Abstract
Spherical microgel particles of sufficiently high degree of internal cross-linking and swollen in a good solvent in many respects behave quite similarly to hard-sphere colloids. Due to solvent uptake they can be refractive-index-matched and density-matched in suitable organic solvents. We present preliminary measurements of the crystallization kinetics of 1:10 cross-linked polystyrene microgel particles. We measured Bragg and small-angle light scattering of the solidifying shear melt. Two different scattering patterns, a set of Debye-Scherrer rings and a second ring pattern at small angles could be observed. We check for similarities and differences compared to previously investigated colloidal systems.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Phan SE, Russel WB, Cheng Z, Zhu J, Chaikin PM, Dunsmuir JH, Ottewill RH (1996) Phys Rev E 54:6633
Vrij A (1983) Faraday Discuss Chem Soc 76:19
Pusey PN, van Megen W (1986) Nature 320:340
Hoover WG, Ree FH (1968) J Chem Phys 27:1208
Bartlett P, van Megen W (1994) In: Mehta A (ed) Granular matter. Springer, Berlin Heidelberg New York, pp 195–257
Palberg T (1997) Curr Opin Colloid Interface Sci 2:607
Harland JL, Henderson SI, Underwood SM, van Megen W (1996) Phys Rev Lett 75:3572
Schätzel K, Ackerson BJ (1992) Phys Rev E 48:3766
He Y, Ackerson BJ, van Megen W, Underwood SM, Schätzel K (1996) Phys Rev E 54:5286
Palberg T (1999) J Phys Condens Matter 11:R323
Saunders BR, Vincent B (1999) Adv Colloid Interface Sci 80:1
Bartsch E, Kirsch S, Lindner P, Scherer T, Stölken S (1998) Ber Bunsenges Phys Chem 102:1597
Bartsch E (1995) In: Yip E (ed) Relaxation kinetics in supercooled liquids-mode coupling theory and its experimental test, Transport Theory and Statistical Physics 24:1125
Bartsch E, Frenz V, Baschnagel J, Schärtl W, Sillescu H (1997) J Chem Phys 106:3743
Kasper A, Kirsch S, Renth F, Bartsch E, Sillescu H (1996) Prog Colloid Polym Sci 100:151
Kasper A, Bartsch E, Sillescu H (1998) Langmuir 14:5004
Kirsch S, Doerk A, Bartsch E, Sillescu H, Landfester K, Spiess HW, Maechtle W (1999) Macromolecules 32:4508
Kirsch S (1996) Ph D thesis. Mainz
Henderson SI, Mortensen TC, Underwood SM, van Megen W (1996) Physica A 233:102
Monovaukas Y, Gast A (1990) Phase Transitions 21:217
Elliot MS, Bristol BTF, Poon WCK (1997) Physica A 235:216
Pusey PN, van Megen W, Bartlett P, Ackerson BJ, Rarity JG, Underwood SM (1989) Phys Rev Lett 63:2753
Schätzel K (1996) In: Arora AK, Tata BVR (eds) Ordering and phase transitions in charged colloids. VCH, New York, pp 17–40
Heymann A, Stipp A, Sinn C, Palberg T (1998) J Colloid Interface Sci 206:119
Heymann A (1997) Ph D thesis. Mainz
van Duijneveldt JS (1994) PhD thesis. Utrecht
Furukawa H (1984) Physica A 123:497
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer-Verlag
About this paper
Cite this paper
Stipp, A., Sinn, C., Palberg, T., Weber, I., Bartsch, E. (2000). Crystallizing polystyrene microgel colloids. In: Buckin, V. (eds) Trends in Colloid and Interface Science XIV. Progress in Colloid and Polymer Science, vol 115. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46545-6_13
Download citation
DOI: https://doi.org/10.1007/3-540-46545-6_13
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-67128-2
Online ISBN: 978-3-540-46545-4
eBook Packages: Springer Book Archive