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Acyl migration and hydrolysis in monoolein-based systems

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Book cover Lipid and Polymer-Lipid Systems

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 120))

Abstract

The extent of acyl migration and hydrolysis phenomena in glycerol monooleate/water based systems and how they are affected by acetic acid and oleic acid has been examined. To facilitate analysis and interpretation of the data, samples with a low water content, 2–5 wt%, which form a liquid reverse micellar, L2, phase, were chosen. Acyl migration and hydrolysis were monitored versus time by 13C NMR analysis. In addition, the acid value to monitor hydrolysis has been also determined. The formation of small amounts of glycerol-2-monooleate as well as hydrolysis products was observed. These phenomena depend on the water content and storage conditions. The implications of these findings for the observed phase behaviour of the glycerol monooleate/water system are discussed.

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References

  1. Verger R, Pattus F (1982) Chem Phys Lipids 30:189–227

    Article  CAS  Google Scholar 

  2. Panaitov I, Verger R (2000) In: Baszkin A, Norde W (eds) Physical chemistry of biological interfaces. Dekker, New York, pp 359–400

    Google Scholar 

  3. Patton JS, Carey MC (1979) Science 204:145–148

    Article  CAS  Google Scholar 

  4. Patton JS, Vetter RD, Hamosh M, Borgström B, Lindström M, Carey MC (1985) Food Microstruct 4:29–41

    CAS  Google Scholar 

  5. Boswinkel G, Derksen JTP, van’t Riet K, Cuperus FP (1996) J Am Oil Chem Soc 73:707–711

    Article  CAS  Google Scholar 

  6. Lawrence MJ (1994) Chem Soc Rev 23:417

    Article  CAS  Google Scholar 

  7. Ganem-Quintanar A, Quintanar-Guerrero D, Buri P (2000) Drug Dev Ind Pharm 26:809, and references therein

    Article  CAS  Google Scholar 

  8. Larsson K (2000) Curr Opin Colloid Interface Sci 5:64

    Article  CAS  Google Scholar 

  9. Engström S, Alfons K, Rasmusson M, Ljusberg-Wahren H (1998) Prog Colloid Polym Sci 108:93

    Article  Google Scholar 

  10. Norling T, Lading P, Engström S, Larsson K, Krog N, Nissen SS (1992) J Clin Periodontol 19:687–692

    CAS  Google Scholar 

  11. Geraghty PB, Attwood D, Collet JH (1996) Pharm Res 13:8

    Article  Google Scholar 

  12. Caboi F, Amico GS, Pitzalis P, Monduzzi M, Nylander T, Larsson K (2001) Chem Phys Lipids 109:47, and references therein

    Article  CAS  Google Scholar 

  13. Pitzalis P, Monduzzi M, Krog N, Larsson H, Ljusberg-Wahren H, Nylander T (2000) Langmuir 16:6358

    Article  CAS  Google Scholar 

  14. Ljusberg-Wahren H, Herslöf M, Larsson K (1983) Chem Phys Lipids 33:211

    Article  CAS  Google Scholar 

  15. Lindblom G, Larsson K, Johansson L, Fontell K, Forsén S (1979) J Am Chem Soc 101:5465–5470

    Article  CAS  Google Scholar 

  16. Crossley A, Freeman IP, Hudson BJF, Pierce JH (1959) J Chem Soc 760–764

    Google Scholar 

  17. Serdarevich B (1967) J Am Oil Chem Soc 44:381–393

    Article  CAS  Google Scholar 

  18. Mattson FH, Volpenhein RA (1962) J Lipid Res 3:281

    CAS  Google Scholar 

  19. Caffrey M (1987) Biochemistry 26:6349

    Article  CAS  Google Scholar 

  20. Caffrey M (1987) Annu Rev Biophys Biophys Chem 18:159

    Article  Google Scholar 

  21. Luzzati V, Vargas R, Gulik A, Mariani P, Seddon JM, Rivas E, (1992) Biochemistry 31:279

    Article  CAS  Google Scholar 

  22. Borné J, Nylander T, Khan A (2001) Langmuir 17:7742–7751

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Dept. Scienze Chimiche, Cagliari University, Cittadella Monserrato, S.S. 554 Bivio Sestu, 09042, Monserrato-Cagliari, Italy

    Sergio Murgia, Francesca Caboi & Maura Monduzzi

  2. Camurus AB, Ideon, Gamma 1, Solvegatan 41, 223 70, Lund, Sweden

    Helena Ljusberg-Wahren

  3. Department of Physical Chemistry 1, Lund University, Center for Chemistry and Chemical Engineering, P.O. Box 124, 221 00, Lund, Sweden

    Tommy Nylander

Authors
  1. Sergio Murgia
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  2. Francesca Caboi
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  3. Maura Monduzzi
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  4. Helena Ljusberg-Wahren
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  5. Tommy Nylander
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Editor information

Tommy Nylander Björn Lindman

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© 2002 Springer-Verlag

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Murgia, S., Caboi, F., Monduzzi, M., Ljusberg-Wahren, H., Nylander, T. (2002). Acyl migration and hydrolysis in monoolein-based systems. In: Nylander, T., Lindman, B. (eds) Lipid and Polymer-Lipid Systems. Progress in Colloid and Polymer Science, vol 120. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45291-5_6

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  • DOI: https://doi.org/10.1007/3-540-45291-5_6

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-43001-8

  • Online ISBN: 978-3-540-45291-1

  • eBook Packages: Springer Book Archive

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