Abstract
A single channel Titchmarsh-Weyl resonance scattering theory is extended to a coupled equations formulation. It is demonstrated that the intrinsic simplicity of the theory persists also in the multichannel case. Explicit theorems in connection with the multichannel case are proved, and simple Wronskian expressions for resonant scattering wave functions and related physical quantities are derived. The computational features are illustrated by an application to a non-trivial curve crossing problem. The numerical results display the detailed behaviour of resonance poles in the complex plane. The relevant diabatic and/or adiabatic limits as well as the effect of the strength of the interaction on the resonance structures are studied. Applications to the modeling of laser photofragment spectroscopy data are finally mentioned
This is a preview of subscription content, log in via an institution.
Preview
Unable to display preview. Download preview PDF.
References
H. Weyl, Ann. Math. 68, 220 (1910).
E. A. Coddington and N. Levinsson, Theory of Ordinary Differential Equations, McGraw-Hill New York, 1955.
J. Aquilar and J. M. Combes, Commun. Math. Phys. 22, 269 (1971).
E. Balslev and J. M. Combes, Commun. Math. Phys. 22, 280 (1971).
B. Simon, Ann. Math. 97, 247 (1973).
C. van Winter, J. Math. Anal. Appl. 47, 633 (1974).-C. van Winter, J. Math. Anal. Appl. 47, 368 (1974).
R. T. Pack and J. O. Hirschfelder, J. Chem. Phys. 49, 4009 (1970).
R. T. Pack and J. O. Hirschfelder, J. Chem. Phys. 52, 521 (1970).
A. Macias and A. Riera, Phys. Rep. 90, 299 (1982).
H. Lefebvre-Brion, in Atoms, Molecules and Lasers, International Atomic Energy, Vienna (1974), p.411.
K. Morokuma and T. F. George, J. Chem. Phys. 59, 1959 (1973).
P. Pechukas, T. F. George, K. Morokuma, F. J. McLaferty and J. R. Laing, J. Chem. Phys. 64, 1099 (1976).
J. Simons, J. Chem. Phys. 75, 2465 (1981); P. O. Löwdin, Int. J. Quantum Chem. 27, 494 (1985).
M. Rittby, N. Elander and E. Brändas, Phys. Rev. A24, 1636 (1981).
M. Rittby, N. Elander and E. Brändas, Mol. Phys. 45, 553 (1982).
M. Rittby, N. Elander and E. Brändas, Chem. Phys. 87, 55 (1984).
M. Hehenberger, E. Brändas and N. Elander, Int. J. Quantum Chem. Symp. 12, 67 (1978).
N. Elander, M. Rittby and E. Brändas Int. J. Quantum Chem. 22, 445 (1982).
M. Rittby, N. Elander, E. Brändas and A. Barany, J. Phys. B17, L677 (1984).
E. Brändas, M. Rittby and N. Elander, J. Math. Phys. 26, 2648 (1985).
E. Engdahl, E. Brändas, M. Rittby and N. Elander, Phys. Rev A. 37, 377 (1988).
B. R. Junker, Adv. Atom. and Molec. Phys. 18, 207 (1982).
W. P. Reinhardt, Ann. Rev. Phys. Chem. 33, 223 (1982).
Y. K. Ho, Phys. Rep. 1, 99 (1983).
B. Simon, Phys. Lett. A 71, 211 (1979).
J. D. Morgan and B. Simon, J. Phys. B14, L167 (1981).
E. Balslev, in Resonances-Models and Phenomena Lectures Notes in Physics 211, (Eds. S. Albeverio, L. S. Ferreira and L. Streit, Springer Verlag, Heidelberg 1984) page 27.
M. Reed and B. Simon, Methods of Modern Mathematical Physics IV, Analysis of Operators (Academic Press, New York, 1978) page 183–191.
M. Rittby, N. Elander and E. Brändas, Int. J. Quant. Chem. 23, 865 (1983).
P. Erman in Specialist Periodic Reports Vol 6 (Chem. Soc. London, 1979) page 501.
C. P. Edwards, C. S. MacLean and P. J. Sarre, Mol. Phys. 52, 1453 (1984).
M. S. Childs in Molecular Spectroscopy,Vol. 2 (Eds. R. F. Barrow, D. A. Long and D. J. Millen Chem. Soc. Specialist Periodical Report London 1974) page 466.
H. Lefebvre-Brion and R. Colin J. Mol. Spectrosc. 65, 33 (1977).
R. D. Levine, B. R. Johnson and R. B. Bernstein, J. Chem. Phys. 50, 1694 (1969).
G. Sillén, M. Rittby, N. Elander and E. Briindas, J. Chem. Phys. submittted (1988).
O. Atabek and R. Lefebvre, Chem. Phys 52, 199 (1980).
O. Atabek and R. Lefebvre, Chem. Phys 55, 395 (1981).
O. Atabek and R. Lefebvre, Chem. Phys 56, 195 (1981).
B. R. Johnson, J. Chem. Phys. 69, 4678 (1978).
L. Klynning and H. Martin, Physica Scripta 20, 594 (1979).
J. M. Robbe, Thesis, L'Universite des Sciences et Techniques de Lille (1978).
M. S. Childs and R. Lefebvre, Chem. Phys. Lett. 55, 213 (1978)
L. E. Selin Ark. Fys. 21, 529 (1962).
W. J. Balfour and H. M. Cartwright, Can. J. Phys. 54, 1898 (1976).
W. J. Balfour and H. M. Cartwright, Astron. Astrophys. Suppl. 26 389 (1976).
W. J. Balfour and B. Lindgren, Can. J. Phys. 56, 767 (1978).
M. Rittby, Thesis, University of Stockholm (May 1985).
H. J. Korsch, R. Möhlenkamp and K. E. Thylwe, J. Phys. B19, 2151 (1986).
H. J. Korsch and R. Möhlenkamp, Phys. Rev. A34, 4716 (1986).
O. Atabek, R. Lefebvre and A. Jacon, J. Phys. Bxx, yy (198ZZ).
C. J. Williams, K. F. Freed, S. J. Singer and Y. B. Band, Faraday Discuss. Chem. Soc. 82, paper 6 (1986).
S. J. Singer K. F. Freed and Y. B. Band, J. Chem. Phys. 79, 6060 (1983).
S. J. Singer, K. F. Freed and Y. B. Band, J. Chem. Phys. 81, 3064 (1984).
S. J. Singer, K. F. Freed and Y. B. Band, J. Chem. Phys. 81, 3091 (1984).
C. J. Williams and K. F. Freed, J. Chem. Phys. 85, 2699 (1986).
S. Lee, C. J. Williams and K. F. Freed. Chem. Phys. Lett. 130, 271 (1986).
X. He, O. Atabec and A. Suzor Submitted to Phys. Rev. A (1988).
M. Hehenberger, H. V. McIntosh and E. Brändas, Phys. Rev. A10, 1494 (1974).
E. Brändas, M. Hehenberger and H. V. McIntosh, Int. J. Quantum Chem. 9, 103 (1975).
M. Hehenberger, B. Laskowski and E. Brändas, J. Chem. Phys. 65, 4559 (1976).
M. Hehenberger, P. Froelich and E. Brändas, J. Chem. Phys. 65, 4571 (1976).
E. Engdahl, E. Brändas, M. Rittby and N. Elander, J. Math. Phys. 27, 2629 (1986).
P. Krylstedt, N. Elander and E. Brändas, Int. J. Quantum Chem Symp. 20, 253 (1986).
P. Krylstedt, M. Rittby, N. Elander and E. Brändas, J. Phys. B in press 1987.
P. Krylstedt, N. Elander and E. Brändas, submitted to J. Phys. B 1987.
E. Brändas, E. Engdahl, M. Rittby and N. Elander, Int. J. Quantum Chem. S19, 457 (1986).
M. Rittby, N. Elander and E. Brändas, this book page 133.
D. W. Norcross and M. J. Seaton, J. Phys. B6 614,1973.
R. Lefebvre in Intramolecular Dynamics (Eds. J. Jortner and B. Pullman, D. Reidel Publ. Comp., Paris, 1982).
R. Lefebvre, in ACS SYMPOSIUM SERIES 263 Resonances in ElectronMolecule Scattering, van der Waals Complexes and Reactive Chemical Dymamics (Ed. D. Truhlar, American Chem. Soc. Washington D.C. 1984).
A. Fröman, J. Chem. Phys. 36, 1490 (1962).
F. T. Smith Phys. Rev. 118, 349 (1960).
B. Andresen and S. E. Nielsen, Mol. Phys., 21, 523 (1971).
J. B. Delos Rev. Mod. Phys. 53, 287 (1981).
J. Garquad, Phys. B14, 2259 (1981).
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1989 Springer-Verlag
About this paper
Cite this paper
Brändas, E., Rittby, M., Elander, N. (1989). Multichannel complex scaled Titchmarsh Weyl theory a model for diatomic fragmentation. In: Brändas, E., Elander, N. (eds) Resonances The Unifying Route Towards the Formulation of Dynamical Processes Foundations and Applications in Nuclear, Atomic and Molecular Physics. Lecture Notes in Physics, vol 325. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-50994-1_49
Download citation
DOI: https://doi.org/10.1007/3-540-50994-1_49
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-50994-3
Online ISBN: 978-3-540-46130-2
eBook Packages: Springer Book Archive