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Glycoscience pp 77–114Cite as

D-Xylose (D-Glucose) Isomerase and Related Enzymes in Carbohydrate Synthesis

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Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 215))

Abstract

Enzymatically catalysed isomerisation of free sugars is an important and economically viable alternative to chemical means for achieving such transformations. The conversion of D-glucose into D-fructose with D-xylose (D-glucose) isomerase (EC 5.3.1.5) has become a largescale industrial application producing more than ten million tons of fructose syrup annually. Due to the remarkable tolerance of this and related enzymes, for example, L-fucose isomerase (EC 5.3.1.3), for epimers, as well as chemically modified substrate analogues bearing nonnatural features, such as azido or fluoro substituents, a large variety of interesting and novel synthetic applications has become feasible for these remarkably useful and easy-to-handle biocatalysts.

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  1. Glycogroup, Institut für Organische Chemie der Technischen Universität Graz, Stremayrgasse 16, 8010, Graz, Austria

    Herwig Häsler & Arnold E. Stütz

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  1. Herwig Häsler
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  1. Institut für Organische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010, Graz, Austria

    Arnold E. Stütz

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Häsler, H., Stütz, A.E. (2001). D-Xylose (D-Glucose) Isomerase and Related Enzymes in Carbohydrate Synthesis. In: Stütz, A.E. (eds) Glycoscience. Topics in Current Chemistry, vol 215. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44422-X_5

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