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Molecular Self-Assembly Organic Versus Inorganic Approaches pp 177–201Cite as

Molecular Paneling Through Metal-Directed Self-Assembly

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 96))

Abstract

Metal-directed self-assembly is widely recognized as an efficient method for constructing well-defined discrete structures. Among the many fascinating structures that have been prepared by this method, recent interest is in large three-dimensional compounds with a large cavity in the framework. Following on from the preceding chapter, which dealt with various three-dimensional coordination assemblies, this chapter focuses on a unique approach to three-dimensional assemblies via “molecular paneling”. Families of planer exomultidentate organic ligands (molecular panels) are found to assemble into large three-dimensional assemblies through metal coordination. In particular, cis-protected square planer metals [e.g. (en)Pd2+, en = ethylenediamine] are shown to be very useful to panel molecules. Metal-assembled cages, bowl, tube, capsule, and polyhedra, are efficiently constructed by this approach.

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Authors and Affiliations

  1. Graduate School of Engineering, Nagoya University, Chikusaku, Nagoya, 464-8603, Japan

    Makato Fujita

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  1. Makato Fujita
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Editors and Affiliations

  1. Department of Applied Chemistry Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, 464-8603, Japan

    Makoto Fuiita

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© 2000 Springer Verlag Berlin Heidelberg

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Fujita, M. (2000). Molecular Paneling Through Metal-Directed Self-Assembly. In: Fuiita, M. (eds) Molecular Self-Assembly Organic Versus Inorganic Approaches. Structure and Bonding, vol 96. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46591-X_6

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  • DOI: https://doi.org/10.1007/3-540-46591-X_6

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-66948-7

  • Online ISBN: 978-3-540-46591-1

  • eBook Packages: Springer Book Archive

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