids

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Polymer Physics

Part of the book series: Advances in Polymer Science ((POLYMER,volume 95))

Abstract

The present work is a review of a particular field of polymer science which is developing fast and is at the interface of rheology, chemical hydrodynamics, macrokinetics, and the kinetics of polymerization processes. It involves the analysis of the way the viscosity growth affects a chemical reaction, i.e. the hydrodynamic, thermal, and concentration fields during polymerization.

In this review, the rheokinetic approach is presented, complete mathematical and physical statements of the problem are given, and the operation of a tubular polymerization reactor is analyzed as an example. The fundamental necessity of using the rheokinetic approach, whenever there is a sharp growth in the viscosity, is demonstrated. The trends of further investigation are presented.

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Authors and Affiliations

  1. Research Institute of Plastics, USSR 111 112, Perovskii pr. 35, E-112, Moscow

    A. Ya. Malkin

  2. Academy of Sciences of USSR, Institute of Structural Macrokinetics, USSR, 142432, Moscow District, Chernogolovka

    P. V. Zhirkov

Authors
  1. A. Ya. Malkin
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  2. P. V. Zhirkov
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© 1990 Springer-Verlag

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Malkin, A.Y., Zhirkov, P.V. (1990). Flow of polymerizing liquids. In: Polymer Physics. Advances in Polymer Science, vol 95. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-52159-3_7

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  • DOI: https://doi.org/10.1007/3-540-52159-3_7

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-52159-4

  • Online ISBN: 978-3-540-46909-4

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