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Properties of a membrane-forming polymer, poly(1-trimethylgermyl-1-propyne), in dilute solutions

  • G. M. Pavlov
  • N. A. Michailova
  • E. V. Korneeva
  • N. P. Yevlampieva
  • E. I. Rjumtsev
  • V. S. Khotimsky
  • E. G. Litvinova
  • M. B. Chirkova
Conference paper
Part of the Progress in Colloid and Polymer Science book series (PROGCOLLOID, volume 119)

Abstract

Samples and fractions of a membrane-forming polymer, poly (1-trimethylgermyl-1-propyne) (PTMGP), were studied by methods of molecular hydrodynamics in cyclohexane in the molecular weight range 4 < M x 10-4 < 170. Molecular-weight dependencies of the hydrodynamic characteristics were established and analysed. On the basis of them the equilibrium rigidity of PTMGP chains was evaluated. The influence of volume effects on the size of macromolecules is discussed. A comparison is made with the results published for molecules of poly(1-phenyl-1-propyne) and poly(1-trimethylsilyl-1-propyne).

Key words

Polygermylpropyne Hydrodynamic properties Macromolecule size 

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Copyright information

© Springer-Verlag 2002

Authors and Affiliations

  • G. M. Pavlov
    • 1
  • N. A. Michailova
    • 1
  • E. V. Korneeva
    • 2
  • N. P. Yevlampieva
    • 1
  • E. I. Rjumtsev
    • 1
  • V. S. Khotimsky
    • 3
  • E. G. Litvinova
    • 3
  • M. B. Chirkova
    • 3
  1. 1.Institute of Physics of St. PetersburgState UniversitySt. PetersburgRussia
  2. 2.Institute of Macromolecular compoundsRussian Academy of SciencesSt. PetersburgRussia
  3. 3.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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