Abstract
Interfaces formed or exposed by polymer mixtures are often employed in modern technological applications. This is especially true for thin polymer films used nowadays in photoresist lithography, electrooptical devices or nanometer-scale surface patterning. Apart from these technology-oriented aspects the interfacial phenomena in thin polymer films pose a fundamental scientific challenge to physics of polymers and thermodynamics of condensed matter. This work reviews experimental results on the equilibrium properties of interfaces created by polymer mixtures confined in thin films. It confronts experimental data with theoretical expectations based mainly on mean field models. Most of the data have been obtained by high resolution profiling techniques emerged in the last decade. These techniques allow us to trace concentration vs depth profiles across a thin film with a depth resolution better than the characteristic size of a polymer coil. The interfacial phenomena of phase coexistence and segregation are described as observed in thin polymer films. This work also considers related issues in the focus of current research such as wetting phenomena, finite size effects expected in very thin films, surface (and bulk) properties of mixtures with stiffness disparity and conformational properties of end-segregated macromolecules forming polymer brushes.
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References
Sanchez IC (1983) Ann Rev Mater Sci 13:387
de Gennes PG (1979) Scaling concepts in polymer physics. Cornell University, Ithaca
Strobl G ( 1996) The physics of polymers. Springer, Berlin Heidelberg New York
Binder K (1999) Adv Polymer Sci 138:1
Binder K (1995) Acta Polymer 46:204
de Gennes PG (1985) Rev Modern Phys 57:827
Koningsveld R, Kleintjens LA, Nies E (1987) Croatica Chemica Acta 60:53
Bates FS (1991) Science 251:898
Helfand E, Sapse AM (1975) J Chem Phys 62:1327
Klein J (1990) Science 250:640
de Gennes PG (1983) Physics Today 36:33
Steiner U, Klein J, Eiser E, Budkowski A, Fetters LJ (1992) Science 258:1126
Schmidt I, Binder K (1985) J Physique 46:1631
Budkowski A, Scheffold F, Klein J, Fetters LJ (1997) J Chem Phys 106:719
Krausch G (1995) Material Sci Eng R14:1
Budkowski A (1997) Metals Alloys Technologies 31:587
Chaturvedi UK, Steiner U, Zak O, Krausch G, Schatz G, Klein J (1990) Appl Phys Lett 56:1228
Payne RS, Clough AS, Murphy P, Mills PJ (1989) Nucl. Instrum. Meth B42:130
Kerle T, Scheffold F, Losch A, Steiner U, Schatz G, Klein J (1997) Acta Polymer 48:548
Mills PJ, Green PF, Palmstrom CJ, Mayer JW, Kramer EJ ( 1984) Appl Phys Lett 4:957
Genzer J, Rothman JB, Composto RJ (1994) Nucl Instrum Meth B 86:345
Coulon G, Russell TP, Deline VR, Green PF (1989) Macromolecules 22:2581
Withlow SJ, Wool RP (1989) Macromolecules 22:2648
Schwarz SA, Wilkens BJ, Pudensi MA, Rafailovich MH, Sokolov J, Zhao X, Zhao W, Zheng X, Russell TP, Jones RAL (1992) Mol Phys 76:937
Bernasik A, Rysz J, Budkowski A, Kowalski K, Camra J, Jedlinski J (1997) In:Olefjord I, Nyborg L, Bryggs D (eds) ECASIA ’97, 7th European Conference on Applications of Surface and Interface Analysis. John Wiley, Chichester, p 775
Russell TP (1990) Materials Sci Reports 5:171
Kramer EJ (1991) Physica B 174:189
Herkt-Maetzky C, Schelten J (1983) Phys Rev Lett 51:896
Bates FS, Wignall GD, Koehler WC (1985) Phys Rev Lett 55:2425
Sawyer LC, Grubb DT (1987) Polymer Microscopy. Chapman and Hall, New York
Bielefeldt H, Hoersch I, Krausch G, Mlynek J, Marti O (1994) Appl Phys A59:103
Thomas EL (1986) Electron Microscopy. Wiley, New York
Albrecht TR, Dovek MM, Lang CA, Gruetter P, Quate CF, Kuan SNJ, Frank CW, Pease RFW (1988) J Appl Phys 64:1178
Flory PJ (1942) J Chem Phys 10:51
Huggins ML (1942) J Am Chem Soc 64:1712
Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca, New York
Sariban A, Binder K (1987) J Chem Phys 86:5859
Ginzburg VL (1960) Sov Phys Solid State 2:341
Schwahn D, Mortensen K, Yee-Madeira Y (1987) Phys Rev Lett 58:896
Taylor JK, Debenedetti PG, Graessley WW, Kumar SK (1996) Macromolecules 29:764
Bates FS, Muthukumar M, Wignall GD, Fetters LJ (1988) J Chem Phys 89:535
Pesci AI, Freed KF (1989) J Chem Phys 90:2017
Curro JG, Schweizer KS (1988) J Chem Phys 88:7242
Dudowicz I, Freed KF (1990) Macromolecules 23:1519
Dudowicz I, Freed KF, Lifschitz M (1994) Macromolecules 27:5387
Sanchez IC, Lacombe RH (1978) Macromolecules 11:1145
Binder K (1983) J Chem Phys 79:6387
Gehlsen MD, Rosedale JH, Bates FS, Wignall GD, Hansen L, Almdal K (1992) Phys Rev Lett 68:2452
Deutsch HP, Binder K (1992) Euro Phys Lett 17:697
Schweizer KS, Curro JG (1989) J Chem Phys 91:5059
Cahn JW, Hilliard JE (1958) J Chem Phys 28:258
Landau LD, Lifshitz EJ (1980) Statistical Physics, Oxford
de Gennes PG (1980) J Chem Phys 72:4756
Roe RJ (1986) Macromolecules 19:728
Jannik G, de Gennes PG (1986) J Chem Phys 48:2260
Tang H, Freed KF (1991) J Chem Phys 94:6307
Lifschitz M, Freed KF, Tang H (1995) J Chem Phys 103:3767
Flebbe T, Duenweg B, Binder K (1996) J Phys II (France) 6:667
Nakanishi H, Pincus P (1983) J Chem Phys 79:997
Shibayama M, Yang H, Stein RS, Han CC (1985) Macromolecules 18:2179
Sanchez IC (1989) Polymer 30:471
Cumming A, Wiltzius P, Bates FS (1990) Phys Rev Lett 65:863
Shen S, Torkelson JM (1992) Macromolecules 25:721
Huh W, Karasz FE (1992) Macromolecules 25:1057
Lohse DJ, Fetters LJ, Daoyle MJ, Wang H-C, Kow C (1993) Macromolecules 26:3444
Bates FS, Wignall GD (1986) Phys Rev Lett 57:1429
Bates FS, Fetters LJ, Wignall GD (1988) Macromolecules 21:1086
Schwahn D, Hahn K, Streib J, Springer T (1990) J Chem Phys 93:8383
Nicholson JC, Finerman TM, Crist B (1990) Polymer 31:2287
Balsara NP, Fetters LJ, Hadjichristidis N, Lohse DJ, Han CC, Graessley WW, Krishna-moorti R (1992) Macromolecules 25:6137
Londono JD, Narten AH, Wignall GD, Honnel KG, Hsieh T, Johnson TW, Bates FS (1994) Macromolecules 27:2864
Budkowski AS, Steiner U, Klein J, Schatz G (1992) EuroPhys Lett 18:705
Bruder F, Brenn R (1991) Macromolecules 24:5552
Chaturvedi UK, Steiner U, Zak O, Krausch G, Klein J (1989) Phys Rev Lett 63:616
Bruder F, Brenn R, Stuehn B, Strobl GR (1989) Macromolecules 22:4434
Klein J, Briscoe BJ (1975) Nature 257:387
Klein J, Briscoe BJ (1979) Proc Roy Soc (London) A 365:53
Green PF (1985) PhD Thesis, Cornell University, Ithaca, New York
Jones RAL (1987) PhD Thesis, Cambridge University
Kausch HH, Tirell M (1989) Annu Rev Mater Sci 19:341
de Gennes PG (1989) CR Acad Sci Paris, Serie II 308:13
Harden JL (1990) J Phys France 51:1777
Puri S, Binder K (1991) Phys Rev B 44:9735
Wang SQ, Shi Q (1993) Macromolecules 26:1091
Brochard F, Jouffroy J, Levinson P (1983) Macromolecules 16:1638
Steiner U (1993) PhD Thesis, Konstanz University
Steiner U, Krausch G, Schatz G, Klein J (1990) Phys Rev Lett 64:1119
Crank J (1975) The mathematics of diffusion. Oxford University Press, Oxford
Scheffold F, Eiser E, Budkowski A, Steiner U, Klein J, Fetters LJ (1996) J Chem Phys 104:8786
Budkowski A, Steiner U, Klein J (1992) J Chem Phys 97:229
Parry AO, Evans R (1992) Physica A 181:250
Straub W, Bruder F, Brenn R, Krausch G, Bielefeldt H, Kirsch A, Marti O, Mlynek J, Marko JF (1995) EuroPhys Lett 29:353
Bruder F (1992) PhD Thesis, Albert-Ludwigs Univ, Freiburg i. Br
Eiser E, Budkowski A, Steiner U, Klein J, Fetters LJ, Krishnamoorti R (1993) ACS PMSE Proc 69:176
Straub W (1996) PhD Thesis, Albert-Ludwigs Univ, Freiburg i. Br
Genzer J (1996) PhD Thesis, University of Pennsylvania
Genzer J, Composto RJ (1997) EuroPhys Lett 38:171
Cahn JW (1965) J Chem Phys 42:93
Pincus P (1981) J Chem Phys 75:1996
Hashimoto T (1988) Phase Transitions 12:47
Lifshitz IM, Slyoyzov VV (1961) J Chem Phys Solids 19:35
Ball RC, Essery RLH (1990) J Phys: Condens Matter 2:10,303
Marko JF (1993) Phys Rev E 48:2861
Puri S, Binder K (1994) Phys Rev E49:5359
Budkowski A (unpublished)
Jones RAL, Norton LJ, Shull KR, Kramer E, Bates FS, Wiltzius P (1991) Phys RevLett 66:1326
Krausch G, Dai C-A, Kramer EJ, Bates FS (1993) Phys Rev Lett 71:3669
Krausch G, Mlynek J, Straub W, Brenn R, Marko JF (1994) EuroPhys Lett 28:323
Krausch G, Dai C-A, Kramer EJ, Marko JF, Bates FS (1993) Macromolecules 26:5566
Kim E, Krausch G, Kramer EJ, Osby JO (1994) Macromolecules 27:5927
Geoghegan M, Jones RAL, Clough AS (1995) J Chem Phys 103:2719
Bruder F, Brenn R (1992) Phys Rev Lett 69:624
Steiner U, Eiser E, Budkowski A, Fetters JL, Klein J (1994) Ber Bunsenges Phys Chem 98:366
Rysz J, Bernasik A, Ermer H, Budkowski A, Brenn R, Hashimoto T, Jedlinski J (1997) EuroPhys Lett 40:503
Steiner U, Klein J, Fetters LJ (1994) Phys Rev Lett 72:1498
Binder K, Nielaba P, Pereyra V (1997) Z Phys B 104:81
Krausch G, Kramer EJ, Rafailovich MH, Sokolov J (1994) Appl Phys Lett 64:2655
Scheffold F, Budkowski A, Steiner U, Eiser E, Klein J, Fetters LJ (1996) J Chem Phys 104:8795
Kerle T, Klein J, Binder K (1996) Phys Rev Lett 77:1318
Hildebrand JH, Scott RL (1950) The solubility of non-electrolytes. Reinhold
van Laar JJ, Lorentz R (1925) Z Anorg Allgem Chem 146:42
Coleman MM, Serman CJ, Bhagwar DE, Painter PC (1990) Polymer 31:1187
Lin J-L, Roe R-J (1987) Macromolecules 20:2168
Han CC, Bauer BJ, Clark JC, Muroga Y, Matsushita Y, Okada M, Tran-Cong Q, Chang I, Sanchez IC (1988) Polymer 29:2002
Dudowicz J, Freed KF (1991) Macromolecules 24:5112
Lifschitz M, Freed KF (1993) J Chem Phys 98:8994
Schubert DW, Stamm M (1996) EuroPhys Lett 35:419
Sferrazza M, Xiao C, Jones RAL, Bucknall DG, Webster J, Penfold (1997) Phys Rev Lett 78:3693
Majkrzak CF, Flecher GP (1990) MRS Bulletin November, p 65
Atkin EL, Kleintjens LA, Koningsveld R, Fetters LJ (1984) Makromol Chem 185:377
Sakurai S, Hasegawa H, Hashimoto T, Hargis IG, Aggarwal SL, Han CC (1990) Macromolecules 23:451
Rhee J, Crist B (1991) Macromolecules 24:5663
Larbi FBC, Leloup S, Halary JL, Monnerie L (1986) Polymer Communications 27:23
Rhee J, Crist B (1993) J Chem Phys 98:4174
Graessley WW, Krishnamoorti R, Balsara NP, Fetters LJ, Lohse DJ, Schultz DN, Sissano JA (1993) Macromolecules 26:1137
Krishnamoorti R, Graessley WW, Balsara NP, Lohse DJ (1994) J Chem Phys 100:3894
Graessley WW, Krishnamoorti R, Balsara NP, Fetters LJ, Lohse DJ, Schultz DN, Sissano JA (1994) Macromolecules 27:2574
Graessley WW, Krishnamoorti R, Balsara NP, Butera RJ, Fetters LJ, Lohse DJ, Schultz DN, Sissano JA (1994) Macromolecules 27:3896
Krishnamoorti R, Graessley WW, Balsara NP, Lohse DJ (1994) Macromolecules 27:3073
Graessley WW, Krishnamoorti R, Reichart GC, Balsara NP, Fetters LJ, Lohse DJ (1995) Macromolecules 28:1260
Budkowski A, Klein J, Eiser E, Steiner U, Fetters LJ (1993) Macromolecules 26:3858
ten Brinke G, Karasz FE, MacKnight WJ (1983) Macromolecules 16:1827
Budkowski A, Rysz J, Scheffold F, Klein J, Fetters LJ (1998) J Polym Sci: Part B: Polymer Physics 36:2691
Fredrickson GH, Liu AJ (1995) J Polym Sci: Part B: Polymer Physics 33:1203
Kohl PR, Seifert AM, Hellmann GP (1990) J Polymer Sci: Part B: Polym Physics 28:1309
Schwahn D, Janssen S, Springer T (1992) J Chem Phys 97:8775
Schwahn D, Meier G, Mortensen K, Janssen S (1994) J Phys II France 4:837
Rouault Y, Baschnagel J, Binder K (1995) J Statistical Physics 80:1009
Bates FS, Wignall GD (1986) Macromolecules 19:932
Young T (1805) Philos Trans R Soc London 95:65
Cahn JE (1977) J Chem Phys 66:3667
Moldover MR, Cahn JW (1980) Science 207:1073
Schmidt JW, Moldover MR (1983) J Chem Phys 79:379
Pohl DW, Goldburg WI (1982) Phys Rev Lett 48:1111
Ragil K, Meunier J, Broseta D, Indekeu JO, Bonn D (1996) Phys Rev Lett 77:1532
Dietrich S (1988) In:Domb C, Lebowitz J (eds.) Phase transitions and critical phenomena, 12. Academic Press, London, p 1
Jones RAL (1994) Polymer 35:2160
Steiner U, Klein J (1996) Phys Rev Lett 77:2526
Wang JS, Binder K (1991) J Chem Phys 94:8537
Genzer J, Composto RJ (1997) J Chem Phys 106:1257
Genzer J, Kramer EJ (1997) Phys Rev Lett 78:4946
Bhatia QS, Pan DH, Koberstein JT (1988) Macromolecules 21:2166
Jones RAL, Kramer EJ, Rafailovich M, Sokolov J, Schwarz SA (1989) Phys Rev Lett 62:280
Faldi A, Genzer J, Composto RJ, Dozier WD (1995) Phys Rev Lett 74:3388
Bruder F, Brenn R (1993) EuroPhys Lett 22:707
Ermer H, Straub W, Brenn R (1996) Verhand DPG (VI) 31:PO9.3
Jones RAL, Norton LJ, Kramer EJ, Composto RJ, Stein RS, Russell TP, Mansour A, Karim A, Felcher GP, Rafailovich MH, Sokolov J, Zhao X, Schwarz SA (1990) EuroPhys Lett 12:41
Zhao X, Zhao W, Sokolov J, Rafailovich MH, Schwarz SA, Wilkens BJ, Jones RAL, Kramer EJ (1991) Macromolecules 24:5991
Hariharan A, Kumar SK, Russell TP (1993) J Chem Phys 98:4163
Hariharan A, Kumar SK, Rafailovich MH, Sokolov J, Zheng X, Duong D, Russell TP (1993) J Chem Phys 99:656
Guckenbiehl B, Stamm M, Springer T (1994) Coll Surf A: Physicochem Eng Aspects 86:311
Genzer J, Faldi A, Oslanec R, Composto RJ (1996) Macromolecules 20:5438
Budkowski A, Rysz J, Scheffold F, Klein J (1998) EuroPhys Lett 43:404
Jerry RA, Dutta A (1994) J Coll Int Sci 167:287
Jerry RA, Nauman EB (1992) Phys Lett A 167:198
Kumar SK, Tang H, Szleifer I (1994) Molecular Physics 81:867
Rouault Y, Duenweg B, Baschnagel J, Binder K (1996) Polymer 37:297
Lipowski R, Huse DA (1986) Phys Rev Lett 52:353
Binder K, Frisch HL (1991) Z Phys B: Condensed Matter 84:403
Jones RAL, Kramer EJ (1990) Philos Mag B 62:129
Cohen S, Muthukumar M (1989) J Chem Phys 90:5749
Fredrickson GH, Donley JP (1992) J Chem Phys 97:8941
Jerry RA, Nauman EB (1992) J Coll Int Sci 154:122
Donley JP, Fredrickson GH (1995) J Polym Sci: Part B: Polymer Physics 33:1343
Carmesin I, Noolandi J (1989) Macromolecules 22:1689
Norton LJ, Kramer EJ, Bates FS, Gehlsen MD, Jones RAL, Karim A, Felcher GP, Kleb R (1995) Macromolecules 28:8621
Zink F, Kerle T, Klein J (1998) Macromolecules 31:417
Chen ZY, Noolandi J, Izzo D (1991) Phys Rev Lett 66:727
Jones RAL (1993) Phys Rev E 47:1437
Klein J, Scheffold F, Steiner U, Eiser E, Budkowski A, Fetters LJ (1997) In:Sperling LH (ed) Interfacial aspects of multicomponent polymer materials. Plenum, New York
Genzer J, Faldi A, Composto RJ (1994) Phys Rev E50:2373
Cifra P, Bruder F, Brenn R (1993) J Chem Phys 99:4121
Jones RAL, Kramer EJ (1993) Polymer 34:115
Hariharan A, Kumar SK, Russell TP (1991) Macromolecules 24:4909
Kumar SK, Russell TP (1991) Macromolecules 24:3816
Hariharan A, Kumar SK, Russell TP (1990) Macromolecules 23:3584
Walton DG, Mayes AM (1996) Phys Rev E54:2811
Mayes AM, Kumar SK (1997) MRS Bulletin January, p 43
Wu DT, Fredrickson GH (1996) Macromolecules 29:7919
Walton DG, Soo PP, Mayes AM, Allgor SJS, Fujii JT, Griffith LG, Ankner JF, Kaiser H, Johansson J, Smith GD, Barker JG, Satija SK (1997) Macromolecules 30:6947
Sikka M, Singh N, Karim A, Bates FS, Satija SK, Majkrzak CF (1993) Phys Rev Lett 70:307
Carigano MA, Szleifer I (1995) EuroPhys Lett 30:525
Wu DT, Fredrickson GH, Carton J-P (1996) J Chem Phys 104:6387
Donley JP, Wu DT, Fredrickson GH (1997) Macromolecules 30:2167
Yethiraj A, Kumar S, Hariharan A, Schweizer KS (1994) J Chem Phys 100:4691
Yethiraj A (1995) Phys Rev Lett 74:2018
Kumar S, Yethiraj A, Schweizer KS, Leermakers FAM (1995) J Chem Phys 103:10,332
Steiner U, Klein J, Eiser E, Budkowski A, Fetters LJ (1994) In: Rabin Y, Bruinsma R (eds) Soft order in physical systems. Plenum Press, New York
Steiner U, Eiser E, Budkowski A, Fetters JL, Klein J (1994) In: Teramoto A, Kobayashi M, Norisuje T (eds) ordering in macromolecular systems. Springer, Berlin Heidelberg New York
Scheffold F, Eiser E, Budkowski A, Steiner U, Klein J, Fetters LJ (1996) ACS PMSE Proc. 75 (Aug)
Schweizer KS, David EF, Singh C, Curro JG, Rajasekaran JJ (1995) Macromolecules 28:1528
van der Linden CC, Leermakers FAM, Fleer GJ (1996) Macromolecules 29:1172
Rysz J, Budkowski A, Bernasik A, Klein J, Kowalski K, Jedlinski J (1998) (in preparation)
Wu S (1982) Polymer interfaces and adhesion Marcel Dekker, New York
Guggenheim EA (1945) J Chem Phys 13:253
Balsara NP, Lohse DJ, Graessley WW, Krishnamoorti R (1994) J Chem Phys 100:3905
Tang H, Szleifer I, Kumar SK (1994) J Chem Phys 100:5367
Reich S, Cohen Y (1981) J Polymer Sci 19:1255
Nakanishi H, Fisher ME (1983) J Chem Phys 78:3279
Eggleton CD (1996) Physics Letters A 223:394
Müller M, Binder K (1998) Macromolecules (in press)
Werner A, Schmid F, Müller M, Binder K (1997) J Chem Phys 107:8175
Binder K, Müller M, Schmid F, Werner A (1997) J Computer-Aided Materials Design 4:137
Milner ST (1991) Science 251:905
Halperin A, Tirrell M, Lodge TP (1991) Advances in Polymer Science 100:31
Milner ST (1994) J Polym Sci B: Polymer Physics 32:2743
Alexander S (1977) J Phys (Paris) 38:983
de Gennes PG (1980) Macromolecules 13:1069
Leibler L (1988) Makromol Chem, Macromol Symp 16:1
Aubouy M, Raphaël E (1993) J Phys II France 3:443
Munch MR, Gast AP (1988) Macromolecules 21:1366
Zhulina EB, Borisov OV, Brombacher L (1991) Macromolecules 24:4679
Semenov AN (1992) Macromolecules 25:4967
Shull KR, Kramer EJ (1990) Macromolecules 23:4769
Shull KR (1991) J Chem Phys 94:5723
Shull KR (1993) Macromolecules 26:2346
Grest GS (1996) J Chem Phys 105:5532
Brown HR, Char K, Deline VR (1990) Macromolecules 23:3383
Budkowski A, Steiner U, Klein J, Fetters LJ (1992) EuroPhys Lett 20:499
Clarke CJ, Jones RAL, Edwards JL, Clough AS, Penfold J (1994) Polymer 35:4065
Clarke CJ, Jones RAL, Edwards JL, Shull KR, Penfold J (1995) Macromolecules 28:2042
Liu Y, Schwarz SA, Zhao W, Quinn J, Sokolov J, Rafailovich MH, Iyengar D, Kramer EJ, Dozier W, Fetters LJ, Dickman R (1995) EuroPhys Lett 32:211
Reiter G, Auroy P, Auvray L (1996) Centre de Recherches sur la Physico-Chimie des Surfaces Solides, CNRS, Mulhouse, France (preprint)
Green PF, Russell TP (1991) Macromolecules 24:2931
Russell TP, Anastasiadis SH, Menelle A (1991) Macromolecules 24:1575
Green PF, Russell TP (1992) Macromolecules 25:783
Zhao X, Zhao W, Zheng X, Rafailovich MH, Sokolov J, Schwarz SA, Pudensi MAA, Russell TP, Kumar SK, Fetters LJ (1992) Phys Rev Lett 69:776
Dai KH, Kramer EJ, Shull KR (1992) Macromolecules 25:220
Budkowski A, Klein J, Steiner U, Fetters LJ (1993) Macromolecules 26:2470
Dai KH, Washiyama J, Kramer EJ (1994) Macromolecules 27:4544
Dai KH, Kramer EJ (1994) J Polymer Sci B: Polymer Phys 32:1943
Budkowski A, Klein J, Fetters LJ (1995) Macromolecules 28:8571
Budkowski A, Klein J, Fetters LJ, Hashimoto T (1995) Macromolecules 28:8579
Shull KR, Kellock AJ, Deline VR, MacDonald SA (1992) J Chem Phys 97:2095
Ligoure C, Leibler L (1990) J Phys France 51:1313
Budkowski A, Losch A, Klein J (1995) Israel J Chem 35:55
Sanchez IC (1987) Encycl Polym Sci Technol 11:1
Shull KR, Kramer EJ, Hadziioannou G, Tang W (1990) Macromolecules 23:4780
Dai KH, Norton LJ, Kramer EJ (1994) Macromolecules 27:1949
Jones RAL, Norton LJ, Shull KR, Kramer EJ, Felcher GP, Karim A, Fetters LJ (1992) Macromolecules 25:2359
Dai KH, Kramer EJ (1994) Polymer 35:157
Nicolai T, Clarke CJ, Jones RAL, Penfold J (1994) Colloid Surf A86:155
Zhao X, Zhao W, Rafailovich MH, Sokolov J, Russell TP, Kumar SK, Schwarz SA, Wilkens BJ (1991) EuroPhys Lett 15:725
Losch A, Salomonovic R, Steiner U, Fetters LJ, Klein J (1995) J Polym Sci B: Polymer Physics 33:1821
Aubouy M, Fredrickson GH, Pincus P, Raphaël E (1995) Macromolecules 28:2979
Tanaka H, Hashimoto T (1991) Macromolecules 24:5398
Shull KR, Winey KI, Thomas EL, Kramer EJ (1991) Macromolecules 24:2748
Dan N, Tirrel M (1993) Macromolecules 26:6467
Milner ST (1992) Macromolecules 25:5847
Lai P-Y, Zhulina EB (1992) Macromolecules 25:5201
Laub CF, Koberstein JT (1994) Macromolecules 27:5016
Klein J, Kamiyama Y, Yoshizawa H, Israelachvili JN, Fetters LJ, Pincus P (1992) Macromolecules 25:2062
Kumacheva E, Klein J, Pincus P, Fetters LJ (1993) Macromolecules 26:6477
Perahia D, Wiesler DG, Satija SK, Fetters LJ, Sinha SK, Grest GS (1996) Physica B221:337
Char K, Brown HR, Deline VR (1993) Macromolecules 26:4164
Sung L, Han C (1995) J Polym Sci B: Polymer Phys 33:2405
Kellogg GJ, Walton DG, Mayes AM, Lambooy P, Russell TP, Gallagher PD, Satija SK (1996) Phys Rev Lett 76:2503
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Budkowski, A. (1999). Interfacial Phenomena in Thin Polymer Films: Phase Coexistence and Segregation. In: Interfaces Crystallization Viscoelasticity. Advances in Polymer Science, vol 148. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-48836-7_1
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