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Magnetism in Nanoscale Fe Clusters Studied by Dichroism in X-ray Absorption and Photoemission

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Magnetism and Synchrotron Radiation

Part of the book series: Lecture Notes in Physics ((LNP,volume 565))

Abstract

Dichroism has been used to study magnetism in mass-selected Fe nanoclusters adsorbed on surfaces in UHV as a function of particle size and density. XMCD shows enhanced orbital, m L and spin, m S magnetic moments in exposed 300-atom particles adsorbed on graphite that decrease towards the bulk value with increasing particle size or density on the surface. Coating exposed 400-atom clusters with Co in situ reduces m L but increases m S yielding a total moment 13% higher than the bulk. The isolated clusters show a cubic anisotropy with a blocking temperature below 10K and an anisotropy constant about 10 times the bulk value. Dense cluster films develop an in-plane anisotropy and remanence at higher temperatures.

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© 2001 Springer-Verlag Berlin Heidelberg

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Binns, C. et al. (2001). Magnetism in Nanoscale Fe Clusters Studied by Dichroism in X-ray Absorption and Photoemission. In: Beaurepaire, E., Kappler, J.P., Krill, G., Scheurer, F. (eds) Magnetism and Synchrotron Radiation. Lecture Notes in Physics, vol 565. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44954-X_18

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  • DOI: https://doi.org/10.1007/3-540-44954-X_18

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-42047-7

  • Online ISBN: 978-3-540-44954-6

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