Abstract
Dichroism has been used to study magnetism in mass-selected Fe nanoclusters adsorbed on surfaces in UHV as a function of particle size and density. XMCD shows enhanced orbital, m L and spin, m S magnetic moments in exposed 300-atom particles adsorbed on graphite that decrease towards the bulk value with increasing particle size or density on the surface. Coating exposed 400-atom clusters with Co in situ reduces m L but increases m S yielding a total moment 13% higher than the bulk. The isolated clusters show a cubic anisotropy with a blocking temperature below 10K and an anisotropy constant about 10 times the bulk value. Dense cluster films develop an in-plane anisotropy and remanence at higher temperatures.
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References
I.M.L. Billas, J.A. Becker, A. Chatelain, W.A. de Heer, Phys. Rev. Lett. 34, 4067 (1993).
D.C. Douglass, A.J. Cox, J.P. Bucher, L.A. Bloomfield, Phys. Rev. B 47, 12874 (1993.)
A. E. Berkowitz, J. R. Mitchell, M. J. Carey, A. P. Young, S. Zhang, F. E. Spada, F. T. Parker, A. Hutten, G. Thomas, Phys. Rev. Lett. 68, 3745 (1992).
John Q. Xiao, J. Samuel Jiang, C. L. Chien, Phys. Rev. Lett. 68, 3749 (1992).
S. Mitani, H. Fujimori, K. Takanashi, K. Yakushiji, J-G. Ha, S. Takahashi, S. Maekawa, S. Ohnuma, N. Kobayashi, T. Masumoto, M. Ohnuma, K. Hono, J. Mag. Magn. Mater. 198–199, 179 (1999).
S. H. Baker, S. C. Thornton, K. W. Edmonds, M. J. Maher, C. Norris, C. Binns, Rev. Sci. Instr. 71, 3178 (2000).
M. D. Upward, B. N. Cotier, P. Moriarty, P. H. Beton, S. H. Baker, C. Binns and K. W. Edmonds, J. Vac. Sci. Technol., accepted, July (2000).
B. T. Thole, P. Carra, F. Sette, G. van der Laan, Phys. Rev. Lett. 68, 1943 (1992).
P. Carra, B. T. Thole, M. Altarelli, X. Wang, Phys. Rev. Lett. 70, 694 (1993).
D. Weller, J. Stöhr, R. Nakajima, A. Carl, M. G. Samant, C. Chappert, R. Mégy, P. Beauvillain, P. Veillet, G. Held, Phys. Rev. Lett. 75, 3572 (1995).
K. W. Edmonds, C. Binns, S. H. Baker, M. J. Maher, S. C. Thornton, O. Tjernberg, N. B. Brookes, J. Magn. Magn. Mater., accepted, August (2000).
N. Hamada, J. Phys. Soc. Jpn. 46, 1759 (1979).
K. W. Edmonds, C. Binns, S. H. Baker, S. C. Thornton, P. Finetti, accepted, J. Appl. Phys. (2000).
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Binns, C. et al. (2001). Magnetism in Nanoscale Fe Clusters Studied by Dichroism in X-ray Absorption and Photoemission. In: Beaurepaire, E., Kappler, J.P., Krill, G., Scheurer, F. (eds) Magnetism and Synchrotron Radiation. Lecture Notes in Physics, vol 565. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44954-X_18
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DOI: https://doi.org/10.1007/3-540-44954-X_18
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