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Regional Distribution of Pd, Pt and Au-Emissions from the Nickel Industry on the Kola Peninsula, NW-Russia, as Seen in Moss and Humus Samples

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Abstract

Palladium (Pd), Platinum (Pt) and Gold (Au) were analysed in 598 terrestrial moss and 617 O-horizon samples from a 188,000 km2-area surrounding several plants within the Russian nickel industry on the Kola Peninsula. At the time of the survey ore from the Noril’sk deposits in Siberia, which has high concentrations of platinum group elements (PGE), was processed in the Monchegorsk smelter. In contrast, the smelter in Nikel and the ore roasting plant in Zapolyarnij processed predominantly local Pechenga ore, which has low PGE and Au-concentrations. Moss and O-horizon samples were analysed by a method using reductive co-precipitation to enrich PGE and Au prior to analysis. Unusually low detection limits could be reached (Au: 0.05 ppb, Pd 0.1 ppb and Pt 0.3 ppb), allowing the construction of reliable regional geochemical maps. Maps and transects demonstrate the impact of the smelters on the arctic environment. Differences in the ore feed are well reflected in the emissions. Although the Kola smelters belong to the most important PGE-emitters on earth, background concentrations for all three elements are reached at a distance of less than 200 km from source. Several geogenic anomalies highlight the further exploration potential of the area for Au and PGE-deposits. Results can also be used to calculate approximate emission figures for the Monchegorsk smelter (0.1 t Au, 2.2 t Pd and 0.8 t Pt per year).

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References

  • Äyräs M, Reimann C (1995) Joint ecogeochemical mapping and monitoring in the scale of 1:1 mill. in the West Murmansk Region and contiguous areas of Finland and Norway-1994–1996. Field Manual. Norges Geologiske Undersøkelse Report 95.111.

    Google Scholar 

  • Balcerzak M (1997) Analytical methods for the determination of platinum in biological and environmental materials, a review. Analyst 122:67R–74R.

    Article  CAS  Google Scholar 

  • Barefoot RR (1997) Determination of platinum at trace levels in environmental and biological materials. Env Sci Technol 31:309–314.

    CAS  Google Scholar 

  • Barnes SJ, Boyd R, Korneliussen A, Nilsson LP, Often M, Pedersen RB, Robins B (1988) The use of mantle normalization and metal ratios in discriminating between the effects of partial melting, crystal fractionation and sulphide segregation on platinum-group elements, gold, nickel and copper: examples from Norway. In: Pritchard HM, Potts PJ, Bowles JF, Cripp SJ (eds) Geoplatinum, Elsevier, London:113–143.

    Google Scholar 

  • Borggaard OK (1997) Composition, properties and development of nordic soils. In: Saether OM, Caritat P de (eds): Geochemical Processes, Weathering and Ground-Water Recharge in Catchments. Balkema, Rotterdam:21–75.

    Google Scholar 

  • Boyd R, Niskavaara H, Kontas E, Chekushin V, Pavlov V, Often M, Reimann C (1997) Anthropogenic noble-metal enrichment of topsoil in the Monchegorsk area, Kola Peninsula, northwest Russia. J Geochem Explor 58:283–289.

    Article  CAS  Google Scholar 

  • Boyd R, Barnes SJ, Caritat P de, Chekushin VA, Melezhik VA, Reimann C, Zientek MA (1998) Assessment of heavy metal emissions from the copper-nickel industry on the Kola Peninsula and in other parts of Russia. Norges Geologiske Undersøkelse Report 98.138.

    Google Scholar 

  • Cicchella D, De Vivo B, Lima A (2003) Palladium and platinum concentration in soils from the Napoli metropolitan area, Italy: possible effects of catalytic exhausts. Sci Tot Env 308:121–131.

    CAS  Google Scholar 

  • Dongarrá G, Varrica D, Sabatino G (2003) Occurence of platinum, palladium and gold in pine needles of Pinus pinea L. from the city of Palermo (Italy). Appl Geochem 18:109–116.

    Google Scholar 

  • Dunn CE (1986) Biogeochemistry as an aid to exploration of gold, platinum and palladium in the northern forests of Saskatchewan. J Geochem Explor 24:21–40.

    Google Scholar 

  • Farago ME, Kavanagh P, Blanks R, Kelly J, Kazantsis G, Thornton I, Simpson PR, Cook JM, Parry S, Hall GEM (1996) Platinum metal concentrations in urban road dust and soil in the United Kingdom. Fresenius J Anal Chem 354:660–663.

    CAS  Google Scholar 

  • Gregurek D, Melcher F, Niskavaara H, Pavlov VA, Reimann C, Stumpfl EF (1999). Platinum-Group Elements (Rh, Pd, Pt) and Au distribution in snow samples from the Kola Peninsula, NW Russia. Atmospheric Environment 33/20:3291–3299.

    Article  Google Scholar 

  • Kashulina G, Reimann C, Finne TE, Halleraker JH, Äyräs M, Chekushin VA (1997) The state of the ecosystems in the central Barents Region: scale, factors and mechanism of disturbance. Sci Tot Env 206:203–225.

    CAS  Google Scholar 

  • Kontas E, Niskavaara H, Virtasalo J (1990) Gold, palladium and tellurium in South African, Chinese and Japanese geological reference samples. Geostandards Newsletter 13:477–478.

    Google Scholar 

  • Kovalevskii AL (2001) Biogeochemical prospecting for platinum group metals in eastern Siberia. GEEA 1:143–146.

    CAS  Google Scholar 

  • Lide DR (ed.) (1996) CRC Handbook of Chemistry and Physics. 77th edition. CRC Press, Boca Raton, USA.

    Google Scholar 

  • Leśeniewska BA, Godlewska-Zyłkiewicz B, Bocca B, Caimi S, Caroli S, Hulanicki A (2004) Platinum, palladium and rhodium content in road dust, tunnel dust and common grass in Białystok area (Poland): a pilot study. Sci Tot Env 321:93–104.

    Google Scholar 

  • Müller M, Heumann KG (2000) Isotope dilution inductively coupled plasma quadrupole mass spectrometry in connection with a chromatographic separation for ultra trace determinations of platinum group elements (Pt, Pd, Ru, Ir) in environmental samples. Fresenius J Anal Chem 357:1157–1163.

    Google Scholar 

  • Naldrett AJ, Cabri LJ (1976) Ultramafic and related mafic rocks: their classification and genesis with special reference to the concentration of nickel sulfides and platinum-group elements. Econ Geol 71:1131–1158.

    CAS  Google Scholar 

  • Niskavaara H, Kontas E (1990) Reductive co-precipitation as a separation method for the determination of gold, palladium, platinum, rhodium, silver, selenium and tellurium in geological samples by graphite furnace atomic absorption spectrometry. Anal Chim Acta 231:273–282.

    Article  CAS  Google Scholar 

  • Niskavaara H, Kontas E, Reimann C (2004). Regional distribution and sources of Au, Pd and Pt in moss and O-, B-and C-horizon podzol samples in the European Arctic. GEEA 4:143–159.

    CAS  Google Scholar 

  • Reimann C, Garrett RG (2005) Geochemical background — Concept and reality. Sci Tot Env (in press).

    Google Scholar 

  • Reimann C, Äyräs M, Chekushin VA, Bogatyrev I, Boyd R, Caritat P de, Dutter R, Finne TE, Halleraker JH, Jäger Ø, Lehto O, Niskavaara H, Räisänen ML, Starnd T, Volden T (1998) Environmental Geochemical Atlas of the Central Barents Region. NGU-GTK-CKE Special Publication, Geological Survey of Norway, Trondheim, Norway.

    Google Scholar 

  • Reimann C, Filzmoser P, Garrett RG (2005) Background and threshold: critical comparison of methods of determination. Sci Tot Env (in press).

    Google Scholar 

  • Smirnov VI (1977) Ore deposits of the USSR, Vol. III. Pitman, San Francisco.

    Google Scholar 

  • Smith-Sivertsen T, Lund E, Thomassen Y, Norseth T (1997) Human nickel exposure in an area polluted by nickel refining: The Sør-Varanger study. Arch Environ Health 52/6:464–471.

    Google Scholar 

  • Smith-Sivertsen T, Tchachtchine V, Lund E, Bykov V, Thomassen Y, Norseth T (1998) Urinary nickel excretion in populations living in the proximity of two Russian nickel refineries: a Norwegian-Russian population-based study. Environ Health Persp 106/8:503–511.

    Google Scholar 

  • Taylor SR, McLennan SM (1995) The geochemical evolution of the continental crust. Rev Geophys 33:241–265.

    Article  Google Scholar 

  • Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59:1217–1232.

    CAS  Google Scholar 

  • Wegscheider W, Zischka M (1993) Quality assurance in environmental research: emissions and fate of platinum. Fresenius J Anal Chem 346:525–52.

    Article  CAS  Google Scholar 

  • Wilhelm HJ, Zhang H, Chen FL, Elsenbroek JH, Lombard M, De Bruin D (1997) Geochemical exploration for platinum-group elements in the Bushveld Complex, South Africa. Min Dep 32:349–361.

    Article  CAS  Google Scholar 

  • Zereini F, Skerstupp B, Alt F, Helmers E, Urban H (1997) Geochemical behaviour of platinum group elements (PGE) in particulate emission by automoblile exhaust catalysts: experimental results and environmental investigations. Sci Tot Env 206:137–146.

    CAS  Google Scholar 

  • Zereini F, Skerstupp B, Rankenburg K, Dirksen F, Beyer JM, Claus T, Urban H (2000) Anthropogenic emission of platinum group elements (Pt, Pd and Rh) into the environment: concentration, distribution and geochemical behaviour in soils. In: Zereini F, Alt F. (eds) Anthropogenic platinum group element emission: their impact on man and environment. Heidelberg, Springer Verlag: 73–83.

    Google Scholar 

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Reimann, C., Niskavaara, H. (2006). Regional Distribution of Pd, Pt and Au-Emissions from the Nickel Industry on the Kola Peninsula, NW-Russia, as Seen in Moss and Humus Samples. In: Zereini, F., Alt, F. (eds) Palladium Emissions in the Environment. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-29220-9_4

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