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Decrease of Ferromagnetic Transition Temperature in Nonstoichiometric SrRu1−v O3 Perovskites

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Ruthenate and Rutheno-Cuprate Materials

Part of the book series: Lecture Notes in Physics ((LNP,volume 603))

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Abstract

We have discovered that synthesis at high-pressure oxygen of 600 atm at 1100°C produces nonstoichiometric SrRu1−v O3 perovskites with randomly distributed vacancies on the Ru-sites. The increased amount of Ru vacancies rapidly suppresses the ferromagnetic T C from 162 to 86K for Δv ∼ 0.06. We associate the decrease of T C with an increased formal valence of Ru and the induced structural disorder.

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Authors and Affiliations

  1. Physics Department, Northern Illinois University, DeKalb, IL, 60115, USA

    B. Dabrowski, P. W. Klamut, O. Chmaissem, S. Kolesnik, M. Maxwell, J. Mais & C. W. Kimball

  2. Materials Science Division, Argonne National Laboratory, Argonne, IL, 60439, USA

    J. D. Jorgensen & S. Short

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  1. B. Dabrowski
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  2. P. W. Klamut
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  3. O. Chmaissem
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  4. S. Kolesnik
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  5. M. Maxwell
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  6. J. Mais
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  7. C. W. Kimball
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  8. J. D. Jorgensen
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  9. S. Short
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Editor information

Editors and Affiliations

  1. Dipartimento di Fisica “E.R. Caianiello” Facoltá di Scienze, Universitá di Salerno, Via Salvator Allende, 84081, Baronissi (Salerno), Italy

    C. Noce , A. Vecchione , M. Cuoco  & A. Romano , ,  & 

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© 2002 Springer-Verlag Berlin Heidelberg

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Dabrowski, B. et al. (2002). Decrease of Ferromagnetic Transition Temperature in Nonstoichiometric SrRu1−v O3 Perovskites. In: Noce, C., Vecchione, A., Cuoco, M., Romano, A. (eds) Ruthenate and Rutheno-Cuprate Materials. Lecture Notes in Physics, vol 603. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45814-X_20

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  • DOI: https://doi.org/10.1007/3-540-45814-X_20

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-44275-2

  • Online ISBN: 978-3-540-45814-2

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