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Association of hydrophobically modified poly(sodium acrylate) with cationic copolymers based on N-isopropylacrylamide

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Book cover Trends in Colloid and Interface Science XV

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 118))

Abstract

We have studied the behaviour of aqueous mixtures of a hydrophobically modified poly(sodium acrylate) derivative (PA-Na3C18, containing 3 mol% octadecyl groups) with a cationic copolymer of N-isopropylacrylamide (PNIPAM10, containing 10 mol% cationic groups). Rheology and pyrene fluorescence probing were used to this end. The PA-Na3C18/PNIPAM10 mixtures were compared to mixtures of PANa3C18 with PNIPAM. The combination of both electrostatic attractions and hydrophobic interactions makes the PANa3C18/PNIPAM10 mixtures more effective thickeners than the PANa3C18/PNIPAM ones. In the latter case, only hydrophobic interactions are effective.

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Author information

Authors and Affiliations

  1. Department of Chemical Engineering, University of Patras, 26500, Patras, Greece

    G. Bokias

  2. Laboratoire de Physico-chimie Macromoléculaire, UMR-7615, ESPCI-CNRS-UPMC, 10 rue Vauquelin, 75231, Paris cédex 05, France

    I. Iliopoulos & D. Hourdet

  3. Department of Chemical Engineering, University of Patras and Institute of Chemical Engineering and High Temperature Processes ICE/HT-FORTH, P.O. Box 1414, 26500, Patras, Greece

    G. Staikos

Authors
  1. G. Bokias
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  2. I. Iliopoulos
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  3. D. Hourdet
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  4. G. Staikos
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Editor information

Editors and Affiliations

  1. Department of Chemical Engineering, University of Patras, GR26500, Patras, GREECE

    Petros G. Koutsoukos

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© 2001 Springer-Verlag

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Bokias, G., Iliopoulos, I., Hourdet, D., Staikos, G. (2001). Association of hydrophobically modified poly(sodium acrylate) with cationic copolymers based on N-isopropylacrylamide. In: Koutsoukos, P.G. (eds) Trends in Colloid and Interface Science XV. Progress in Colloid and Polymer Science, vol 118. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45725-9_11

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  • DOI: https://doi.org/10.1007/3-540-45725-9_11

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-42241-9

  • Online ISBN: 978-3-540-45725-1

  • eBook Packages: Springer Book Archive

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