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Organoboron Compounds

  • Norio Miyaura
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 219)

Abstract

Until recently, organoboronic acids had found limited use in organic synthesis due to their low reactivity for ionic reactions. However, it became increasingly clear that they are a valuable reagent capable of undergoing many catalytic carbon-carbon bond formations in organic syntheses including asymmetric synthesis, combinatorial synthesis, and polymer synthesis. A review of the metal-catalyzed cross-coupling reaction of these compounds is presented here with particular emphasis on their application in selective organic syntheses. Representative methods for achieving selective coupling are outlined, along with a survey of a wide range of C-C bond formations.

Keywords

Cross-coupling reaction Organoboron compounds Palladium and nickel catalysts Carbon-carbon bond formation 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2002

Authors and Affiliations

  • Norio Miyaura
    • 1
  1. 1.Division of Molecular Chemistry, Graduate School of EngineeringHokkaido UniversitySapporoJapan

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