Abstract
The full dissolution and crystallization of PA6 in water and PA4.6 in water and ethanol under pressure are described. Dissolution of PA6 in water is very fast and effective: it is completed during heating at 5°C/min in a DSC without stirring. It drastically lowers subsequent crystallization and melting temperatures. The maximum depression of the crystallization and melting temperatures is approximately 60°C.
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References
B. Frank, P. Frübing, P. Pissis, J Polym Sci B Polym Phys 34, 1853 (1996).
K. Kawasaki, Y. Sekita, J Polym Sci A 3, 2437 (1964).
J. L. Hutchison, N. S. Murthy, E. T. Samulski, Macromolecules 29, 5551 (1996).
B. Knopp, U. W. Suter, Macromolecules 30, 6114 (1997).
N. S. Murthy, M. K. Akkapeddi, W. J. Orts, Macromolecules 31, 142 (1998).
C. A. Fyfe, L. H. Randall, N. E. Burlinson, J Polym Sci A Polym Chem 31, 159 (1993).
L. P. Razumovskii, V. S. Markin, G. Y. Zaikov, Polym Sci USSR 27, 751 (1985).
J. Aerts, et al., Thechnische Thermoplaste, Polyamide part 3 (Hanser Verlag: München, 1998), chap. 3, pp. 549–638.
H. K. Reimschuessel, J Polym Sci Polym Chem 16, 1229 (1978).
N. S. Murthy, M. Stamm, J. P. Sibilia, S. Krimm, Macromolecules 22, 1261 (1989).
G. J. Kettle, Polymer 18, 742 (1977).
P. Adriaensens, et al., Polymer 42, 7943 (2001).
N. Jia, H. A. Fraenkel, J Reinf Plast Compos 23, 729 (2004).
K. Inoue, S. Hoshino, J Polym Sci Polym Phys 14, 1513 (1976).
R. J. Hernandez, R. Gavara, J Polym Sci B Polym Phys 32, 2367 (1994).
Y. P. Khanna, P. Han, E. D. Day, Polym Eng Sci 36, 1745 (1996).
F. P. La Mantia, R. Scaffaro, Polym Degrad Stab 75, 473 (2002).
Y. S. Papir, S. Kapur, C. E. Rogers, E. Baer, J Polym Sci A2 10, 1305 (1972).
D. C. Prevorsek, R. H. Butler, H. K. Reimschuessel, J Polym Sci A2 9, 867 (1971).
H. W. Starkweather, J Appl Polym Sci 2, 129 (1959).
J. Hirschinger, H. Miura, K. H. Gardner, A. D. English, Macromolecules 23, 2153 (1990).
V. M. Litvinov, J. P. Penning, Macromol Chem Phys 205, 1721 (2004).
A. Koshimo, J Appl Polym Sci 9, 55 (1965).
A. Koshimo, T. Tagawa, J Appl Polym Sci 9, 117 (1965).
N. S. Murthy, W. J. Orts, J Polym Sci B Polym Phys 32, 2695 (1994).
J. Pleštil, J. Baldrian, Y. M. Ostanevich, V. Y. Bezzabotnov, J Polym Sci B Polym phys 29, 509 (1991).
N. S. Murthy, S. M. Aharoni, A. B. Szollosi, J Polym Sci Polym Phys 23, 2549 (1985).
G. A. Campbell, J Polym Sci Polym Lett 7, 629 (1969).
H. M. Heuvel, R. Huisman, J Appl Polym Sci 23, 713 (1981).
K. Nagasubramanian, H. K. Reimschuessel, J Appl Polym Sci 17, 1663 (1973).
R. Puffr, J. Šebenda, J Polym Sci C 16, 79 (1967).
H. W. Starkweather, J. R. Barkley, J Polym Sci Polym Phys 19, 1211 (1981).
E. G. Chatzi, H. Ishida, J. L. Koenig, Appl Spectrosc 40, 847 (1986).
M. Tsuruta, A.Koshimo, T. Tagawa, J Appl Polym Sci 9, 31 (1965).
M. Tsuruta, A. Koshimo, J Appl Polym Sci 9, 39 (1965).
A. Koshimo, J Appl Polym Sci 9, 81 (1965).
M. F. J. Pijpers, V. B. F. Mathot, R. L. Scherrenberg, Kristallisatie- en smelttemperatuur depressie van polyamiden door water, methanol and andere oplosmiddelen onder verhoogde (damp)druk, Tech. Rep. RC95–12799, DSM Research (1995).
R. Korbee, A. V. Geenen, Patent No. WO 99/297467 pp. 1–16 (1999).
S. Rastogi, A. E. Terry, E. Vinken, Macromolecules 37, 8825 (2004).
N. Kosaric, et al., Ulmann’s encyclopedia of industrial chemistry (Wiley-VCH Verlag GmbH:Weinheim, 2000 electronic release), chap. Ethanol-physical properties, 6th edn.
E. U. Frank, G. Wiegand, N. Dahmen, Ullmann’s encyclopedia of industrial chemistry (Wiley-VCH Verlag GmbH:Weinheim, 2000 electronic release), chap. Water at high pressure and temperature, 6th edn.
V. B. F. Mathot, Calorimetry and thermal analysis of polymers (Hanser Publishers: Münich, 1994), Chap. 5, pp. 105–167.
V. Mathot, T. Pijpers, M. Steinmetz, G. van der Plaats, Proceedings of the 25th North American Thermal Analysis Society Conference (McClean: Virginia, 1997), p. 64. The temperature dependent crystallinity software program which runs under Windows and is not instrument specific, has been developed by DSM Research BV and Anatech BV jointly, and is availabe trough PerkinElmer.
http://web.utk.edu/~athas/databank/intro.html.
D. R. Holmes, C. W. Bunn, D. J. Smith, J Polym Sci 17, 159 (1955).
H. Arimoto, M. Ishibashi, M. Hirai, Y. Chatani, J Polym Sci A 3, 317 (1965).
A. Ziabicki, Koll-Z 167, 132 (1959).
L. G. Roldan, H. S. Kaufman, J Polym Sci B Polym Lett 1, 603 (1963).
F. Auriemma, V. Petraccone, L. Parravicini, P. Corradini, Macromolecules 30, 7554 (1997).
J. Gianchandani, J. E. Spruiell, E. S. Clark, J Appl Polym Sci 27, 3527 (1982).
J. P. Parker, P. H. Lindenmeyer, J Appl Polym Sci 21, 821 (1977).
R. Tol, V. B. F. Mathot, H. Reynaers, B. Goderis, G. Groeninckx, Polymer 46, 2966 (2005).
G. Gurato, A. Fichera, F. Z. Grandi, R. Zannetti, P. Canal, Makromol Chem 175, 953 (1974).
V. Malta, G. Cojazzi, A. Fichera, D. Ajo, R. Zanetti, Eur Polym J 15, 765 (1979).
J. Ibarretxe Uriguen, L. Bremer, V. Mathot, G. Groeninckx, Polymer 45, 5961 (2004).
N. S. Murthy, S. A. Curran, S. M. Aharoni, H. Minor, Macromolecules 24, 3215 (1991).
http://www.cryst.chem.uu.nl/platon/pl000000.html.
http://www.cryst.chem.uu.nl/platon/pl000302.html.
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Wevers, M.G., Mathot, V.B., Pijpers, T.F., Goderis, B., Groeninckx, G. (2007). Full Dissolution and Crystallization of Polyamide 6 and Polyamide 4.6 in Water and Ethanol. In: Reiter, G., Strobl, G.R. (eds) Progress in Understanding of Polymer Crystallization. Lecture Notes in Physics, vol 714. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-47307-6_9
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DOI: https://doi.org/10.1007/3-540-47307-6_9
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