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Optical Spectroscopic Studies of Metal-Insulator Transitions in Perovskite-Related Oxides

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Book cover Localized to Itinerant Electronic Transition in Perovskite Oxides

Part of the book series: Structure and Bonding ((STRUCTURE,volume 98))

Abstract

This article examines metal-insulator transitions observed in perovskite-like Ti-, V-, Mn-, Fe-, Co-, Ni-, Cu-, Bi-, and Ru-oxide systems using optical spectroscopies, particularly infrared reflectance and Raman scattering. The rich phenomena examined in these materials include bandfilling- and bandwidth-induced metal-insulator transitions, mass renormalization effects, metal-insulator transitions involving charge-, spin-, and orbital-ordering, colossal magnetoresistance, polaronic effects, double exchange ferromagnetism, and electronic phase separation. In addition to describing the optical spectroscopic signatures of these remarkable phenomena, this article will examine theoretical models of this diverse behavior, and will explore some of the outstanding questions confronting the physics of these materials.

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  1. Department of Physics, Frederick Seitz Materials Research Laboratory, and Science and Technology Center for Superconductivity, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA

    S. L. Cooper

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  1. Texas Materials Institute, University of Texas at Austin, ETC 9.102, Austin, TX, 78712, USA

    John B. Goodenough

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Cooper, S.L. (2001). Optical Spectroscopic Studies of Metal-Insulator Transitions in Perovskite-Related Oxides. In: Goodenough, J.B. (eds) Localized to Itinerant Electronic Transition in Perovskite Oxides. Structure and Bonding, vol 98. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45503-5_4

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