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Hybrid polymer heterogeneity and boundary profile in a low-speed sedimentation experiment

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Analytical Ultracentrifugation VI

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 119))

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Abstract

Solution properties of a new hybrid polymer (fullerene-containing polymer, FP) with a regular structure of macromolecules have been studied. In the starlike polymer molecule, six equal polystyrene chains and six poly(tert-butyl methacrylate) ones are attached as the arms to the fullerene C60 molecule used as a core. Hydrodynamic characteristics of the FP sample were compared with param eters of the six-arm star FP. The boundary profile in a low-speed sedimentation experiment obtained in several solvents with different refractive indices was analyzed to determine the inhomogeneity of the hybrid polymer sample.

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Author information

Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    Peter Lavrenko & Darya Volokhova

  2. Physical Department, St. Petersburg State University, Petergoff, 198904, St. Petersburg, Russia

    Kirill Yevlampiev

Authors
  1. Peter Lavrenko
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  2. Kirill Yevlampiev
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  3. Darya Volokhova
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Editor information

W. Borchard A. Straatmann

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© 2002 Springer-Verlag

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Lavrenko, P., Yevlampiev, K., Volokhova, D. (2002). Hybrid polymer heterogeneity and boundary profile in a low-speed sedimentation experiment. In: Borchard, W., Straatmann, A. (eds) Analytical Ultracentrifugation VI. Progress in Colloid and Polymer Science, vol 119. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44672-9_3

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  • DOI: https://doi.org/10.1007/3-540-44672-9_3

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-42489-5

  • Online ISBN: 978-3-540-44672-9

  • eBook Packages: Springer Book Archive

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