Evaluation of draining and volume effects in the interpretation of hydrodynamic data for linear macromolecules

  • G. M. Pavlov
Conference paper
Part of the Progress in Colloid and Polymer Science book series (PROGCOLLOID, volume 119)


The equations describing the molecular-weight dependences of hydrodynamic values are compared for the cases of the excluded-volume effect and the draining effect. It is shown that they may be presented in a symmetric form. The equation obtained on the basis of the Gray—Bloomfield—Hearst theory of translational friction is applied to several polymer-solvent systems. The cases of a flexible chain with an excluded-volume effect and a semirigid chain with both excluded-volume and draining effects are considered. The intrinsic viscosity data are considered in a similar way.

Key words

Molecular hydrodynamics Excluded volume Draining effects Linear macromolecules 


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Copyright information

© Springer-Verlag 2002

Authors and Affiliations

  • G. M. Pavlov
    • 1
    • 2
  1. 1.Institute of PhysicsSt. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Laboratoire de Biophysique MoleculaireInstitut de Biologie StructuraleGrenobleFrance

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