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Dynamic magnetic resonance of liquid crystal polymers: Molecular organization and macroscopic properties

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Polymer Physics

Part of the book series: Advances in Polymer Science ((POLYMER,volume 95))

Abstract

Thermotropic liquid crystal main and side chain polymers (LCPs) have been studied by dynamic magnetic resonance techniques, including continuous wave ESR and pulsed deuteron NMR. Analysis of the various experiments, employing an appropriate relaxation model, provides detailed information about the dynamic organization of these systems. The discussion reveals the prominent molecular features distinguishing LCPs from their monomeric analogues. Concomitant investigations of the bulk behaviour indicate that the unique macroscopic properties of these polymers are strongly correlated to the specific molecular properties, determined by magnetic resonance techniques. In summary, the results clearly demonstrate the particular advantages of dynamic magnetic resonance in characterizing LCPs.

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  1. K. -H. Wassmer

    Present address: BASF Aktiengesellschaft, D-6700, Ludwigshafen, West-Germany

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  1. Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-7000, Stuttgart 80, FRG

    K. Müller, K. -H. Wassmer & G. Kothe

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Müller, K., Wassmer, K.H., Kothe, G. (1990). Dynamic magnetic resonance of liquid crystal polymers: Molecular organization and macroscopic properties. In: Polymer Physics. Advances in Polymer Science, vol 95. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-52159-3_5

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  • DOI: https://doi.org/10.1007/3-540-52159-3_5

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