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Metal-Aminoxyl-Based Molecular Magnets

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Book cover π-Electron Magnetism

Part of the book series: Structure and Bonding ((STRUCTURE,volume 100))

Abstract

The nitroxide radical is one example of a stable organic radical, and the oxygen atom of the nitroxide group exhibits weak basicity; therefore, it demonstrates coordinating ability with respect to transition metal ions. There are many π-conjugated oligo-nitroxides which have high-spin ground states. When the oligo-nitroxides are used as a bridging ligand for paramagnetic metal ions, we can control both of the structure of the complex and the spin structure. This chapter discusses one-dimensional, two-dimensional, and three-dimensional magnetic materials derived from coordination complexes consisting of magnetic metal ions and nitroxide radicals.

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Author information

Authors and Affiliations

  1. Institute for Molecular Science, 38 Nishigounaka, Myodaiji, Okazaki, 444-8585, Japan

    Katsuya Inoue

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  1. Katsuya Inoue
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Editors and Affiliations

  1. Institut de Ciència de Materials de Barcelona, Campus Universitari de Bellaterra, 01893, Cerdanyola, Spain

    Jaume Veciana

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Dedicated to the memory of Prof. Olivier Khan

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© 2001 Springer-Verlag Berlin Heidelberg

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Inoue, K. (2001). Metal-Aminoxyl-Based Molecular Magnets. In: Veciana, J., et al. π-Electron Magnetism. Structure and Bonding, vol 100. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44684-2_3

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  • DOI: https://doi.org/10.1007/3-540-44684-2_3

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-41680-7

  • Online ISBN: 978-3-540-44684-2

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