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Formation of trichlorofluoromethane hydrate in w/o emulsions studied by differential scanning calorimetry

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Trends in Colloid and Interface Science XIII

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 112))

Abstract

The presence of trichlorofluoromethane hydrate in bulk water and in water-in-oil emulsions has been detected by differential scanning calorimetry. Hydrates have been observed during the heating of samples introduced into the head of a calorimeter. The amount of hydrate crystals was found to be dependent on the sample volume, the temperature reached during the cooling performed prior to the heating, and the time spent at the subambient temperature. These results confirm the kinetic aspects of hydrate formation and show that ice crystals may act as hydrate nucleating agents. Furthermore, two polymorphic forms are suspected to exist, but this must be confirmed by another technique.

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Authors and Affiliations

  1. Laboratoire CNRS - UPRES A Génie des Procédés, Equipe Thermodynamique et Physicochimie de Procédés Industriels, Université de Technologie de Compiègne, B.P. 529, F-60205, Compiègne, France

    B. Fouconnier, V. Legrand, L. Komunjer & D. Clausse

  2. Department of Chemistry, University of Bergen, Allégt.41, N-5007, Bergen, Norway

    L. Bergflødt & J. Sjöblom

Authors
  1. B. Fouconnier
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  2. V. Legrand
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  3. L. Komunjer
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  4. D. Clausse
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  5. L. Bergflødt
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  6. J. Sjöblom
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Durdica Težak Mladen Martinis

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© 1999 Springer-Verlag

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Fouconnier, B., Legrand, V., Komunjer, L., Clausse, D., Bergflødt, L., Sjöblom, J. (1999). Formation of trichlorofluoromethane hydrate in w/o emulsions studied by differential scanning calorimetry. In: Težak, D., Martinis, M. (eds) Trends in Colloid and Interface Science XIII. Progress in Colloid and Polymer Science, vol 112. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-48953-3_23

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  • DOI: https://doi.org/10.1007/3-540-48953-3_23

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-65810-8

  • Online ISBN: 978-3-540-48953-5

  • eBook Packages: Springer Book Archive

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