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Hydrogen-Bonded Liquid Crystals: Molecular Self-Assembly for Dynamically Functional Materials

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Book cover Molecular Self-Assembly Organic Versus Inorganic Approaches

Part of the book series: Structure and Bonding ((STRUCTURE,volume 96))

Abstract

Liquid crystals are molecular materials which combine anisotropy with a dynamic nature. This unique character can lead to the fabrication of new dynamically functional materials. A new class of liquid crystals prepared by self-assembly processes through the formation of intermolecular interactions such as hydrogen bonding would be key materials for such an approach. Supramolecular hydrogen-bonded liquid-crystalline complexes have been prepared from different and independent molecules such as carboxylic acids and pyridines. A variety of molecular structures as well as polymeric complexes have been obtained by the self-association of hydrogen-bonded components. Hydrogen-bonded complexes consisting of identical molecules such as benzoic acids, amides, and polyols also form liquid-crystalline aggregates which exhibit a variety of ordered structures. In addition to these materials which exhibit homogeneous mesophases, anisotropic liquid-crystalline gels which consist of heterogeneous structures are obtained as a new mesomorphic material. These self-assembled liquid crystals could bridge the disciplines of materials science and supramolecular chemistry.

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  1. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

    Takashi Kato

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  1. Department of Applied Chemistry Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, 464-8603, Japan

    Makoto Fuiita

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Kato, T. (2000). Hydrogen-Bonded Liquid Crystals: Molecular Self-Assembly for Dynamically Functional Materials. In: Fuiita, M. (eds) Molecular Self-Assembly Organic Versus Inorganic Approaches. Structure and Bonding, vol 96. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46591-X_4

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