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Determination of Nanosize Particle Distribution by Low Frequency Raman Scattering: Comparison to Electron Microscopy

  • M. Ivanda
  • A. M. Tonejc
  • I. Djerdj
  • M. Gotić
  • S. Musić
  • G. Mariotto
  • M. Montagna
Conference paper
Part of the Lecture Notes in Physics book series (LNP, volume 588)

Abstract

The methodology for the determination of a nanosized particle distribution by low frequency Raman spectroscopy is described. It is based on a ν -1 dependence of the Raman light of the vibration coupling coefficient C(ν) and on the fact that each nanocrystalite of diameter D vibrates with its eigenfrequency í α 1/D. The effect of the particle vibrational lifetime on the shape of the distribution is analyzed and found to be negligible for free TiO2 nanoparticles. The size distributions of TiO2 nanoparticles estimated by Raman spectroscopy were compared to those obtained by transmission electron microscopy including dark field and high resolution imaging. The Raman spectroscopy was shown to be a simple, fast method that has favourable statistics due to a macroscopic probe volume and makes in situ measurements possible.

Keywords

Particle Size Distribution High Resolution Transmission Electron Microscopy Sound Velocity High Resolution Transmission Electron Microscopy Particle Mode 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2002

Authors and Affiliations

  • M. Ivanda
    • 1
    • 3
  • A. M. Tonejc
    • 2
  • I. Djerdj
    • 2
  • M. Gotić
    • 1
  • S. Musić
    • 1
  • G. Mariotto
    • 3
  • M. Montagna
    • 3
  1. 1.Rudjer Bošković InstituteZagrebCroatia
  2. 2.Faculty of Sciences, Department of PhysicsUniversity of ZagrebZagrebCroatia
  3. 3.Instituto Nazionale per la Fisica della Materia, Dipartimento di FisicaUniversità di TrentoTrentoItaly

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