Skip to main content

Electrodeposited Magnetic Monolayers: In-Situ Studies of Magnetism and Structure

  • Chapter
  • First Online:
Solid—Liquid Interfaces

Part of the book series: Topics in Applied Physics ((TAP,volume 85))

Abstract

We show that ultrathin magnetic films of Co and Fe in the thickness range of a few atomic monolayers can be prepared by electrodeposition from an aqueous electrolyte. The high quality of these films is demonstrated by their magnetic and structural properties, which are equivalent to the properties of molecular beam grown Co and Fe films. In order to measure the intrinsic properties of films in this thickness range, in situ measurements are applied to the electrochemical cell, similarly to in situ measurements at ultrathin films in ultrahigh vacuum. Magneto-optical Kerr effect and surface X-ray diffraction are presented as examples to measure magnetism and structure, even at the same film. Thus, electrodeposition of magnetic monolayers turns out to be a useful alternative to the preparation of magnetic ultrathin films by ultrahigh vacuum techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W. Schindler, J. Kirschner: Phys. Rev. B 55, R1989 (1997)

    Article  CAS  Google Scholar 

  2. L. N. Liebermann, D. R. Fredkin, H. B. Shore: Phys. Rev. Lett. 22, 539 (1969)

    Article  CAS  Google Scholar 

  3. N. Liebermann, J. Clinton, D. M. Edwards, J. Mathon: Phys. Rev. Lett. 25, 232 (1970)

    Article  CAS  Google Scholar 

  4. E. Budevski, G. Staikov, W. J. Lorenz: Electrochemical Phase Formation and Growth (VCH, Weinheim 1996)

    Google Scholar 

  5. M. H. Hölzle, V. Zwing, D. M. Kolb: Electrochim. Acta 40, 1237 (1995)

    Article  Google Scholar 

  6. T. Iwasita, N. C. Nart: Prog. Surf. Sci. 55, 271 (1997)

    Article  CAS  Google Scholar 

  7. S. M. Stole, D. D. Popenoe, M. D. Porter: in H. D. Abruna (Ed.): Electrochemical Interfaces (VCH, New York 1992), p. 341

    Google Scholar 

  8. G. L. Richmond: in H. D. Abruna (Ed.): Electrochemical Interfaces (VCH, New York 1992), p. 267

    Google Scholar 

  9. I. K. Robinson, D. J. Tweet: Rep. Prog. Phys. 55, 599 (1992)

    Article  CAS  Google Scholar 

  10. J. Zegenhagen, G. Materlik, J. P. Dirks, M. Schmäh: in Synchrotron Techniques in Interfacial Electrochemistry (Kluwer Academic, Dordrecht 1994), p. 349

    Google Scholar 

  11. Th. Koop, W. Schindler, A. Kazimirov, G. Scherb, J. Zegenhagen, Th. Schulz, R. Feidenhans’l, J. Kirschner: Rev. Sci. Instrum. 69, 1840 (1998)

    Article  CAS  Google Scholar 

  12. S. D. Bader: J. Magn. Magn. Mater. 100, 4 (1991)

    Article  Google Scholar 

  13. M. F. Toney: Synchrotron Techniques in Interfacial Electrochemistry (Kluwer Academic, Dordrecht 1994) p. 109

    Google Scholar 

  14. W. Schindler, Th. Koop, J. Kirschner: Z. Phys. Chem. 208, 93 (1999)

    CAS  Google Scholar 

  15. W. Schindler, J. Kirschner: Rev. Sci. Instrum. 67, 3578 (1996)

    Article  CAS  Google Scholar 

  16. W. Schindler, Th. Koop, D. Hofmann, J. Kirschner: IEEE Trans. Mag. 34, 963 (1998)

    Article  CAS  Google Scholar 

  17. C. M. Schneider, P. Bressler, P. Schuster, J. Kirschner, J. J. de Miguel, R. Miranda: Phys. Rev. Lett. 64, 1059 (1990)

    Article  CAS  Google Scholar 

  18. P. Krams, F. Lauks, R. L. Stamps, B. Hillebrands, G. Güntherodt: Phys. Rev. Lett. 69, 3674 (1992)

    Article  CAS  Google Scholar 

  19. H. A. Wierenga, W. de Jong, M. W. J. Prins, Th. Rasing, R. Vollmer, A. Kirilyuk, H. Schwabe, J. Kirschner: Phys. Rev. Lett. 74, 1462 (1995)

    Article  CAS  Google Scholar 

  20. Ch. Kittel: Introduction to Solid State Physics (Wiley, New York 1996)

    Google Scholar 

  21. J. H. van der Merwe: J. Appl. Phys. 34, 117 (1963)

    Article  Google Scholar 

  22. W. A. Jesser, J. W. Matthews: Philos. Mag. 17, 461 (1968)

    Article  CAS  Google Scholar 

  23. J. Fassbender, U. May, B. Schirmer, R. M. Jungblut, B. Hillebrands, G. Güntherodt: Phys. Rev. Lett. 75, 4476 (1995)

    Article  CAS  Google Scholar 

  24. W. Schindler, Th. Koop, G. Scherb, A. Kazimirov, J. Zegenhagen, Th. Schultz, R. Feidenhans’l, J. Kirschner: Surf. Sci. 465, L738 (2000)

    Google Scholar 

  25. S. Müller, P. Bayer, A. Kinne, C. Reischl, R. Metzler, K. Heinz: Surf. Sci. 331–333, 723 (1995)

    Article  Google Scholar 

  26. H. Landskron, G. Schmidt, K. Heinz, K. Müller, C. Stuhlmann, U. Beckers, M. Wuttig, H. Ibach: Surf. Sci. 256, 115 (1991)

    Article  CAS  Google Scholar 

  27. J. Shen, H. Jenniches, C. V. Mohan, J. Barthel, M. Klaua, P. Ohresser, J. Kirschner: Europhys. Lett. 43, 349 (1998)

    Article  CAS  Google Scholar 

  28. H. Jenniches, J. Shen, C. V. Mohan, S. S. Manoharan, J. Barthel, P. Ohresser, M. Klaua, J. Kirschner: Phys. Rev. B 59, 1196 (1999)

    Article  CAS  Google Scholar 

  29. A. Kirilyuk, J. Giergiel, J. Shen, J. Kirschner: Phys. Rev. B 52, R11672 (1995)

    Article  CAS  Google Scholar 

  30. P. Schmailzl, K. Schmidt, P. Bayer, R. Döll, K. Heinz: Surf. Sci. 312, 73 (1994)

    Article  CAS  Google Scholar 

  31. J. Giergiel, J. Kirschner, J. Landgraf, J. Shen, J. Woltersdorf: Surf. Sci. 310, (1994)

    Google Scholar 

  32. J. Giergiel, J. Shen, J. Woltersdorf, A. Kirilyuk, J. Kirschner: Phys. Rev. B 52, 8528 (1995)

    Article  CAS  Google Scholar 

  33. J. Shen, C. Schmidthals, J. Woltersdorf, J. Kirschner: Surf. Sci. 407, 90 (1998)

    Article  CAS  Google Scholar 

  34. R. Vollmer: Phys. Rev. B 61, 4146 (2000)

    Article  CAS  Google Scholar 

  35. H. Ibach: Surf. Sci. Rep. 29, 193 (1997)

    Article  CAS  Google Scholar 

  36. R. Koch, J.Phys.: Condens. Matter 6, 9519 (1994)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Schindler, W. (2003). Electrodeposited Magnetic Monolayers: In-Situ Studies of Magnetism and Structure. In: Wandelt, K., Thurgate, S. (eds) Solid—Liquid Interfaces. Topics in Applied Physics, vol 85. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44817-9_8

Download citation

  • DOI: https://doi.org/10.1007/3-540-44817-9_8

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-42583-0

  • Online ISBN: 978-3-540-44817-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics